Nonclassical behaviour of binary mixtures in gas-liquid critical region and its quantitative description

1989 ◽  
Vol 54 (11) ◽  
pp. 2863-2867
Author(s):  
Ivan Wichterle ◽  
Zdeněk Wagner

The gas-liquid critical region is described by means of an exponential relation, parameters of which are independent of system. It can be used for the preparation of nonclassical fluid phase behaviour. The isothermal vapour-liquid equilibrium data on the sulphur hexafluoride-pentane system measured in neighbourhood of the critical point of SF6 are presented.

2014 ◽  
Vol 59 (5) ◽  
pp. 1643-1650 ◽  
Author(s):  
Ranjeetha Hirawan ◽  
Sumit Sinha ◽  
Samuel A. Iwarere ◽  
J. David Raal ◽  
Paramespri Naidoo ◽  
...  

2018 ◽  
Vol 63 (5) ◽  
pp. 1228-1233 ◽  
Author(s):  
Deresh Ramjugernath ◽  
Alain Valtz ◽  
Dominique Richon ◽  
Mark D. Williams-Wynn ◽  
Christophe Coquelet

2013 ◽  
Vol 67 ◽  
pp. 134-142 ◽  
Author(s):  
Shalendra Clinton Subramoney ◽  
Paramespri Naidoo ◽  
Alain Valtz ◽  
Christophe Coquelet ◽  
Dominique Richon ◽  
...  

1991 ◽  
Vol 56 (12) ◽  
pp. 2773-2785 ◽  
Author(s):  
Antonio Correa ◽  
Antonio Blanco ◽  
Jose Tojo ◽  
Jose M. Correa ◽  
Alberto Arce

Experimental vapour-liquid equilibrium data for the binary mixtures ethyl acetate + pyridine, n-propyl acetate + pyridine and n-butyl acetate + pyridine have been determined at 101.325 kPa. The Wilson, NRTL, LEMF, UNIQUAC and Effective UNIQUAC equations have been fitted to the data, which have also been used to establish UNIFAC parameters for interaction between CCOO and PYRIDINE groups.


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