Synthesis and Self-Assembly of 9,9'-Spirobifluorene-2,2',7,7'-tetracarboxylic Acid and Its Tetraamide. Non-Catenated Formation of Achiral Grid Layers with Large Chiral Pores

2006 ◽  
Vol 71 (2) ◽  
pp. 139-154 ◽  
Author(s):  
Petr Holý ◽  
Martin Havlík ◽  
Miloš Tichý ◽  
Jiří Závada ◽  
Ivana Císařová
Keyword(s):  
Self Assembly ◽  
Crystallographic Analysis ◽  
Tetracarboxylic Acid

The title tetrasubstituted spirobifluorenes 3a, 3b have been designed to serve as convenient achiral tectons for self-assembly of 2D layers with large chiral pores. The underlying stereochemical concept has been confirmed by the results of crystallographic analysis of tetraacid 3a. Self-assembly of isosteric tetraamide 3b led to markedly different results.

scholarly journals X-Ray Crystallographic Analysis, EPR Studies, and Computational Calculations of a Cu(II) Tetramic Acid Complex

2017 ◽  
Vol 2017 ◽  
pp. 1-10
Author(s):  
Dimitrios Matiadis ◽  
Dimitrios Tsironis ◽  
Valentina Stefanou ◽  
Olga Igglessi–Markopoulou ◽  
Vickie McKee ◽  
...  
Keyword(s):  
Self Assembly ◽  
Copper Ions ◽  
Copper Ion ◽  
Spectroscopic Properties ◽  
Crystallographic Analysis ◽  
Computational Techniques ◽  
Tetramic Acid ◽  
Acid Complex ◽  
X Ray ◽  
Computational Calculations

In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of symmetry, with each ligand ion coordinated to two copper ions, forming a 2D sheet. Moreover, the EPR spectroscopic properties of the Cu(II) tetramic acid complex were also explored and discussed. Finally, a computational approach was performed in order to obtain a detailed and precise insight of product structures and properties. It is hoped that this study can enrich the field of functional supramolecular systems, giving place to the formation of coordination-driven self-assembly architectures.

Shape-persistent macrocycles — Self-assembly reactions and characterization by hyperpolarized 129Xe NMR spectroscopy**In memory of Professor Michael M. Pollard.

2011 ◽  
Vol 89 (10) ◽  
pp. 1264-1276 ◽  
Author(s):  
Katie Campbell ◽  
Kristopher J. Ooms ◽  
Michael J. Ferguson ◽  
Peter J. Stang ◽  
Roderick E. Wasylishen ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Self Assembly ◽  
Chemical Shifts ◽  
Crystallographic Analysis ◽  
Temperature Dependent ◽  
129Xe Nmr ◽  
Spectroscopic Analyses ◽  
Conjugated Macrocycles ◽  
Hyperpolarized 129Xe ◽  
Solvent Molecules

The use of three shape-persistent, conjugated macrocycles 2a–2c as ligands for self-assembly reactions is described. The macrocycles have been characterized through a combination of spectroscopic analyses and, for compounds 2b and 2c, X-ray crystallographic analysis. Whereas the reaction of 2a with the cis-Pt(II) species 3 successfully provides the porous solid 4a, the analogous reaction of 2b and 2c with 3 leads only to mixtures of products. The application of continuous-flow hyperpolarized 129Xe NMR spectroscopy to investigate the solid-state pores of macrocycles 2b and 2c and the supramolecular complex 4a as a function of temperature is described. All three species show permanent porosity upon removal of co-crystallized solvent molecules. Using trends in the 129Xe chemical shifts and temperature-dependent dynamics of Xe atoms in the solids, information is obtained on the nature of the pores in these systems. Using the 129Xe NMR data for complex 4a, the effective heat of adsorption (ΔHads) was calculated to be ~29 kJ mol–1.

Self-assembly of Zn(salphen) complexes: Steric regulation, stability studies and crystallographic analysis revealing an unexpected dimeric 3,3′-t-Bu-substituted Zn(salphen) complex

2010 ◽  
Vol 39 (19) ◽  
pp. 4541 ◽  
Author(s):  
Marta Martínez Belmonte ◽  
Sander J. Wezenberg ◽  
Robert M. Haak ◽  
Daniele Anselmo ◽  
Eduardo C. Escudero-Adán ◽  
...  
Keyword(s):  
Self Assembly ◽  
Crystallographic Analysis ◽  
Stability Studies

Mixing behavior of p-terphenyl-3,5,3′,5′-tetracarboxylic acid with trimesic acid at the solid–liquid interface

2021 ◽  
Author(s):  
Wei Li ◽  
Jianbin Chen ◽  
Chengdong Zhang ◽  
Yudie Li ◽  
Lijia Wan ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Solid Surface ◽  
Self Assembly ◽  
Liquid Interface ◽  
Tetracarboxylic Acid ◽  
Trimesic Acid ◽  
Mixing Behavior ◽  
Functional Patterns ◽  
Solid Liquid Interface ◽  
Solid Liquid

The molecular self-assembly of carboxylic acid molecules on a solid surface plays an important role in understanding the nanoscale-precision construction of functional patterns. In this study, the mixing behavior of...

