cw CO2 laser powered pyrolysis of methane

1985 ◽  
Vol 50 (7) ◽  
pp. 1543-1547 ◽  
Author(s):  
Josef Pola ◽  
Václav Chvalovský

The cw CO2 laser-photosensitized (SF6) pyrolysis of methane with high content of the sensitizer affords ethylene and acetylene the yields of those are shown to depend upon the laser output and the foccusing conditions of the laser radiation.

1986 ◽  
pp. 313-330 ◽  
Author(s):  
I. Ursu ◽  
L. C. Nistor ◽  
I. N. Mihailescu ◽  
V. S. Teodorescu ◽  
L. Nanu ◽  
...  

1979 ◽  
Vol 11 (6) ◽  
pp. 313-316 ◽  
Author(s):  
W.W. Duley ◽  
D.J. Semple ◽  
J.-P. Morency ◽  
M. Gravel

1986 ◽  
Vol 41 (4) ◽  
pp. 245-250 ◽  
Author(s):  
J. Stańco ◽  
Z. Rozkwitalski ◽  
G. Sliwiński ◽  
J. Konefał ◽  
P. Kukiełło ◽  
...  

1983 ◽  
Vol 48 (5) ◽  
pp. 1314-1322 ◽  
Author(s):  
Pavel Engst ◽  
Milan Horák ◽  
Josef Pola

The halogen exchange reaction between hexafluorobenzene (HFB) and boron trichloride, BCl3 initiated by a continuous-wave CO2 laser primarily affords chloropentafluorobenzene, C6F5Cl and dichlorofluoroborane, BCl2F. For the reaction initiation a number of rotational-vibrational lines of the vibrational 00°1→10°0 transition was used. With wavenumber radiation 977.21 cm-1 a faster V-V energy transfer between HFB and BCl3 molecules may occur. For this case the rate of the exchange reaction was observed to be by an order of magnitude higher compared to the reaction initiated by the laser radiation at 949.48 cm-1 and carried out under the identical absorption conditions.


1997 ◽  
Vol 293 (1-2) ◽  
pp. 220-226 ◽  
Author(s):  
P. Laurens ◽  
H. L’Enfant ◽  
M.C. Sainte Catherine ◽  
J.J. Bléchet ◽  
J. Amouroux

1997 ◽  
Vol 96 (2-3) ◽  
pp. 169-175 ◽  
Author(s):  
H. L'Enfant ◽  
P. Laurens ◽  
M.C. Sainte Catherine ◽  
T. Dubois ◽  
J. Amouroux

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