Dipole moment of the charge transfer complex 1-ethyl-4-methoxy carbonyl pyridinium iodide

1991 ◽  
Vol 56 (3) ◽  
pp. 560-568
Author(s):  
Mahboob Mohammad ◽  
Athar Yaseen Khan ◽  
Rashid Iqbal ◽  
Intisar Ahmed Khan ◽  
Tariq Mahmood

Dipole moment of a biologically important model compound: Charge transfer complex 1-ethyl-4-methoxy carbonyl pyridinium iodide was determined experimentally. A three component method was employed for this purpose, which is especially useful for determining the dipole moment of a salt insoluble in nonpolar solvents. The experimental dipole moment of this compound, hitherto unmeasured, was found to be (37.7 ± 1.0) . 10-30 C m against the theoretical (contact) ion pair value of 46.4 . 10-30 C m.

2010 ◽  
Vol 212 (2-3) ◽  
pp. 142-146 ◽  
Author(s):  
Fuyuki Ito ◽  
Takayasu Nagai ◽  
Yasuhiro Sota ◽  
Toshihiko Nagamura

2010 ◽  
Vol 97-101 ◽  
pp. 634-637
Author(s):  
Guo Xuan Xiong ◽  
Hai Qing Huang ◽  
Chuo Yang

A ferrocenyl Schiff base monomer was synthesized through the condensation of ferrocenecarboxaldehyde and phenylenediamine under neutral conditions, and then been used to produce copolymer materials with terephthaloyl chloride monomer by the Friedel-Crafts method. The model compound and copolymer of a novel poly(ferrocene-Schiff base) and their charge transfer complex with iodine was successful obtained, their structures been characterized by 1H-NMR spectra, infrared spectra, and ultraviolet spectra. In addition, the effects of iodine doping degree on its structure was studied, the electrical measurement results showed its conductivity can be increased several orders of magnitude after doping with iodine, the maximum conductivity at room temperature is 3.17×10-4 S•cm-1.


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