Diffusion Dialysis of Sulfuric Acid in a Batch Cell

1994 ◽  
Vol 59 (9) ◽  
pp. 1971-1982 ◽  
Author(s):  
Zdeněk Palatý ◽  
Alena Žáková
Keyword(s):  
Differential Equation ◽  
Sulfuric Acid ◽  
Sulfuric Acid Concentration ◽  
Geometrical Arrangement ◽  
Modified Method ◽  
Basic Differential Equation ◽  
Diffusion Dialysis ◽  
The Given ◽  
Dialysis Cell ◽  
Batch Cell

The paper deals with the diffusion dialysis of sulfuric acid into water in a batch cell with a Neosepta-AFN anionselective membrane. The transport of sulfuric acid through the membrane has been quantified with respect to the dissociation of the acid by the dialysis coefficients for HSO4- and SO42- ions. These coefficients have been determined by numerical integration of the basic differential equation describing the time dependence of sulfuric acid concentration in the dialysis cell with subsequent optimization of dialysis coefficients. Moreover, the membrane permeability coefficients for HSO4- and SO42- ions and nondissociated sulfuric acid have been determined by the modified method of the Wilson diagram using the data about mass transfer in liquid for the given geometrical arrangement of cell.

Difference Schemes for Nonlinear BVPS on the Semiaxis

2007 ◽  
Vol 7 (1) ◽  
pp. 25-47 ◽  
Author(s):  
I.P. Gavrilyuk ◽  
M. Hermann ◽  
M.V. Kutniv ◽  
V.L. Makarov
Keyword(s):  
Differential Equation ◽  
Exact Solution ◽  
Boundary Value Problem ◽  
Difference Scheme ◽  
Adaptive Algorithm ◽  
Order Differential Equation ◽  
Constructive Method ◽  
Numerical Examples ◽  
Exact Difference ◽  
The Given

Abstract The scalar boundary value problem (BVP) for a nonlinear second order differential equation on the semiaxis is considered. Under some natural assumptions it is shown that on an arbitrary finite grid there exists a unique three-point exact difference scheme (EDS), i.e., a difference scheme whose solution coincides with the projection of the exact solution of the given differential equation onto the underlying grid. A constructive method is proposed to derive from the EDS a so-called truncated difference scheme (n-TDS) of rank n, where n is a freely selectable natural number. The n-TDS is the basis for a new adaptive algorithm which has all the advantages known from the modern IVP-solvers. Numerical examples are given which illustrate the theorems presented in the paper and demonstrate the reliability of the new algorithm.

scholarly journals Effective Recovery Process of Copper from Waste Printed Circuit Boards Utilizing Recycling of Leachate

JOM ◽  
2020 ◽  
Author(s):  
Joona Rajahalme ◽  
Siiri Perämäki ◽  
Roshan Budhathoki ◽  
Ari Väisänen
Keyword(s):  
Hydrogen Peroxide ◽  
Sulfuric Acid ◽  
Printed Circuit Boards ◽  
Sulfuric Acid Concentration ◽  
Recovery Process ◽  
Copper Recovery ◽  
Circuit Boards ◽  
Printed Circuit ◽  
Waste Printed Circuit Boards ◽  
Acid Consumption

AbstractThis study presents an optimized leaching and electrowinning process for the recovery of copper from waste printed circuit boards including studies of chemical consumption and recirculation of leachate. Optimization of leaching was performed using response surface methodology in diluted sulfuric acid and hydrogen peroxide media. Optimum leaching conditions for copper were found by using 3.6 mol L−1 sulfuric acid, 6 vol.% hydrogen peroxide, pulp density of 75 g L−1 with 186 min leaching time at 20°C resulting in complete leaching of copper followed by over 92% recovery and purity of 99.9% in the electrowinning. Study of chemical consumption showed total decomposition of hydrogen peroxide during leaching, while changes in sulfuric acid concentration were minor. During recirculation of the leachate with up to 5 cycles, copper recovery and product purity remained at high levels while acid consumption was reduced by 60%.

Improved Method for the Determination of Ethylenebisdithiocarbamate Residues in Plants, Fruits, and Vegetables

1967 ◽  
Vol 50 (5) ◽  
pp. 1102-1108
Author(s):  
Charles F Gordon ◽  
Richard J Schuckert ◽  
William E Bornak
Keyword(s):  
Sulfuric Acid ◽  
Fruits And Vegetables ◽  
Analytical Procedure ◽  
Improved Method ◽  
Modified Method ◽  
Fungicide Residues ◽  
Crop Types ◽  
Large Representative

Abstract A modified method for the determination of dithiocarbamate fungicide residues on crops is presented. A large representative subsample of the frozen crop is blended in ice-cold deaerated water and an aliquot of the homogenate is added to the analytical apparatus containing hot 5 0% sulfuric acid. Dithiocarbamates are decomposed to evolve CS2 which is removed by a continuous gentle air-sweep from the digestion flask. Variations in technique allow the analysis of dithiocarbamate fungicide residues in several ranges, 1-10, 10-200, and 200-1000 /ig maneb. Recoveries from a wide variety of crops averaged 70 to 103%. Certain crop types present low recoveries and/or high apparent control values, but modifications in the analytical procedure are successful in solving these problems.

