Role of Water in Synthesis of Higher Alcohols from CO and H2 over MoS2

1997 ◽  
Vol 62 (1) ◽  
pp. 130-135
Author(s):  
Atanas A. Andreev ◽  
Lubomir S. Mintchev ◽  
Margarita V. Gabrovska
Keyword(s):  
Reaction Mechanism ◽  
Water Gas Shift ◽  
Higher Alcohols ◽  
Water Gas Shift Reaction ◽  
Hydrocarbon Synthesis ◽  
Shift Reaction ◽  
Water Gas ◽  
Synthesis Reactions ◽  
Formate Intermediate

Experimental evidence was found in support of the direct participation of water in synthesis reactions from CO and hydrogen over MoS2 and K/MoS2 through its dissociation to activated OH and H. A reaction mechanism based on a common formate intermediate in alcohol and hydrocarbon synthesis and water-gas shift reaction is proposed.

The role of Pt in α-MoC on the water-gas shift reaction at low temperatures

Joule ◽  
2021 ◽  
Vol 5 (3) ◽  
pp. 521-523
Author(s):  
Tiago J. Goncalves ◽  
Samira Siahrostami
Keyword(s):  
Low Temperatures ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Shift Reaction ◽  
Water Gas

Facet-dependent activity of shape-controlled TiO2 supported Au nanoparticles for water-gas shift reaction†

2022 ◽  
Author(s):  
Yuanting Tang ◽  
Yongjie Chen ◽  
Xiao Liu ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
...  
Keyword(s):  
Au Nanoparticles ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Oxide Interface ◽  
Wgs Reaction ◽  
Dependent Activity ◽  
Shape Controlled ◽  
Shift Reaction ◽  
Water Gas

The bifunctional role of noble metal/oxide interface in the activation of reactants is of vital importance in heterogeneous catalysis of water-gas shift (WGS) reaction. Herein, three types of shape-controlled TiO2...

On the Role of a Cobalt Promoter in a Water-Gas-Shift Reaction on Co-MoS2

2010 ◽  
Vol 114 (39) ◽  
pp. 16669-16676 ◽  
Author(s):  
Yan-Yan Chen ◽  
Mei Dong ◽  
Jianguo Wang ◽  
Haijun Jiao
Keyword(s):  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Shift Reaction ◽  
Water Gas

Role of alkali metal in a highly active Pd/alkali/Fe2O3 catalyst for water gas shift reaction

2013 ◽  
Vol 457 ◽  
pp. 1-11 ◽  
Author(s):  
Ryo Watanabe ◽  
Yuji Sakamoto ◽  
Keisuke Yamamuro ◽  
Sakurako Tamura ◽  
Eiichi Kikuchi ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Highly Active ◽  
Shift Reaction ◽  
Water Gas
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