Catalyst Selection for Hydrogenation of 1,2-Dihydroacenaphthylene

1998 ◽  
Vol 63 (11) ◽  
pp. 1945-1953 ◽  
Author(s):  
Jiří Hanika ◽  
Karel Sporka ◽  
Petr Macoun ◽  
Vladimír Kysilka
Keyword(s):  
Activation Energy ◽  
Nickel Catalyst ◽  
Palladium Catalyst ◽  
Active Component ◽  
Reaction Order ◽  
Nickel Catalysts ◽  
Practical Application ◽  
Repeated Use ◽  
Selection For ◽  
Catalyst Selection

The activity of ruthenium, palladium, and nickel catalysts for the hydrogenation of 1,2-dihydroacenaphthylene in cyclohexane solution was studied at temperatures up to 180 °C and pressures up to 8 MPa. The GC-MS technique was used to identify most of the perhydroacenaphthylene stereoisomers, whose fractions in the product were found dependent on the nature of the active component of the catalyst. The hydrogenation was fastest on the palladium catalyst (3% Pd/C). The nickel catalyst Ni-NiO/Al2O3, which is sufficiently active also after repeated use, can be recommended for practical application. The activation energy of 1,2-dihydroacenaphthylene hydrogenation using this catalyst is 17 kJ/mol, the reaction order with respect to hydrogen is unity.

Hydrogenation of methylacetylene. III. The reaction of methylacetylene with hydrogen catalyzed by nickel, copper, and their alloys

1968 ◽  
Vol 46 (4) ◽  
pp. 623-633 ◽  
Author(s):  
R. S. Mann ◽  
K. C. Khulbe
Keyword(s):  
Activation Energy ◽  
Nickel Catalyst ◽  
Hydrogen Pressure ◽  
Constant Volume ◽  
Temperature Dependent ◽  
Nickel Copper ◽  
Wide Range ◽  
Initial Hydrogen Pressure

The reaction between methylacetylene and hydrogen over unsupported nickel, copper, and their alloys has been investigated in a static constant volume system between 20 and 220 °C for a wide range of reactant ratios. The order of reaction with respect to hydrogen was one and nearly independent of temperature. While the order of reaction with respect to methylacetylene over nickel catalyst was slightly negative and temperature dependent, it was always positive and nearly independent of temperature for copper and copper-rich alloys. Selectivity was independent of initial hydrogen pressure for nickel and copper only; for others it decreased rapidly with increasing hydrogen pressure. The overall activation energy varied between 9 and 21.2 kcal/g mole. Selectivity and extent of polymerization increased with increasing amount of copper in the alloy.

Some Guidance for Hull Form Selection for SWATH Ships

1988 ◽  
Vol 25 (04) ◽  
pp. 239-252
Author(s):  
G. Robed Lamb
Keyword(s):  
High Speed ◽  
Early Stage ◽  
The United States ◽  
Practical Application ◽  
Hull Form ◽  
Stage Design ◽  
Seakeeping Performance ◽  
The World ◽  
Selection For ◽  
Early Stage Design

Even though in 1987 there were only a dozen SWATH (smali-waterplane-area twin-hull) craft and ships afloat around the world, word of their markedly superior seakeeping performance is spreading rapidly. The number of SWATH vessels is likely to double within five years. As in many other areas of technology, the United States and Japan are the acknowledged leaders in the development and practical application of the SWATH concept. This paper reviews the characteristics of existing SWATH craft and ships from the standpoint of the stated seakeeping objective. Hull form differences between four SWATH craft and ships, including the Navy's SSP Kairnalino, are analyzed and interpreted. Important considerations for the early-stage design of a SWATH ship are discussed. Differences in the range of feasible hull form geometries for coastal areas and unrestricted ocean operations, and for low-speed versus moderately high-speed applications, are pointed out.

Dynamic Model of Rapeseed Oil Hydrolysis Reaction in Sub-Critical Water

2013 ◽  
Vol 860-863 ◽  
pp. 510-513 ◽  
Author(s):  
Yi Zhe Li ◽  
Hua Wang ◽  
Gui Rong Bao
Keyword(s):  
Activation Energy ◽  
Reaction Time ◽  
Dynamic Model ◽  
Rapeseed Oil ◽  
Reaction Order ◽  
Volume Ratio ◽  
Hydrolysis Reaction ◽  
Water Volume ◽  
Oil Water ◽  
Oil Hydrolysis

Experiments of Rapeseed Oil Hydrolysis Reaction in Sub-Critical Water (250-300°C, 5-60min) are Conducted in this Paper. Results Show that the Best Conditions for Rapeseed Oil Hydrolysis are Reaction Temperature 290°C, Oil-Water Volume Ratio 1:3, Reaction Time 40min, and Conversion Rate 98.9%. Meanwhile, Kinetic Analysis of this Hydrolysis Reaction is Presented. we Learn that Hydrolysis Reaction Order is 0.7778, Activation Energy is 55.34kJ/mol and the Dynamic Model is .