Separation and recovery of sulfuric acid from acidic vanadium leaching solution by diffusion dialysis

2012 ◽  
Vol 96 ◽  
pp. 44-49 ◽  
Author(s):  
Wang Li ◽  
Yimin Zhang ◽  
Jing Huang ◽  
Xiaobo Zhu ◽  
Yi Wang
Keyword(s):  
Sulfuric Acid ◽  
Leaching Solution ◽  
Diffusion Dialysis

An Inverse Inviscid Method for the Design of Quasi-Three-Dimensional Turbomachinery Cascades

1993 ◽  
Vol 115 (1) ◽  
pp. 121-127 ◽  
Author(s):  
E. Bonataki ◽  
P. Chaviaropoulos ◽  
K. D. Papailiou
Keyword(s):  
Differential Equation ◽  
Three Dimensional ◽  
Test Cases ◽  
Elliptic Type ◽  
Flow Angle ◽  
Blade Shape ◽  
Closure Conditions ◽  
Type Boundary ◽  
Absolute Frame ◽  
The Given

The calculation of the blade shape, when the desired velocity distribution is imposed, has been the object of numerous investigations in the past. The object of this paper is to present a new method suitable for the design of turbomachinery stator and rotor blade sections, lying on an arbitrary axisymmetric stream-surface with varying streamtube width. The flow is considered irrotational in the absolute frame of reference and compressible. The given data are the streamtube geometry, the number of blades, the inlet flow conditions and the suction and pressure side velocity distributions as functions of the normalized arc-length. The output of the computation is the blade shape that satisfies the above data. The method solves an elliptic type partial differential equation for the velocity modulus with Dirichlet and periodic type boundary conditions on the (potential function, stream function)-plane (Φ, Ψ). The flow angle field is subsequently calculated solving an ordinary differential equation along the iso-Φ or iso-Ψ lines. The blade coordinates are, finally, computed by numerical integration. A set of closure conditions has been developed and discussed in the paper. The method is validated on several test cases and a discussion is held concerning its application and limitations.

scholarly journals Release of reducing sugars from water hyacinth by thermochemical and enzymatic hydrolysis

2021 ◽  
Vol 6 (1) ◽  
pp. 156-164
Author(s):  
Jessica E. Guzmán-Pérez ◽  
◽  
Oscar J. Salinas-Luna ◽  
Ernesto Favela-Torres ◽  
Nohemi López-Ramírez ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Enzymatic Hydrolysis ◽  
Acid Concentration ◽  
Water Hyacinth ◽  
Dry Matter ◽  
Eichhornia Crassipes ◽  
Reducing Sugars ◽  
Sulfuric Acid Concentration ◽  
Raw Material ◽  
Thermochemical Pretreatment

Water hyacinth (Eichhornia crassipes) is considered a pernicious herb in many parts of the world due to its rapid growth. However, for its high content of cellulose and hemicellulose, it could be considered as raw material to produce fermentable sugars. In this work, the effect of sulfuric acid concentration by thermochemical pretreatment and enzymatic hydrolysis on the release of sugars from water hyacinth was evaluated. Initially, the effect of the sulfuric acid concentration from 1.5 to 9% at 120 ºC was evaluated. With 1.5%, the release of reducing sugars was 160 milligrams of reducing sugars per gram of dry matter (mg red-sug/g dm). After the thermochemical pretreatment, the enzymatic hydrolysis with the cellulase complex (NS22086) allowed obtaining a reducing sugars concentration up to 317 mg red-sug/g dm. These thermochemical and enzymatic approaches to recover reducing sugars from water hyacinth is promising and should be evaluated for bioprocess using reducing sugars as the main source of carbon, such as bioethanol production.

scholarly journals New particle formation in the sulfuric acid–dimethylamine–water system: reevaluation of CLOUD chamber measurements and comparison to an aerosol nucleation and growth model

2018 ◽  
Vol 18 (2) ◽  
pp. 845-863 ◽  
Author(s):  
Andreas Kürten ◽  
Chenxi Li ◽  
Federico Bianchi ◽  
Joachim Curtius ◽  
António Dias ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Detection Threshold ◽  
Sulfuric Acid Concentration ◽  
Water System ◽  
Particle Formation ◽  
New Particle Formation ◽  
Flow Tube ◽  
Aerosol Model ◽  
Wide Range ◽  
Good Agreement

Abstract. A recent CLOUD (Cosmics Leaving OUtdoor Droplets) chamber study showed that sulfuric acid and dimethylamine produce new aerosols very efficiently and yield particle formation rates that are compatible with boundary layer observations. These previously published new particle formation (NPF) rates are reanalyzed in the present study with an advanced method. The results show that the NPF rates at 1.7 nm are more than a factor of 10 faster than previously published due to earlier approximations in correcting particle measurements made at a larger detection threshold. The revised NPF rates agree almost perfectly with calculated rates from a kinetic aerosol model at different sizes (1.7 and 4.3 nm mobility diameter). In addition, modeled and measured size distributions show good agreement over a wide range of sizes (up to ca. 30 nm). Furthermore, the aerosol model is modified such that evaporation rates for some clusters can be taken into account; these evaporation rates were previously published from a flow tube study. Using this model, the findings from the present study and the flow tube experiment can be brought into good agreement for the high base-to-acid ratios (∼ 100) relevant for this study. This confirms that nucleation proceeds at rates that are compatible with collision-controlled (a.k.a. kinetically controlled) NPF for the conditions during the CLOUD7 experiment (278 K, 38 % relative humidity, sulfuric acid concentration between 1 × 106 and 3 × 107 cm−3, and dimethylamine mixing ratio of ∼ 40 pptv, i.e., 1 × 109 cm−3).

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