THE FLOW OF GASES AND VAPORS THROUGH ADSORBING POROUS MEDIA
The flow rates of gases and vapors through highly activated charcoal rods have been measured. The results obtained indicate that a new phenomenon has been discovered. While the flow rates of gases that are not highly adsorbed can be satisfactorily correlated by the Adzumi equation and other equations of similar mathematical form, it has been found that the strongly adsorbed vapors of diethyl ether and ethyl chloride pass through the charcoal rods at rates considerably m excess of those required by known equations. To explain the results it appears necessary to resort to mechanisms quite outside of those usually considered in the application of kinetic theory to problems associated with passage of gas through porous diaphragms. The simplest and most direct of such mechanisms involves mobility of the adsorbed material. It is particularly striking that the flow rate of diethyl ether through activated charcoal rods has been found to be greater than that of helium in pressure regions where relative rates of flow of gases through non-adsorbing porous diaphragms are dominated by inverse square root molecular weight ratios. The measurement of gaseous flow rates through porous media are rendered the more difficult where appreciable adsorption occurs. The experimental methods are described in detail, sources of error are discussed, and results presented for the gases helium, hydrogen, nitrogen, carbon dioxide, diethyl ether, and ethyl chloride.