MEASUREMENT OF DIELECTRIC CONSTANT OF ELECTROLYTES

1935 ◽  
Vol 12 (3) ◽  
pp. 377-397 ◽  
Author(s):  
R. W. McKay
Keyword(s):  
Dielectric Constant ◽  
Sodium Chloride ◽  
Hydrogen Chloride ◽  
Magnesium Sulphate ◽  
Copper Sulphate ◽  
Potassium Ferrocyanide ◽  
Potassium Sulphate ◽  
Sources Of Error ◽  
Voltage Resonance

An apparatus for measuring the dielectric constant of conducting solutions by voltage resonance is described. The theory of the circuit and the sources of error are discussed. The design of the apparatus is such as to eliminate errors other than those due to inductance of cell leads, for which a correction is made.Measurements have been made on solutions of sodium chloride, hydrogen chloride, potassium sulphate, magnesium sulphate, copper sulphate and potassium ferrocyanide, at 23.0 °C. and 2 × 106 cycles frequency. An increase in dielectric constant with concentration greater than that predicted by Debye and Falkenhagen has been found in all cases. The results are compared with those of other workers. Graphs are given of the results obtained.

Salt effect in hydrolysis of 3-acyl-1,3-diphenyltriazenes

1981 ◽  
Vol 46 (12) ◽  
pp. 3104-3109 ◽  
Author(s):  
Miroslav Ludwig ◽  
Oldřich Pytela ◽  
Miroslav Večeřa
Keyword(s):  
Sodium Chloride ◽  
Temperature Dependence ◽  
Potassium Chloride ◽  
Rate Constants ◽  
Zinc Sulphate ◽  
Salt Effect ◽  
Sodium Sulphate ◽  
Potassium Sulphate ◽  
Lithium Sulphate ◽  
Hydrolysis Of

Rate constants of non-catalyzed hydrolysis of 3-acetyl-1,3-diphenyltriazene (I) and 3-(N-methylcarbamoyl)-1,3-diphenyltriazene (II) have been measured in the presence of salts (ammonium chloride, potassium chloride, lithium chloride, sodium chloride and bromide, ammonium sulphate, potassium sulphate, lithium sulphate, sodium sulphate and zinc sulphate) within broad concentration ranges. Temperature dependence of the hydrolysis of the substrates studied has been measured in the presence of lithium sulphate within temperature range 20° to 55 °C. The results obtained have been interpreted by mechanisms of hydrolysis of the studied substances.

RECIPROCAL SALT PAIRS, INVOLVING THE CATIONS Li2, Na2, AND K2, THE ANIONS SO4, AND Cl2, AND WATER, AT 25 °C

1958 ◽  
Vol 36 (11) ◽  
pp. 1511-1517 ◽  
Author(s):  
A. N. Campbell ◽  
E. M. Kartzmark ◽  
E. G. Lovering
Keyword(s):  
Sodium Chloride ◽  
Potassium Chloride ◽  
Mole Fraction ◽  
Lithium Chloride ◽  
Invariant Point ◽  
Double Salt ◽  
Potassium Sulphate ◽  
Lithium Sulphate ◽  
Solid Phases ◽  
Chloride Monohydrate

In the reciprocal salt pair Li2, K2, Cl2, SO4, and water, at 25 °C there are large areas in which potassium sulphate and potassium lithium sulphate (KLiSO4) are separately in equilibrium with solution. Two incongruent invariant points exist. At one of these the composition of the solution is 0.917 mole fraction chloride, 0.437 mole fraction lithium, and 19.4 moles of water per total mole of salt, the equilibrium solid phases being potassium chloride, potassium sulphate, and the double salt. At the second, the composition of the solution is 0.967 mole fraction chloride, 0.870 mole fraction lithium, and 13.8 moles of water per mole of salt, the solid phases being potassium chloride, double salt, and lithium sulphate monohydrate. One congruent invariant point exists, at which the composition of the solution is 1.00 mole fraction chloride, 0.960 mole fraction lithium, and 9.6 moles of water per mole of salt, the solid phases being lithium sulphate monohydrate, lithium chloride monohydrate, and potassium chloride.In the reciprocal salt pair Li2, Na2, Cl2, SO4, and water, at 25 °C there is an incongruent invariant point at which the composition of the solution is 0.873 mole fraction chloride, 0.668 mole fraction lithium, and 15.1 moles water per total mole of salt, the solid phases being sodium chloride, solid solution of sodium and lithium sulphates, and lithium sulphate monohydrate. A congruent invariant point exists, at which the composition of the solution is practically entirely lithium chloride, the solid phases present being lithium chloride monohydrate, lithium sulphate monohydrate, and sodium chloride.

