scholarly journals Investigating the cheletropic reaction between sulfur dioxide and butadiene-containing linkers in UiO-66

2018 ◽  
Vol 96 (2) ◽  
pp. 139-143 ◽  
Author(s):  
Jinfeng Zhang ◽  
Jared B. DeCoste ◽  
Michael J. Katz
Keyword(s):  
Carboxylic Acid ◽  
Sulfur Dioxide ◽  
Solvothermal Method ◽  
Metal Organic Framework ◽  
Chemical Change ◽  
Constant Flow ◽  
Muconic Acid ◽  
Metal Organic ◽  
Organic Framework

UiO-66 and a muconic acid functionalized derivative of UiO-66 (UiO-66-MA) were synthesized via the solvothermal method to determine if the muconic acid could undergo a cheletropic reaction in the presence of sulfur dioxide inside the metal-organic framework (MOF). Both MOFs were exposed to a constant flow of sulfur dioxide, and UiO-66-MA was observed to take up three times more sulfur dioxide than unfunctionalized UiO-66. Despite the improved uptake of sulfur dioxide in UiO-66-MA, NMR and IR data indicate that no chemical change occurred to the muconic acid indicating that a cheletropic reaction did not occur. We thus propose that the increased adsorption is due to either an interaction between the sulfur dioxide and unbound carboxylic acid from the muconic acid or a favourable interaction between the butadiene of muconic acid and sulfur dioxide.

Covalent-coordination tandem functionalization of metal-organic framework (UiO-66) as a hybrid probe for luminescence detection of trans, trans-muconic acid as a biomarker of benzene and Fe3+

The Analyst ◽  
2021 ◽  
Author(s):  
Jie Min ◽  
Xiang-Long Qu ◽  
Bing Yan
Keyword(s):  
Hybrid Material ◽  
Metal Organic Framework ◽  
Luminescent Properties ◽  
Muconic Acid ◽  
Luminescence Detection ◽  
Metal Organic ◽  
Organic Framework

By means of post-synthetic treatment on the UiO-66 derivative with -SO3H, a novel luminescent hybrid material named Tb3+@UiO-66-SO3H has been prepared simply and efficiently. Given its wonderful luminescent properties like...

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization

2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

A zwitterionic metal–organic framework with free carboxylic acid sites that exhibits enhanced hydrogen adsorption energies

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9408 ◽  
Author(s):  
Marianne B. Lalonde ◽  
Rachel B. Getman ◽  
Jeong Yong Lee ◽  
John M. Roberts ◽  
Amy A. Sarjeant ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Acid Sites ◽  
Metal Organic ◽  
Adsorption Energies ◽  
Organic Framework

A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

CrystEngComm ◽  
2019 ◽  
Vol 21 (24) ◽  
pp. 3679-3685 ◽  
Author(s):  
Donghai Sheng ◽  
Ying Zhang ◽  
Yang Han ◽  
Guang Xu ◽  
Qingxiang Song ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Uptake Capacity ◽  
High Affinity ◽  
Metal Organic ◽  
Organic Framework

A new metal–organic framework {[Zn2(Htzba)2(dmtrz)]·(CH3)2NH}n (1) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity.

In situ solvothermal growth of highly oriented Zr-based metal organic framework UiO-66 film with monocrystalline layer

CrystEngComm ◽  
2015 ◽  
Vol 17 (18) ◽  
pp. 3422-3425 ◽  
Author(s):  
M. Miyamoto ◽  
S. Kohmura ◽  
H. Iwatsuka ◽  
Y. Oumi ◽  
S. Uemiya
Keyword(s):  
Solvothermal Method ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A highly oriented UiO-66 film, with a monocrystalline layer, was successfully prepared by the solvothermal method.

Functionalized Defects through Solvent-Assisted Linker Exchange: Synthesis, Characterization, and Partial Postsynthesis Elaboration of a Metal–Organic Framework Containing Free Carboxylic Acid Moieties

2015 ◽  
Vol 54 (4) ◽  
pp. 1785-1790 ◽  
Author(s):  
Olga Karagiaridi ◽  
Nicolaas A. Vermeulen ◽  
Rachel C. Klet ◽  
Timothy C. Wang ◽  
Peyman Z. Moghadam ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

Highly Selective and Reversible Sulfur Dioxide Adsorption on a Microporous Metal–Organic Framework via Polar Sites

2019 ◽  
Vol 11 (11) ◽  
pp. 10680-10688 ◽  
Author(s):  
Yan Zhang ◽  
Peixin Zhang ◽  
Weikang Yu ◽  
Jinghan Zhang ◽  
Jiejing Huang ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A zinc(II) metal–organic framework with a novel topology formed from 4,4′,4′′-nitrilotribenzoate and 4,4′-bipyridine ligands

2015 ◽  
Vol 71 (9) ◽  
pp. 799-803 ◽  
Author(s):  
Meng Zhao ◽  
Jian Su ◽  
Jun Zhang ◽  
Jie-Ying Wu ◽  
Yu-Peng Tian
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
Solvothermal Method ◽  
Metal Organic Framework ◽  
Topological Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Paddle Wheel ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework with a novel topology, poly[sesqui(μ2-4,4′-bipyridine)bis(dimethylformamide)bis(μ4-4,4′,4′′-nitrilotribenzoato)trizinc(II)], [Zn3(C21H12NO6)2(C10H8N2)1.5(C3H7NO)2]n, was obtained by the solvothermal method using 4,4′,4′′-nitrilotribenzoic acid and 4,4′-bipyridine (bipy). The structure, determined by single-crystal X-ray diffraction analysis, possesses three kinds of crystallographically independent ZnIIcations, as well as binuclear Zn2(COO)4(bipy)2paddle-wheel clusters, and can be reduced to a novel topology of a (3,3,6)-connected 3-nodal net, with the Schläfli symbol {5.62}4{52.6}4{58.87} according to the topological analysis.

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