ChemInform Abstract: Catalyst Selection for Metal Carbene Transformations

ChemInform ◽  
2001 ◽  
Vol 32 (20) ◽  
pp. no-no
Author(s):  
Daren J. Timmons ◽  
Michael P. Doyle
Keyword(s):  
Selection For ◽  
Catalyst Selection

scholarly journals Elastomeric polyethylenes accessible via ethylene homo-polymerization using an unsymmetrical α-diimino-nickel catalyst

2017 ◽  
Vol 8 (18) ◽  
pp. 2785-2795 ◽  
Author(s):  
Xinxin Wang ◽  
Linlin Fan ◽  
Yanping Ma ◽  
Cun-Yue Guo ◽  
Gregory A. Solan ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Nickel Catalyst ◽  
Elastic Recovery ◽  
Nickel Catalysts ◽  
High Thermal Stability ◽  
Elongation At Break ◽  
New Family ◽  
High Elongation

Elastomeric polyethylenes, with good elastic recovery and high elongation at break, have been prepared using a new family of unsymmetrical α-diimino-nickel catalysts that display high activities and high thermal stability.

scholarly journals Analysis of Decision Support System Based on 2-Tuple Spherical Fuzzy Linguistic Aggregation Information

2019 ◽  
Vol 10 (1) ◽  
pp. 276
Author(s):  
Saleem Abdullah ◽  
Omar Barukab ◽  
Muhammad Qiyas ◽  
Muhammad Arif ◽  
Sher Afzal Khan
Keyword(s):  
Decision Making ◽  
Weighted Average ◽  
Multiple Attribute Decision Making ◽  
Aggregation Operators ◽  
Comparison Analysis ◽  
Practical Application ◽  
Multiple Attribute ◽  
Ordered Weighted Average ◽  
Selection For ◽  
Fuzzy Linguistic

The aim of this paper is to propose the 2-tuple spherical fuzzy linguistic aggregation operators and a decision-making approach to deal with uncertainties in the form of 2-tuple spherical fuzzy linguistic sets. 2-tuple spherical fuzzy linguistic operators have more flexibility than general fuzzy set. We proposed a numbers of aggregation operators, namely 2-tuple spherical fuzzy linguistic weighted average, 2-tuple spherical fuzzy linguistic ordered weighted average, 2-tuple spherical fuzzy linguistic hybrid average, 2-tuple spherical fuzzy linguistic weighted geometric, 2-tuple spherical fuzzy linguistic ordered geometric, and 2-tuple spherical fuzzy linguistic hybrid geometric operators. The distinguishing feature of these proposed operators is studied. At that point, we have used these operators to design a model to deal with multiple attribute decision-making issues under the 2-tuple spherical fuzzy linguistic information. Then, a practical application for best company selection for feeds is given to prove the introduced technique and to show its practicability and effectiveness. Besides this, a systematic comparison analysis with other existent methods is conducted to reveal the advantage of our method. Results indicate that the proposed method is suitable and effective for decision making problems.

Catalyst selection for a rep-pulsed high-power self-sustained discharge CO 2 laser

1996 ◽  
Author(s):  
Paul Lewis ◽  
John Fortino ◽  
Paul F. Gozewski ◽  
Francisco Faria-e-Maia ◽  
Anthony Doucette ◽  
...  
Keyword(s):  
High Power ◽  
Selection For ◽  
Sustained Discharge ◽  
Catalyst Selection

scholarly journals Easy Method for the Transformation of Levulinic Acid into Gamma-Valerolactone Using a Nickel Catalyst Derived from Nanocasted Nickel Oxide

Materials ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 2918 ◽  
Author(s):  
Sanchis ◽  
García ◽  
Dejoz ◽  
Vázquez ◽  
Llopis ◽  
...  
Keyword(s):  
High Temperature ◽  
Nickel Oxide ◽  
Hydrothermal Method ◽  
Nickel Catalyst ◽  
Levulinic Acid ◽  
Nickel Catalysts ◽  
Metallic Nickel ◽  
Easy Method ◽  
High Temperature Water ◽  
Temperature Water

Different nickel catalysts have been tested for the transformation of levulinic acid into γ-valerolactone using an easy hydrothermal method, taking advantage of the properties of the high temperature water. A metallic nickel catalyst derived from NiO synthesized by a nanocasting procedure can achieve a productivity to γ-valerolactone, which is two orders of magnitude higher than that obtained by a commercial nickel catalyst. This nanocasted metallic nickel catalyst has shown bifunctionality as it is capable of activating water as the source for hydrogen and undertaking the further hydrogenation step. In contrast with metallic nickel, nickel oxide has shown to be incapable of transforming levulinic acid into γ-valerolactone.

scholarly journals Kinetic study of wood pyrolysis in presence of metal halides

2014 ◽  
Vol 12 (12) ◽  
pp. 1294-1303 ◽  
Author(s):  
Vladimir Beliy ◽  
Elena Udoratina
Keyword(s):  
Activation Energy ◽  
Lewis Acids ◽  
Alkaline Earth ◽  
Reaction Order ◽  
Earth Metal ◽  
Inorganic Salts ◽  
Alkaline Earth Metal ◽  
Metal Halides ◽  
Wood Pyrolysis ◽  
Kinetics Of

AbstractThe purpose of this work was to study the kinetics of wood pyrolysis in the presence of inorganic salts, representatives of classes of alkali and alkaline earth metal halides (NaCl, KCl, KBr, CaCl2, BaCl2·2H2O) and Lewis acids (AlCl3·6H2O, FeCl3·6H2O, CuCl2, CuBr2, ZnCl2·1.5H2O, NiCl2·6H2O, SnCl2·2H2O) using TG-DSC. The activity of these catalysts was estimated by the temperature of the beginning of pyrolysis, charcoal yield and kinetic parameters, such as energy of activation and reaction order. Using the Lewis acids as catalysts for pyrolysis leads to a decrease in the temperature of the process beginning and the activation energy. In the presence of other catalysts activation energy does not significantly change. The increase of a seeming reaction order in the presence of Lewis acids possibly is a consequence of complication of the thermodestruction mechanism, with the appearance of new parallel competing stages.

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