A simplified form of Stokes–Robinson equation

1976 ◽  
Vol 54 (1) ◽  
pp. 9-11 ◽  
Author(s):  
Chai-Fu Pan
Keyword(s):  
Sodium Chloride ◽  
Hydrogen Chloride ◽  
Activity Coefficients ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Solvent Interactions ◽  
Interionic Interactions ◽  
Two Parameter ◽  
Robinson Equation ◽  
Existing Data

In non-associated dilute aqueous electrolyte solutions, the deviation from ideality is principally attributed to the interionic interactions and hydration of ions. Stokes and Robinson combined Bjerrum's thermodynamic treatment of ion–solvent interactions with Debye–Hückel treatment of interionic interactions to obtain a two-parameter equation. In very dilute regions, the Stokes and Robinson's equation reduces to a much simpler form, i.e.[Formula: see text]Activity coefficients of an electrolyte at lower concentrations, say up to 0.1 m, can be calculated from the equation provided suitable values of &([a-z]+); and h are available. Solutions of hydrogen chloride and sodium chloride were chosen as examples. The results agree with the existing data very satisfactorily.

Thermodynamic Calculation of Hydrogen Chloride Generation in Blast Furnace Smelting Process

2014 ◽  
Vol 1033-1034 ◽  
pp. 1300-1304
Author(s):  
Bin Sheng Hu ◽  
Xiao Guang Liu ◽  
Yong Liang Gui ◽  
Kai Lv
Keyword(s):  
Blast Furnace ◽  
Sodium Chloride ◽  
Sulfur Dioxide ◽  
Nitrogen Dioxide ◽  
Hydrogen Chloride ◽  
Thermodynamic Calculation ◽  
Smelting Process ◽  
Blast Furnace Smelting ◽  
Furnace Shaft ◽  
Furnace Smelting

The generating pathways of hydrogen chloride in blast furnace smelting process may have two pathways: 1.sodium chloride and water react with phosphorus pentaoxide forming hydrogen chloride gas.2. Sodium chloride and water react with sulfur dioxide and nitrogen dioxide forming hydrogen chloride gas. Based on Thermodynamic calculation of hydrogen chloride generation in blast furnace smelting process, hydrogen chloride gas is generated in the upper part of blast furnace shaft ,the generating temperature main range from 300°C too 800°C.

scholarly journals Effect of Solvent on Protonation Equilibria ofL-Proline andL-Valine in 1, 2-Propanediol-Water Mixtures

2012 ◽  
Vol 9 (2) ◽  
pp. 517-524 ◽  
Author(s):  
P. Bhushanavathi ◽  
B. Veeraswamy ◽  
G. Nageswara Rao ◽  
U. Viplavaprasad
Keyword(s):  
Dielectric Constant ◽  
Sodium Chloride ◽  
Ionic Strength ◽  
Protonation Constants ◽  
Protonation Equilibria ◽  
Effect Of Solvent ◽  
R Factor ◽  
Chemical Models ◽  
Best Fit ◽  
Skewness And Kurtosis

Protonation equilibria ofL-proline and L-valine in varying compositions (0.0-60.0% v/v) of 1, 2-Propanediol-water mixtures were investigated pH-metrically. Titrations were performed at 303.0 K and the ionic strength of the medium was maintained at 0.16 mol L-1using sodium chloride. The best fit chemical models of the protonation equilibria were based on crystallographic R-factor, Χ2, skewness, and kurtosis. All the protonation constants of proline and valine increased with increasing propanediol content. This is attributed to the dielectric constant of the medium.

The effects of potassium and magnesium fertilizers on yield and composition of successive crops of ryegrass, clover, sugar beet, potatoes, kale and barley on sandy soil at Woburn

1968 ◽  
Vol 70 (3) ◽  
pp. 303-311 ◽  
Author(s):  
J. Bolton ◽  
A. Penny
Keyword(s):  
Sodium Chloride ◽  
Sugar Beet ◽  
Dry Matter ◽  
Magnesium Deficiency ◽  
Yield Response ◽  
Potassium Sulphate ◽  
Exchangeable Potassium ◽  
Percentage Yield ◽  
Exchangeable Magnesium ◽  
South East England

SUMMARYIn an 8-year field experiment, potassium sulphate and to a lesser extent magnesium sulphate increased yields of all crops both when applied alone and together. Although K/Mg interactions did not affect yields they considerably affected the ratio of concentrations of these elements in the dry matter of the crops. Sodium chloride increased yields of kale but not of barley harvested at ear-emergence.Percentage yield response to potasium followed the orderPotatoes (218%) < clover = barley < sugar beet < kato; < ryegress (17%).Magnesium increased yields from 3 to 10%, most with potatoes.Changes in exchangeable magnesium in the soil reflected differences between applied magnesium and crop uptakes. Changes in exchangeable potassium were less than expected, probably because non-exchangeable potassium was released on plots without added potassium and ‘fixed’ in non-exchangeable forms on plots where much fertilizer potassium had been given.Increase in the incidence of magnesium deficiency symptoms reported recently in South. East England are attributed to the local liming materials containing only small amounts of magnesium and to less F.V.M being applied to crops than previously.

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