Saturated vapour pressures of the ternary system urea-ammonium nitrate-water

1983 ◽  
Vol 48 (8) ◽  
pp. 2130-2140
Author(s):  
Jiřina Hejtmánková ◽  
Lidmila Bartovská ◽  
Marie Šišková ◽  
Lubomír Jäger
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Ammonium Nitrate ◽  
Binary Systems ◽  
Isopiestic Method ◽  
Saturated Vapour ◽  
Liquid Solutions ◽  
Urea Ammonium Nitrate ◽  
Standard Solutions

Saturated vapour pressures of the ternary liquid solutions of urea and ammonium nitrate in water were investigated by the isopiestic method at 15, 25 and 35 °C. The measurements were carried out within the concentrations that are measurable by means of the NaCl standard solutions (i.e. up to the NaCl molality 6 mol/kg). The experimental data are correlated in terms of isotonic solutions of the urea-water and ammonium nitrate-water binary systems.

Physico-chemical properties of the ternary system urea-ammonium nitrate-water. Density

1983 ◽  
Vol 48 (4) ◽  
pp. 1097-1103
Author(s):  
Ludmila Bartovská ◽  
Jiřina Hejtmánková ◽  
Marie Šišková ◽  
Lubomír Jäger
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Ammonium Nitrate ◽  
Binary Systems ◽  
Chemical Properties ◽  
Water Density ◽  
Physico Chemical ◽  
Temperature Dependences ◽  
Urea Ammonium Nitrate

Density of the ternary system urea-ammonium nitrate-water was measured in the range of overall concentrations 0-75 mass % at temperatures of 0, 20, 30 and 40 °C. The experimental data are compared with the values calculated from the relation obtained by combining the temperature dependences of densities of the binary systems urea-water and ammonium nitrate-water.

Physico-chemical properties of the ternary system urea-ammonium nitrate-water. Surface tension

1985 ◽  
Vol 50 (8) ◽  
pp. 1629-1635 ◽  
Author(s):  
Marie Šišková ◽  
Jiřina Hejtmánková ◽  
Lidmila Bartovská
Keyword(s):  
Surface Tension ◽  
Ternary System ◽  
Ammonium Nitrate ◽  
Binary Systems ◽  
Chemical Properties ◽  
Ternary Systems ◽  
Surface Tensions ◽  
Physico Chemical ◽  
Urea Ammonium Nitrate ◽  
Experimental Values

Surface tension of two binary systems ammonium nitrate-water and urea-water and of the ternary system ammonium nitrate-urea-water was measured as a function of concentration at 20 and 40 °C. The experimental values were compared with those calculated from the relations which were proposed for calculating surface tensions of ternary systems from measured surface tensions of both binary systems.

scholarly journals The Addition of N-Butanol in Ethanol-Isooctane Mixture to Reduce Vapor Pressure of Oxygenated-Gasoline Blend

2017 ◽  
Vol 17 (3) ◽  
pp. 500 ◽  
Author(s):  
Rendra Panca Anugraha ◽  
Zul Akbar Andi Picunang ◽  
Annas Wiguno ◽  
Rizky Tetrisyanda ◽  
Kuswandi Kuswandi ◽  
...  
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Vapor Pressure ◽  
Binary Systems ◽  
Experimental Results ◽  
Ideal Solution ◽  
Positive Deviation ◽  
Relative Deviation ◽  
Wilson Model ◽  
Binary Parameter

In this work, vapor pressure of binary systems for isooctane + ethanol, isooctane + n-butanol and ethanol + n-butanol and ternary system for isooctane + ethanol + n-butanol were measured in the temperature range from 313.15 to 318.15 K using the inclined ebulliometer. The experimental results showed that the existence of n-butanol in isooctane decreases the vapor pressure of mixture, while increasing n-butanol fraction in ternary isooctane-ethanol-n-butanol mixture decreased vapor pressure of mixture. Experimental data for binary systems studied were correlated with Wilson, NRTL and UNIQUAC models with average relative deviation (ARD) of 3.5%. The optimized binary parameter pairs obtained in this work were used to estimate the ternary system. The Wilson model gave the best performance for estimation of ternary system with ARD of 5.4%. All systems studied showed non-ideal solution with positive deviation from Raoult’s law.

scholarly journals Sn-Ni-Bi liquid phase thermodynamic properties

2011 ◽  
Vol 9 (1) ◽  
pp. 149-156 ◽  
Author(s):  
Nikolina Milcheva ◽  
Jolanta Romanowska ◽  
Gueorgui Vassilev
Keyword(s):  
Experimental Data ◽  
Liquid Phase ◽  
Thermodynamic Properties ◽  
Binary Systems ◽  
Isopiestic Method ◽  
Miscibility Gap ◽  
Calphad Approach ◽  
Activity Data ◽  
General Solution Model ◽  
Good Agreement

AbstractExperimental data of bismuth activity coefficients at 1773 K were obtained by isopiestic method and compared to calculated values. Thermodynamic properties of the Sn-Ni-Bi liquid phase were estimated by means of the general solution model and by the methods of Kohler. Description of the ternary liquid phase (Gibbs excess energy dependence on the temperature and the composition) was achieved by using available thermodynamic data of the constitutive binary systems (Ni-Bi, Sn-Bi, Sn-Ni). A comparison between calculated quantities and experimental data wasconducted. The present assessment with thermodynamically optimized values of the system Sn-Ni-Bi (obtained by the CALPHAD approach) was in good agreement. The suggested appearance of a liquid phase miscibility gap at high temperatures is in agreement with the experimental bismuth activity data and with the assessed thermochemical functions.

