Contribution to the study of the kinetics of redox reactions proceeding via electrode processes. Theory of the method

1984 ◽  
Vol 49 (12) ◽  
pp. 2857-2866 ◽  
Author(s):  
Antonín Tockstein ◽  
Jaroslav Macenauer
Keyword(s):  
Kinetic Model ◽  
Analytical Solution ◽  
Numerical Solution ◽  
Redox Reaction ◽  
Redox Reactions ◽  
Kinetic Equations ◽  
Electrode Processes ◽  
Kinetics Of ◽  
Kinetics Of Redox Reactions

A system of differential kinetic equations is derived for the redox reaction n2 Ox1 + n1 Red2 ⇌ n1 Ox2 + n2 Red1, proceeding only through electrode processes. Its numerical solution is compared with a simplified analytical solution which leads to linearization of the relations between measurable quantities and thus verification of the kinetic model used on real redox reactions.

Contribution to the study of the kinetics of redox reactions proceeding via electrode processes: Reactions with two-electron transfer

1986 ◽  
Vol 51 (3) ◽  
pp. 493-497
Author(s):  
Jaroslav Macenauer
Keyword(s):  
Electron Transfer ◽  
Reaction Time ◽  
Redox Reactions ◽  
Redox Systems ◽  
Electrode Processes ◽  
Experimental Parameters ◽  
Kinetics Of ◽  
Kinetics Of Redox Reactions ◽  
Model Reactions

The author studied the kinetics of redox reactions of the type n2Ox1 + n1Red2 ⇄ n1Ox2 + n2Red1 proceeding via electrodes, for the case of two-electron redox systems. The dependence of the reaction time on experimental parameters (resistance, concentration, and volume of reactants) was studied on two model reactions, and the theory was verified.

Contribution to the study of the kinetics of redox reactions proceeding via electrode processes. Verification of the theory

1984 ◽  
Vol 49 (12) ◽  
pp. 2867-2874
Author(s):  
Jaroslav Macenauer
Keyword(s):  
Reaction Time ◽  
Surface Area ◽  
Electrode Surface ◽  
Redox Reactions ◽  
Theoretical Equation ◽  
Electrode Processes ◽  
Experimental Parameters ◽  
Kinetics Of ◽  
Kinetics Of Redox Reactions

The kinetics of redox reactions of the type n2 Ox1 + n1 Red2 → n1 Ox2 + n2 Red1 proceeding via electrode processes was studied on seven practical examples. The reaction time was measured as function of experimental parameters (resistance, concentration, volume of solution, electrode surface area), and the theoretical equation for the reaction time was verified.

The effect of viscosity on the kinetics of redox reactions in highly viscous silicate liquids

2012 ◽  
Vol 136 (22) ◽  
pp. 224502 ◽  
Author(s):  
Ladislav Kido ◽  
Matthias Müller ◽  
Christian Rüssel
Keyword(s):  
Redox Reactions ◽  
Silicate Liquids ◽  
Kinetics Of ◽  
Kinetics Of Redox Reactions

ChemInform Abstract: Influence of Reaction Medium on the Catalyst and Kinetics of Redox Reactions

ChemInform ◽  
1989 ◽  
Vol 20 (1) ◽  
Author(s):  
S. A. VENYAMINOV ◽  
T. V. ANDRUSHKEVICH ◽  
A. V. KHASIN
Keyword(s):  
Redox Reactions ◽  
Reaction Medium ◽  
Kinetics Of ◽  
Kinetics Of Redox Reactions
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