scholarly journals Experimental measurements of the Paschen–Back effect in helium triplet transitions

2017 ◽  
Vol 95 (10) ◽  
pp. 993-998 ◽  
Author(s):  
Andrew S. Taylor ◽  
Oleg V. Batishchev
Keyword(s):  
Near Infrared ◽  
Theoretical Calculations ◽  
Spectral Shift ◽  
High Resolution Spectroscopy ◽  
Zero Magnetic Field ◽  
Good Precision ◽  
Line Shapes ◽  
Novel Approach ◽  
Fluorescence Camera ◽  
Magnetic Field Position

Experimental confirmation of the theoretical calculations of the Zeeman and Paschen–Back effects in the prominent 2 3S – 2 3P He I 1083 nm near-infrared (NIR) transition by means of high-resolution spectroscopy is reported. A novel approach using a small-pixel-size fluorescence camera delivers required spectral resolution. In particular, it allows to quantify with good precision the spectral shift of the weak λ0 = 1082.9 nm line from the zero magnetic field position. Measurements of the strong visible (VIS) He I 587 and 706 nm triplet line shapes are reported for B = 0–1.0 T interval, indicating nonlinear wave function mixing as well.

scholarly journals A multicolor and ratiometric fluorescent sensing platform for metal ions based on arene–metal-ion contact

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Anna Kanegae ◽  
Yusuke Takata ◽  
Ippei Takashima ◽  
Shohei Uchinomiya ◽  
Ryosuke Kawagoe ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Near Infrared ◽  
Molecular Design ◽  
Theoretical Calculations ◽  
Probe Design ◽  
One Pot ◽  
Fluorescent Sensing ◽  
Sensing Platform ◽  
Ratiometric Detection

AbstractDespite continuous and active development of fluorescent metal-ion probes, their molecular design for ratiometric detection is restricted by the limited choice of available sensing mechanisms. Here we present a multicolor and ratiometric fluorescent sensing platform for metal ions based on the interaction between the metal ion and the aromatic ring of a fluorophore (arene–metal-ion, AM, coordination). Our molecular design provided the probes possessing a 1,9-bis(2′-pyridyl)-2,5,8-triazanonane as a flexible metal ion binding unit attached to a tricyclic fluorophore. This architecture allows to sense various metal ions, such as Zn(II), Cu(II), Cd(II), Ag(I), and Hg(II) with emission red-shifts. We showed that this probe design is applicable to a series of tricyclic fluorophores, which allow ratiometric detection of the metal ions from the blue to the near-infrared wavelengths. X-ray crystallography and theoretical calculations indicate that the coordinated metal ion has van der Waals contact with the fluorophore, perturbing the dye’s electronic structure and ring conformation to induce the emission red-shift. A set of the probes was useful for the differential sensing of eight metal ions in a one-pot single titration via principal component analysis. We also demonstrate that a xanthene fluorophore is applicable to the ratiometric imaging of metal ions under live-cell conditions.

scholarly journals Colossal anomalous Nernst effect in a correlated noncentrosymmetric kagome ferromagnet

2021 ◽  
Vol 7 (13) ◽  
pp. eabf1467
Author(s):  
T. Asaba ◽  
V. Ivanov ◽  
S. M. Thomas ◽  
S. Y. Savrasov ◽  
J. D. Thompson ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Electronic Structure ◽  
Theoretical Calculations ◽  
Zero Magnetic Field ◽  
Nernst Effect ◽  
Nodal Lines ◽  
Transverse Response ◽  
Narrow Bands ◽  
Strong Spin ◽  
Anomalous Nernst Effect