Synthesis of Perylene-Containing Polyimides for Non-Covalent Functionalization of Graphene by Self-Assembly

2012 ◽  
Vol 534 ◽  
pp. 118-121 ◽  
Author(s):  
Wen Jie He ◽  
Cheng En He ◽  
Ren Gui Peng ◽  
Ying Kui Yang
Keyword(s):  
High Temperature ◽  
Polymer Composites ◽  
Graphite Oxide ◽  
Self Assembly ◽  
Basal Plane ◽  
Graphene Nanosheets ◽  
Functionalized Graphene ◽  
Tetracarboxylic Acid ◽  
Covalent Functionalization ◽  
Thermal Polycondensation

A perylene-containing polyimide (PPI) has been successfully synthesized by thermal polycondensation of perylene-3,4,9,10-tetracarboxylic acid dianhydride and 2,2′-(ethylenedioxy)-diethylamine at high temperature. The as-prepared graphite oxide was ultrasonically exfoliated followed by solvothermal-reduction in N-methyl-2-pyrrolidone in the presence of PPI, yielding PPI-functionalized graphene nanosheets. It was found that PPI chains were non-covalently attached to the conjugated basal plane of graphene to form self-assembly nanostructures by π–π stacking. The present work may open a new route for the fabrication of polymer composites containing graphene.

Molecular capsule constructed by multiple hydrogen bonds: self-assembly of cavitand tetracarboxylic acid with 2-aminopyrimidine

2000 ◽  
pp. 41-42 ◽  
Author(s):  
Kenji Kobayashi ◽  
Toshiaki Shirasaka ◽  
Ernst Horn ◽  
Naomichi Furukawa ◽  
Kentaro Yamaguchi ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Self Assembly ◽  
Tetracarboxylic Acid ◽  
Molecular Capsule ◽  
Multiple Hydrogen Bonds

Self-assembly of water soluble perylene tetracarboxylic acid with metal cations: Selective fluorescence sensing of Cu2+ and Pb2+ ions in paper strips, zebrafish and yeast

2018 ◽  
Vol 203 ◽  
pp. 42-49 ◽  
Author(s):  
S. Sowmiyha ◽  
Vadivel Vinod Kumar ◽  
Jayaraman Pitchaimani ◽  
Vedichi Madhu ◽  
Raman Thiagarajan ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Cations ◽  
Water Soluble ◽  
Tetracarboxylic Acid ◽  
Fluorescence Sensing

Controllable Fabrication of Layer Structures by Self-Assembled Perylene Derivative

2012 ◽  
Vol 554-556 ◽  
pp. 39-42
Author(s):  
Chun Hua Liu ◽  
Yun Zhi Xie ◽  
Yong Dong Li ◽  
Xun Li ◽  
Yi Bao Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
Layer Structure ◽  
Stacking Interactions ◽  
Intermolecular Hydrogen Bonding ◽  
Tetracarboxylic Acid ◽  
High Concentration ◽  
Force Microscopy ◽  
Layer Structures ◽  
Atom Force Microscopy ◽  
Controllable Fabrication

The compound of perylene-3,4,9,10-tetracarboxylic acid (PTCA) has been synthesized and characterized. By varying the concentration, it can be used to modulate the supramolecular self-assembly morphologies. Atom force microscopy (AFM) images show that the nano-layer structure will be obtained in relatively high concentration. This structure mainly depends on the intermolecular hydrogen-bonding and π–π stacking interactions.

Self-assembly of cavitand tetracarboxylic acid: highly porous packing structure of one-dimensional hydrogen-bonded network

1999 ◽  
Vol 40 (50) ◽  
pp. 8883-8886 ◽  
Author(s):  
Kenji Kobayashi ◽  
Toshiaki Shirasaka ◽  
Ernst Horn ◽  
Naomichi Furukawa
Keyword(s):  
Self Assembly ◽  
Tetracarboxylic Acid ◽  
One Dimensional ◽  
Packing Structure ◽  
Highly Porous ◽  
Hydrogen Bonded
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