Correlation and Prediction of Vapor-Liquid Equilibrium for the Propylene Oxide-Ethanol-Water Ternary System

2011 ◽  
Vol 396-398 ◽  
pp. 973-976
Author(s):  
Cheng Xue Wang ◽  
Rui Xia Jiang
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Propylene Oxide ◽  
Binary Systems ◽  
Molar Fraction ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Vle Data ◽  
Consistency Verification ◽  
Vapor Liquid

The vapor-liquid equilibrium (VLE) data for the binary systems ethanol-water (1), propylene oxide (PO)-ethanol (2), PO-water (3) and the ternary system PO-ethanol-water (4) were determined at 101.3kPa. The binary VLE data measured passed the thermodynamic consistency verification. The experimental VLE data of the binary systems were correlated with the nonrandom two-liquid (NRTL) models. The results show that the values of molar fraction of the ternary system (4) in vapor phase from the binary NRTL parameters agree well with the experimental data.

Thermodynamic Analysis of the Fe-Mn-P Ternary Phase Diagram by Combining the First-Principles and CALPHAD Methods

2007 ◽  
Vol 561-565 ◽  
pp. 1899-1902 ◽  
Author(s):  
T. Tokunaga ◽  
N. Hanaya ◽  
Hiroshi Ohtani ◽  
Mitsuhiro Hasebe
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Ternary System ◽  
Thermodynamic Analysis ◽  
First Principles ◽  
Binary Systems ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
First Principles Calculations ◽  
The Enthalpy Of Formation

A thermodynamic analysis of the Fe-Mn-P ternary system has been carried out using the CALPHAD method. Among the three binary systems relevant to this ternary phase diagram, the thermodynamic parameters of the Mn-P binary system were evaluated in this study. The enthalpy of formation of the binary phosphides obtained from our first-principles calculations was utilized in the present analysis to compensate for the lack of available experimental data. The thermodynamic descriptions of the Fe-Mn and Fe-P binary systems were taken from previous studies. The phase equilibria in the Fe-Mn-P ternary system were analysed based on the experimental data on the phase boundaries. The calculated phase diagrams are in agreement with the experimental results.

scholarly journals Calculation of the thermodynamic properties of liquid Ag-In-Sb alloys

2006 ◽  
Vol 71 (3) ◽  
pp. 203-211 ◽  
Author(s):  
Dragana Zivkovic ◽  
Dragan Manasijevic ◽  
Ivan Mihajlovic ◽  
Zivan Zivkovic
Keyword(s):  
Experimental Data ◽  
Liquid Phase ◽  
Thermodynamic Properties ◽  
Ternary System ◽  
Interaction Parameter ◽  
Thermodynamic Data ◽  
Binary Systems ◽  
Ternary Interaction Parameter ◽  
Ternary Interaction ◽  
Mutual Agreement

The results of calculations of the thermodynamic properties of liquid Ag-In-Sb alloys are presented in this paper. The Redlich-Kister-Muggianu model was used for the calculations. Based on known thermodynamic data for constitutive binary systems and available experimental data for the investigated ternary system, the ternary interaction parameter for the liquid phase in the temperature range 1000-1200 K was determined. Comparison between experimental and calculated results showed their good mutual agreement.

Exzeßenthalpien und Solvatationsverhalten der Systeme LiBr/Methanol, ZnBr2/Methanol und LiBr/ZnBr2/Methanol

1982 ◽  
Vol 37 (3) ◽  
pp. 224-231
Author(s):  
M. Christahl ◽  
J. Thönnissen
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Coordination Number ◽  
Binary Systems ◽  
Excess Enthalpy ◽  
Enthalpies Of Solution ◽  
Solvation Number ◽  
Enthalpies Of Mixing ◽  
Mathematical Approximation

Abstract For the binary systems Li Br/methanol and Zn Br 2/methanol as well as for the ternary system Li Br/Zn Br 2/methanol the integral enthalpies of mixing are experimentally determined. The mixing of Li Br and methanol is more exothermic than in the case of Zn Br 2. The excess enthalpy is largest for the ternary system. From the mathematical approximation of experimental data the differential enthalpies of solution and of dilution are obtained. In the discussion it is concluded that in diluted solutions the salts are surrounded by a strongly coordinated inner solvation sphere (coordination number N = 4) and a less coordinated outer solvation sphere (N = 6) resulting in a total solvation number of N = 10.

scholarly journals Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems

Thermo ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 122-133
Author(s):  
Jaén A. Ocádiz Flores ◽  
Bas A. S. Rooijakkers ◽  
Rudy J. M. Konings ◽  
Anna Louise Smith
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Gibbs Energy ◽  
Binary Systems ◽  
Thermodynamic Description ◽  
Structural Models ◽  
Nuclear Industry ◽  
Thermodynamic Investigation ◽  
Liquid Solutions ◽  
Near Future

The ACl-ThCl4 (A = Li, Na, K) systems could be of relevance to the nuclear industry in the near future. A thermodynamic investigation of the three binary systems is presented herein. The excess Gibbs energy of the liquid solutions is described using the quasi-chemical formalism in the quadruplet approximation. The phase diagram optimisations are based on the experimental data available in the literature. The thermodynamic stability of the liquid solutions increases in the order Li < Na < K, in agreement with idealised interactions and structural models.

Sign in / Sign up

Export Citation Format

Share Document