Some electrochemical properties of Raney nickel

1982 ◽  
Vol 47 (6) ◽  
pp. 1695-1704 ◽  
Author(s):  
Olga Marholová ◽  
Karel Smrček ◽  
Zdeněk Ministr ◽  
Zdeněk Spitzer
Keyword(s):  
Electrochemical Properties ◽  
Surface Area ◽  
Nickel Catalyst ◽  
Raney Nickel ◽  
Internal Surface ◽  
Internal Surface Area ◽  
Raney Nickel Catalyst ◽  
Preparation Mode ◽  
And Storage ◽  
Hydrogen Anode

The connexion between the functioning of the Raney nickel catalyst in a hydrogen anode and the conditions of its preparation (mode of grinding the alloy, deactivation, and storage of the catalyst) was investigated. The relation between the internal surface area and the activity of the catalyst is discussed.

Hydrophobic hydrogen anode with a nickel catalyst

1982 ◽  
Vol 47 (12) ◽  
pp. 3230-3235 ◽  
Author(s):  
Olga Marholová ◽  
Karel Smrček
Keyword(s):  
Surface Area ◽  
Nickel Catalyst ◽  
Raney Nickel ◽  
Platinum Catalyst ◽  
Raney Nickel Catalyst ◽  
Electrochemical Parameters ◽  
Geometric Surface ◽  
Geometric Surface Area ◽  
Hydrogen Anode ◽  
In Cells

A hydrophobic porous hydrogen anode was prepared whose electrochemical parameters are comparable with anodes containing a platinum catalyst. For its successful preparation, oxidation of the Raney nickel catalyst with air oxygen or with fluorine from Teflon must be prevented. The electrodes of a geometric surface area up to 450 cm2 were tested in cells and modules filled with 7M-KOH.

scholarly journals Heat-Up Performance of Catalyst Carriers—A Parameter Study and Thermodynamic Analysis

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 964
Author(s):  
Thomas Steiner ◽  
Daniel Neurauter ◽  
Peer Moewius ◽  
Christoph Pfeifer ◽  
Verena Schallhart ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Coefficient ◽  
Transfer Coefficient ◽  
Surface Area ◽  
Internal Surface ◽  
Installation Space ◽  
Parameter Study ◽  
Thin Wall ◽  
Primary Role ◽  
Internal Surface Area

This study investigates geometric parameters of commercially available or recently published models of catalyst substrates for passenger vehicles and provides a numerical evaluation of their influence on heat-up behavior. Parameters considered to have a significant impact on the thermal economy of a monolith are: internal surface area, heat transfer coefficient, and mass of the converter, as well as its heat capacity. During simulation experiments, it could be determined that the primary role is played by the mass of the monolith and its internal surface area, while the heat transfer coefficient only has a secondary role. Furthermore, an optimization loop was implemented, whereby the internal surface area of a commonly used substrate was chosen as a reference. The lengths of the thin wall and high cell density monoliths investigated were adapted consecutively to obtain the reference internal surface area. The results obtained by this optimization process contribute to improving the heat-up performance while simultaneously reducing the valuable installation space required.

Desulfurization of Benzonaphthothiophenes and Dibenzothiophene with a Raney Nickel Catalyst

1987 ◽  
pp. 357-366 ◽  
Author(s):  
Masatoshi Nagai ◽  
Hideo Urimoto ◽  
Kazuya Uetake ◽  
Noriyuki Sakikawa ◽  
Richard D. Gonzalez
Keyword(s):  
Nickel Catalyst ◽  
Raney Nickel ◽  
Raney Nickel Catalyst

scholarly journals Plasma Catalysis: Distinguishing between Thermal and Chemical Effects

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 185 ◽  
Author(s):  
Guido Giammaria ◽  
Gerard van Rooij ◽  
Leon Lefferts
Keyword(s):  
Gas Phase ◽  
Surface Area ◽  
Thermal Effects ◽  
External Surface ◽  
Plasma Chemistry ◽  
Internal Surface ◽  
Plasma Power ◽  
External Surface Area ◽  
Internal Surface Area ◽  
Chemical Effects