The transverse voltage generated by a temperature gradient in a perpendicularly applied magnetic field, termed the Nernst effect, has promise for thermoelectric applications and for probing electronic structure. In magnetic materials, an anomalous Nernst effect (ANE) is possible in a zero magnetic field. We report a colossal ANE in the ferromagnetic metal UCo0.8Ru0.2Al, reaching 23 microvolts per kelvin. Uranium’s 5f electrons provide strong electronic correlations that lead to narrow bands, a known route to producing a large thermoelectric response. In addition, uranium’s strong spin-orbit coupling produces an intrinsic transverse response in this material due to the Berry curvature associated with the relativistic electronic structure. Theoretical calculations show that in UCo0.8Ru0.2Al at least 148 Weyl nodes, and two nodal lines, exist within 60 millielectron volt of the Fermi level. This work demonstrates that magnetic actinide materials can host strong Nernst and Hall responses due to their combined correlated and topological nature.

scholarly journals Integrated impedance sensing of liquid sample plug flow enables automated high throughput NMR spectroscopy

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Omar Nassar ◽  
Mazin Jouda ◽  
Michael Rapp ◽  
Dario Mager ◽  
Jan G. Korvink ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
High Throughput ◽  
Plug Flow ◽  
Microfluidic System ◽  
High Resolution Spectroscopy ◽  
Dead Volume ◽  
Absolute Difference ◽  
Immiscible Fluid ◽  
Flow Sensors ◽  
Novel Approach

AbstractA novel approach for automated high throughput NMR spectroscopy with improved mass-sensitivity is accomplished by integrating microfluidic technologies and micro-NMR resonators. A flow system is utilized to transport a sample of interest from outside the NMR magnet through the NMR detector, circumventing the relatively vast dead volume in the supplying tube by loading a series of individual sample plugs separated by an immiscible fluid. This dual-phase flow demands a real-time robust sensing system to track the sample position and velocities and synchronize the NMR acquisition. In this contribution, we describe an NMR probe head that possesses a microfluidic system featuring: (i) a micro saddle coil for NMR spectroscopy and (ii) a pair of interdigitated capacitive sensors flanking the NMR detector for continuous position and velocity monitoring of the plugs with respect to the NMR detector. The system was successfully tested for automating flow-based measurement in a 500 MHz NMR system, enabling high resolution spectroscopy and NMR sensitivity of 2.18 nmol s1/2 with the flow sensors in operation. The flow sensors featured sensitivity to an absolute difference of 0.2 in relative permittivity, enabling distinction between most common solvents. It was demonstrated that a fully automated NMR measurement of nine individual 120 μL samples could be done within 3.6 min or effectively 15.3 s per sample.

scholarly journals Probing Be star disks: new insights from Hα spectroscopy and detailed numerical models

2010 ◽  
Vol 6 (S272) ◽  
pp. 398-399 ◽  
Author(s):  
Carol E. Jones ◽  
Christopher Tycner ◽  
Jessie Silaj ◽  
Ashly Smith ◽  
T. A. Aaron Sigut
Keyword(s):  
High Resolution ◽  
Numerical Models ◽  
Analytical Tool ◽  
High Resolution Spectroscopy ◽  
Be Stars ◽  
Line Shapes ◽  
Physical Conditions ◽  
Temperature Distributions ◽  
Inclination Angles ◽  
Be Star

AbstractHα high resolution spectroscopy combined with detailed numerical models is used to probe the physical conditions, such as density, temperature, and velocity of Be star disks. Models have been constructed for Be stars over a range in spectral types and inclination angles. We find that a variety of line shapes can be obtained by keeping the inclination fixed and changing density alone. This is due to the fact that our models account for disk temperature distributions self-consistently from the requirement of radiative equilibrium. A new analytical tool, called the variability ratio, was developed to identify emission-line stars at particular stages of variability. It is used in this work to quantify changes in the Hα equivalent widths for our observed spectra.

scholarly journals Effects of fast rotation on the wind of Luminous Blue Variables

2010 ◽  
Vol 6 (S272) ◽  
pp. 56-61
Author(s):  
Jose H. Groh
Keyword(s):  
Near Infrared ◽  
Rotational Velocity ◽  
Spectral Lines ◽  
High Resolution Spectroscopy ◽  
Luminous Blue Variables ◽  
Eta Carinae ◽  
Fast Rotation ◽  
Long Baseline ◽  
Infrared Interferometry ◽  
Fast Rotating

