Colloidal synthesis of Pt–In bimetallic nanoparticles for propane dehydrogenation

2017 ◽  
Vol 95 (11) ◽  
pp. 1135-1140 ◽  
Author(s):  
Xuchun Wang ◽  
Di Yang ◽  
Yong Xu ◽  
Jun Zhong ◽  
Qiao Zhang

Recently, Pt-based bimetallic nanoparticles have drawn much attention because of their great catalytic performance and wide applications in diverse fields. In this work, we report that bimetallic Pt–In nanoparticles with uniform size distribution and controllable composition can be synthesized through a one-step, facile colloidal approach. Various characterization tools such as XRD, TEM, XPS, and synchrotron techniques have been used to characterize the as-obtained nanoparticles. It is demonstrated that the Pt and In elements are homogeneously distributed in the whole nanoparticle. The bimetallic Pt–In nanoparticles have shown great catalytic performance, including high activity, high selectivity, and high stability, for the propane dehydrogenation reaction to produce propene, one of the most important chemicals. The excellent catalytic performance makes Pt–In bimetallic nanoparticles promising catalysts in future industrial application.

2018 ◽  
Vol 42 (8) ◽  
pp. 419-423
Author(s):  
Li-Jie Zhang ◽  
Xian Yao ◽  
Ying-xin Sun ◽  
Jia-wei Zhang ◽  
Chun Cai

Pd–Ni bimetallic nanoparticles (BMNPs) supported on ZrO2 were prepared by an impregnation–reduction method. The BMNPs showed excellent catalytic performance in Suzuki carbon–carbon cross-coupling reactions and almost quantitative conversion of the substrates was obtained under mild conditions in the absence of ligand. The excellent catalytic performance of the bimetallic catalyst could be a result of the synergistic effect between the two metal components. The catalyst showed outstanding recyclability during the reaction process; no obvious decrease in catalytic performance was observed after five cycles.


RSC Advances ◽  
2015 ◽  
Vol 5 (29) ◽  
pp. 23080-23085 ◽  
Author(s):  
Peigen Zhang ◽  
Jian Zhang ◽  
Anjian Xie ◽  
Shikuo Li ◽  
Jiming Song ◽  
...  

A one step method has been developed for the fabrication of hierarchical flower-like bismuth tungstate (Bi2WO6) hollow spheres via a solvothermal process.


Nanoscale ◽  
2016 ◽  
Vol 8 (32) ◽  
pp. 14932-14942 ◽  
Author(s):  
Sunjie Ye ◽  
Felix Benz ◽  
May C. Wheeler ◽  
Joseph Oram ◽  
Jeremy J. Baumberg ◽  
...  

2012 ◽  
Vol 629 ◽  
pp. 381-385 ◽  
Author(s):  
Jun Hui Li ◽  
Zhong Hua Hu ◽  
Ya Nan Wang ◽  
Hao Xiang ◽  
Zhi Rong Zhu

Methylation of toluene with methanol to synthesize p-Xylene was performed in a fixed-bed reactor. HZSM-5 zeolite as a catalyst was prepared by modification with La2O3. In addition, effect of steam treatment for La2O3-modified HZSM-5 on its catalytic performance was investigated as well. The properties of as-prepared catalysts were characterized by XRD, BET and NH3-TPD. The results indicate that modification with La2O3can narrow the size of HZSM-5 channel effectively. And more than 90% selectivity of p-Xylene is obtained over HZSM-5 with loading of 24% and 30% La2O3. However, above La2O3-modified HZSM-5 with high-selectivity exhibit a poor stability for time on-stream of the methylation reaction. Steam treatment of La2O3-modified HZSM-5 can improve its stability and shape selectivity, decreasing by-products. These effects can be attributed to distortion & narrowing of HZSM-5 channel and reduction of HZSM-5 strong Bronsted acid sites during steam treatment. As a result, the excellent catalytic performance is obtained over 24.0% La2O3-modified HZSM-5 by steam treatment at 773 K for 1.0 h, being 23% conversion of toluene, 93% selectivity of p-Xylene during time on-stream.


RSC Advances ◽  
2017 ◽  
Vol 7 (74) ◽  
pp. 47104-47110 ◽  
Author(s):  
Yuan Chen ◽  
Minggui Wang ◽  
Long Zhang ◽  
Yan Liu ◽  
Jie Han

Poly(o-aminothiophenol)-stabilized Pd nanoparticles have been obtained through a facile one-step route, which exhibit excellent catalytic performance in Suzuki cross-coupling reactions.


ACS Catalysis ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 3349-3355 ◽  
Author(s):  
Jie Liu ◽  
Yuanyuan Yue ◽  
Hongyang Liu ◽  
Zhijian Da ◽  
Changcheng Liu ◽  
...  

2020 ◽  
Vol 22 (5) ◽  
pp. 1710-1719
Author(s):  
Dongjie Li ◽  
Suqin Liu ◽  
Guanying Ye ◽  
Weiwei Zhu ◽  
Kuangmin Zhao ◽  
...  

NixFe3−xO4/Ni hybrid nanosheet arrays have been directly fabricated on different substrates via template-free and annealing-free one-step electrodeposition, which show excellent catalytic performance for the oxygen evolution reaction.


Nanoscale ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 6776-6784
Author(s):  
Qinxi Liu ◽  
Jianpei Xing ◽  
Zhou Jiang ◽  
Xue Jiang ◽  
Yi Wang ◽  
...  

The unique bonding feature of TM2Ps contributes to their high stability, excellent catalytic performance, good ductility, and abundant magnetic properties.


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