THE OXIDATION, IGNITION, AND DETONATION OF FUEL VAPORS AND GASES: IV. THE CAUSE OF DETONATION OR COMBUSTION KNOCK IN ENGINES
A nuclear theory of self-ignition is described which is based on the substitution of finely divided carbon for the nuclear drops of the Callendar theory. The finely divided carbon appears in the gaseous combustible mixture in the engine as a result of pyrolysis of the lubricating oil or of the fuel. The theory is therefore of general application and can be applied to explain combustion knock or detonation when permanent gases such as hydrogen as well as hydrocarbon vapors are used as fuel for the carburetor type of internal combustion engine. The theory is supported by experimental evidence quoted mainly from earlier publications and is intended as a working hypothesis for further confirmatory experiments.