Application of Cyclic Chronopotentiometry to the Study of Slow Charge Transfer Reactions at the DME and the SMDE

1996 ◽  
Vol 61 (10) ◽  
pp. 1432-1444 ◽  
Author(s):  
Ángela Molina ◽  
Joaquín González ◽  
Carmen Serna

In this work we apply cyclic chronopotentiometry to analyze charge transfer reactions at spherical electrodes, highlighting the influence of electrode curvature and the formation of amalgam on the potential-time response. Moreover, methods are proposed for determining the formal potential and the kinetic parameters of the electrode reaction. Equations obtained for the dropping mercury electrode are transformed to those corresponding to a static mercury drop electrode and a plane electrode.

1990 ◽  
Vol 55 (7) ◽  
pp. 1666-1672 ◽  
Author(s):  
Jaroslav Němec ◽  
Tomáš Loučka

The electrochemical behaviour of europium at the dropping mercury electrode was studied in the medium of 1M-NaClO4, 1M-NaCl, 1M-NaNO3, and 1M-Na2SO4. The curves obtained by Tast polarography and the kinetic parameters (ks, α) for the Eu3+/Eu2+ system in the medium of perchlorate and chloride solutions are in accord with the results published earlier. The kinetic parameters in nitrate and sulphate media are given for the first time. In the medium of nitrates, the electrode reaction is probably accompanied by a chemical reaction.


2019 ◽  
Vol 6 (6) ◽  
pp. 1668-1672 ◽  
Author(s):  
Zhidong Huang ◽  
Lei Shang ◽  
Huiying Qi ◽  
Zhe Zhao ◽  
Baofeng Tu ◽  
...  

Hyomen Kagaku ◽  
2006 ◽  
Vol 27 (10) ◽  
pp. 609-612 ◽  
Author(s):  
Takeshi ABE ◽  
Zempachi OGUMI

2012 ◽  
Vol 18 (33) ◽  
pp. 10427-10435 ◽  
Author(s):  
Evangelos Krokos ◽  
Fabian Spänig ◽  
Michaela Ruppert ◽  
Andreas Hirsch ◽  
Dirk M. Guldi

RSC Advances ◽  
2015 ◽  
Vol 5 (30) ◽  
pp. 23391-23394 ◽  
Author(s):  
Xin Zhao ◽  
Bingzhe Wang ◽  
Wenwen Yu ◽  
Xin Gao ◽  
Guangzhe Piao

Charge transfer reactions between C60, C70 and pyridine.


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