AbstractWhile theoretical studies have long suggested a fast-rotating nature of Luminous Blue Variables (LBVs), observational confirmation of fast rotation was not detected until recently. Here I discuss the diagnostics that have allowed us to constrain the rotational velocity of LBVs: broadening of spectral lines and latitude-dependent variations of the wind density structure. While rotational broadening can be directly detected using high-resolution spectroscopy, long-baseline near-infrared interferometry is needed to directly measure the shape of the latitude-dependent photosphere that forms in a fast-rotating star. In addition, complex 2-D radiative transfer models need to be employed if one's goal is to constrain rotational velocities of LBVs. Here I illustrate how the above methods were able to constrain the rotational velocities of the LBVs AG Carinae, HR Carinae, and Eta Carinae.

scholarly journals Mid and Near-Infrared Reflection Spectral Database of Natural Organic Materials in the Cultural Heritage Field

2018 ◽  
Vol 2018 ◽  
pp. 1-16 ◽  
Author(s):  
Claudia Invernizzi ◽  
Tommaso Rovetta ◽  
Maurizio Licchelli ◽  
Marco Malagodi
Keyword(s):  
Near Infrared ◽  
Organic Materials ◽  
Protective Coatings ◽  
Total Reflection ◽  
Reflection Mode ◽  
Novel Approach ◽  
Infrared Reflection ◽  
Detailed Interpretation ◽  
Materials Used ◽  
Spectral Database

This study presents mid and near-infrared (7500-375 cm−1) total reflection mode spectra of several natural organic materials used in artworks as binding media, consolidants, adhesives, or protective coatings. A novel approach to describe and interpret reflectance bands as well as calculated absorbance after Kramers-Kronig transformation (KKT) is proposed. Transflection mode spectra have represented a valuable support both to study the distorted reflectance bands and to validate the applicability and usefulness of the KK correction. The aim of this paper is to make available to scientists and conservators a comprehensive infrared reflection spectral database, together with its detailed interpretation, as a tool for the noninvasive identification of proteins, lipids, polysaccharides, and resins by means of portable noncontact FTIR spectrometers.

scholarly journals Multi-Wavelength High-Resolution Spectroscopy for Exoplanet Detection: Motivation, Instrumentation and First Results

Geosciences ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 289 ◽  
Author(s):  
Serena Benatti
Keyword(s):  
High Resolution ◽  
Near Infrared ◽  
Giant Planet ◽  
High Resolution Spectroscopy ◽  
M Dwarfs ◽  
Low Mass Stars ◽  
First Results ◽  
Multi Wavelength ◽  
Low Mass ◽  
Rocky Planets

Exoplanet research has shown an incessant growth since the first claim of a hot giant planet around a solar-like star in the mid-1990s. Today, the new facilities are working to spot the first habitable rocky planets around low-mass stars as a forerunner for the detection of the long-awaited Sun-Earth analog system. All the achievements in this field would not have been possible without the constant development of the technology and of new methods to detect more and more challenging planets. After the consolidation of a top-level instrumentation for high-resolution spectroscopy in the visible wavelength range, a huge effort is now dedicated to reaching the same precision and accuracy in the near-infrared. Actually, observations in this range present several advantages in the search for exoplanets around M dwarfs, known to be the most favorable targets to detect possible habitable planets. They are also characterized by intense stellar activity, which hampers planet detection, but its impact on the radial velocity modulation is mitigated in the infrared. Simultaneous observations in the visible and near-infrared ranges appear to be an even more powerful technique since they provide combined and complementary information, also useful for many other exoplanetary science cases.

scholarly journals Anharmonicity and Spectra–Structure Correlations in MIR and NIR Spectra of Crystalline Menadione (Vitamin K3)

Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 6779
Author(s):  
Krzysztof B. Beć ◽  
Justyna Grabska ◽  
Christian W. Huck ◽  
Sylwester Mazurek ◽  
Mirosław A. Czarnecki
Keyword(s):  
Single Molecule ◽  
Near Infrared ◽  
Structural Information ◽  
Molecular System ◽  
Theoretical Calculations ◽  
Vitamin K3 ◽  
Structure Correlations ◽  
Mir Spectra ◽  
Combination Bands ◽  
The Relationship

Mid-infrared (MIR) and near-infrared (NIR) spectra of crystalline menadione (vitamin K3) were measured and analyzed with aid of quantum chemical calculations. The calculations were carried out using the harmonic approach for the periodic model of crystal lattice and the anharmonic DVPT2 calculations applied for the single molecule model. The theoretical spectra accurately reconstructed the experimental ones permitting for reliable assignment of the MIR and NIR bands. For the first time, a detailed analysis of the NIR spectrum of a molecular system based on a naphthoquinone moiety was performed to elucidate the relationship between the chemical structure of menadione and the origin of the overtones and combination bands. In addition, the importance of these bands during interpretation of the MIR spectrum was demonstrated. The overtones and combination bands contribute to 46.4% of the total intensity of menadione in the range of 3600–2600 cm−1. Evidently, these bands play a key role in shaping of the C-H stretching region of MIR spectrum. We have shown also that the spectral regions without fundamentals may provide valuable structural information. For example, the theoretical calculations reliably reconstructed numerous overtones and combination bands in the 4000–3600 and 2800–1800 cm−1 ranges. These results, provide a comprehensive origin of the fundamentals, overtones and combination bands in the NIR and MIR spectra of menadione, and the relationship of these spectral features with the molecular structure.

scholarly journals On the synergy between Ariel and ground-based high-resolution spectroscopy

2022 ◽  
Author(s):  
Gloria Guilluy ◽  
Alessandro Sozzetti ◽  
Paolo Giacobbe ◽  
Aldo S. Bonomo ◽  
Giuseppina Micela
Keyword(s):  
High Resolution ◽  
Near Infrared ◽  
Major Axis ◽  
High Resolution Spectroscopy ◽  
Correlation Technique ◽  
Temperature Structure ◽  
Low Resolution ◽  
Semi Major Axis ◽  
Species Discovery ◽  
Orbital Parameters

AbstractSince the first discovery of an extra-solar planet around a main-sequence star, in 1995, the number of detected exoplanets has increased enormously. Over the past two decades, observational instruments (both onboard and on ground-based facilities) have revealed an astonishing diversity in planetary physical features (i. e. mass and radius), and orbital parameters (e.g. period, semi-major axis, inclination). Exoplanetary atmospheres provide direct clues to understand the origin of these differences through their observable spectral imprints. In the near future, upcoming ground and space-based telescopes will shift the focus of exoplanetary science from an era of “species discovery” to one of “atmospheric characterization”. In this context, the Atmospheric Remote-sensing Infrared Exoplanet Large (Ariel) survey, will play a key role. As it is designed to observe and characterize a large and diverse sample of exoplanets, Ariel will provide constraints on a wide gamut of atmospheric properties allowing us to extract much more information than has been possible so far (e.g. insights into the planetary formation and evolution processes). The low resolution spectra obtained with Ariel will probe layers different from those observed by ground-based high resolution spectroscopy, therefore the synergy between these two techniques offers a unique opportunity to understanding the physics of planetary atmospheres. In this paper, we set the basis for building up a framework to effectively utilise, at near-infrared wavelengths, high-resolution datasets (analyzed via the cross-correlation technique) with spectral retrieval analyses based on Ariel low-resolution spectroscopy. We show preliminary results, using a benchmark object, namely HD 209458 b, addressing the possibility of providing improved constraints on the temperature structure and molecular/atomic abundances.

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