The goal of this study is to develop a method to distinguish between plasma chemistry and thermal effects in a Dielectric Barrier Discharge nonequilibrium plasma containing a packed bed of porous particles. Decomposition of CaCO3 in Ar plasma is used as a model reaction and CaCO3 samples were prepared with different external surface area, via the particle size, as well as with different internal surface area, via pore morphology. Also, the effect of the CO2 in gas phase on the formation of products during plasma enhanced decomposition is measured. The internal surface area is not exposed to plasma and relates to thermal effect only, whereas both plasma and thermal effects occur at the external surface area. Decomposition rates were in our case found to be influenced by internal surface changes only and thermal decomposition is concluded to dominate. This is further supported by the slow response in the CO2 concentration at a timescale of typically 1 minute upon changes in discharge power. The thermal effect is estimated based on the kinetics of the CaCO3 decomposition, resulting in a temperature increase within 80 °C for plasma power from 0 to 6 W. In contrast, CO2 dissociation to CO and O2 is controlled by plasma chemistry as this reaction is thermodynamically impossible without plasma, in agreement with fast response within a few seconds of the CO concentration when changing plasma power. CO forms exclusively via consecutive dissociation of CO2 in the gas phase and not directly from CaCO3. In ongoing work, this methodology is used to distinguish between thermal effects and plasma–chemical effects in more reactive plasma, containing, e.g., H2.

Evaluation of Nisin-Coated Cellulose Casings for the Control of Listeria monocytogenes Inoculated onto the Surface of Commercially Prepared Frankfurters†‡

2004 ◽  
Vol 67 (5) ◽  
pp. 1017-1021 ◽  
Author(s):  
JOHN B. LUCHANSKY ◽  
JEFFREY E. CALL
Keyword(s):  
Listeria Monocytogenes ◽  
Surface Area ◽  
Internal Surface ◽  
Refrigerated Storage ◽  
Internal Surface Area ◽  
Appreciable Increase ◽  
Potassium Lactate ◽  
Selective Agar ◽  
Peptone Water ◽  
Sodium Diacetate

Commercially prepared frankfurters were formulated with and without ~1.4% potassium lactate and 0.1% sodium diacetate and were subsequently processed in cellulose casings coated with and without nisin (~50,000 IU per square inch of internal surface area) to control the outgrowth of Listeria monocytogenes during refrigerated storage. The frankfurters were inoculated with ~5 log CFU per package of a five-strain mixture of L. monocytogenes and then vacuum sealed before being stored at 4° C for 60 to 90 days. Surviving organisms were recovered and enumerated by rinsing each package with 18 ml of sterile 0.1% peptone water and plating onto MOX selective agar. The data for each of two trials were averaged. In packages that contained frankfurters formulated with potassium lactate and sodium diacetate and prepared in nisin-coated casings, L. monocytogenes levels decreased by 1.15 log CFU per package after 90 days of storage. L. monocytogenes levels decreased by 0.95 log CFU per package in frankfurters that were prepared in casings that were not coated with nisin. In packages of frankfurters that were formulated without potassium lactate and sodium diacetate and prepared in nisin-coated casings, L. monocytogenes levels decreased by 0.88 log CFU per package after 15 days of storage but then increased appreciablythereafter over a 60-day period of refrigerated storage. There was also an appreciable increase in pathogen numbers during 60 days of storage in otherwise similar frankfurters formulated without potassium lactate and sodium diacetate prepared in casings that were not coated with nisin. These data confirm that potassium lactate and sodium diacetate display listeriostatic activity as an ingredient of commercial frankfurters. These data also establish that cellulose casings coated with nisin display only moderate antilisterial activity in vacuum-sealed packages of commercially prepared frankfurters during storage at 4° C.

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