Solubility of thallium pertechnate in nitrate solutions

1981 ◽  
Vol 46 (12) ◽  
pp. 3083-3087 ◽  
Author(s):  
Vladimír Mikulaj ◽  
Eva Mišianiková ◽  
Fedor Macášek
Keyword(s):  
Activity Coefficient ◽  
Aqueous Solutions ◽  
Activity Coefficients ◽  
Molar Activity ◽  
Nitrate Solutions

Solubility of TlTcO4 was determined in water and in HNO3, NaNO3, NH4NO3, Ca(NO3)2, and LiNO3 aqueous solutions in concentrations 5-8 mol l-1. The solubility increases with increasing concentration of the electrolyte; the values measured were used for a calculation of the stoichiometric molar activity coefficients of the Tl+ and TcO4- ions. The activity coefficient values corrected for the fraction of the nonassociated Tl+ ions approach those of the base electrolytes up to their concentrations of 4-5 mol l-1.

Research on Thermodynamic Properties of Bioleaching Solution in Lean Nickel-Cobalt Ore by Pitzer - Meissner Model

2015 ◽  
Vol 1092-1093 ◽  
pp. 1455-1459
Author(s):  
Chu Yue Hou ◽  
Gui Ying Zhou ◽  
Jian Kang Wen ◽  
Biao Wu
Keyword(s):  
Thermodynamic Properties ◽  
Activity Coefficient ◽  
Aqueous Solutions ◽  
Activity Coefficients ◽  
Pitzer Model ◽  
Foreign Ions ◽  
Nickel Cobalt

In this paper, we jointly use the Pitzer model and the Meissner model to study thermodynamic laws of bioleaching solution in a lean nickel-cobalt ore in the Jilin Baishan, by using the Pitzer model to calculate activity coefficients of single electrolyte aqueous solutions and the Meissner model to calculate activity coefficients of components in the bioleaching solution. Also we studied the rules of activity coefficient of NiSO4 and CoSO4 in the solution. Results show that when separating and purifying foreign ions from bioleaching solution of the lean nickel-cobalt ore, the descending sequence of their ion concentration’s effect over the solution is Mg2+, Fe3+, Fe2+, Ni2+, Co2+ and Ca2+.

Activity coefficients of potassium perrhenate in aqueous mixtures with KCl, NaCl and KI at 298.15 K

1975 ◽  
Vol 28 (3) ◽  
pp. 665 ◽  
Author(s):  
C Chan
Keyword(s):  
Activity Coefficient ◽  
Aqueous Solutions ◽  
Activity Coefficients ◽  
Aqueous Mixtures ◽  
Ionic Activity ◽  
Activity Product ◽  
Dilute Aqueous Solutions ◽  
Mean Ionic Activity Coefficients

The solubilities of potassium perrhenate in aqueous NaCl, KCl and KI solutions are reported. The solubility activity product for this electrolyte was determined using extrapolation functions involving three different mean ionic activity coefficient expressions. Mean ionic activity coefficients have been computed for potassium perrhenate in dilute aqueous solutions and there is no justification for considering ion association1,2 in these solutions.

scholarly journals New Data on Activity Coefficients of Potassium, Nitrate, and Chloride Ions in Aqueous Solutions of KNO3 and KCl by Ion Selective Electrodes

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Debasmita Dash ◽  
Shekhar Kumar ◽  
C. Mallika ◽  
U. Kamachi Mudali
Keyword(s):  
Activity Coefficient ◽  
Aqueous Solutions ◽  
Activity Coefficients ◽  
Reference Electrode ◽  
Potassium Nitrate ◽  
Chloride Ions ◽  
Ion Selective Electrodes ◽  
Ion Activity ◽  
Double Junction ◽  
Single Ion Activity

Ion selective electrodes (ISEs) are used to measure the single-ion activity coefficients in aqueous solutions of KNO3 and KCl at 298.15 K against a double-junction reference electrode. The EMF responses of ISEs up to 0.01 m are plotted to obtain the slope and intercept values. The obtained slopes and intercepts are used in Nernst equation for higher concentrated solutions for calculation of individual ion activity coefficient. The mean ionic activity coefficients are estimated from single ion activity coefficient, and the obtained results are compared with the literature values.

Viscosity, electrical conductivity and density of the system ammonium nitrate-dimethyl sulphoxide

1984 ◽  
Vol 49 (5) ◽  
pp. 1109-1115
Author(s):  
Jindřich Novák ◽  
Zdeněk Kodejš ◽  
Ivo Sláma
Keyword(s):  
Electrical Conductivity ◽  
Aqueous Solutions ◽  
Ammonium Nitrate ◽  
Transport Properties ◽  
Calcium Nitrate ◽  
Dimethyl Sulphoxide ◽  
Present System ◽  
Empirical Equations ◽  
Concentrated Solutions ◽  
Nitrate Solutions

The density, viscosity, and electrical conductivity of highly concentrated solutions of ammonium nitrate in dimethyl sulphoxide have been determined over the temperature range 10-60 °C and the concentration range 7-50 mol% of the salt. The variations in the quantities as a function of temperature and concentration have been correlated by empirical equations. A comparison is made between the transport properties for the present system, aqueous solutions of ammonium nitrate, and calcium nitrate solutions in dimethyl sulphoxide.

Ionic Activities of Sodium, Potassium, and Chloride in Human Serum

1968 ◽  
Vol 14 (9) ◽  
pp. 859-870 ◽  
Author(s):  
Harold Dahms ◽  
Robert Rock ◽  
David Seligson
Keyword(s):  
Human Serum ◽  
Water Content ◽  
Activity Coefficients ◽  
Activity Concentration ◽  
Hospitalized Patients ◽  
Sodium Potassium ◽  
Conversion Factors ◽  
Disease States ◽  
Molar Activity

Abstract Ionic activities of sodium, potassium, and chloride in serums of 26 hospitalized patients were determined with ion-specific electrodes. Comparison of the activities with the corresponding concentrations shows that the two most important parameters influencing the molar activity coefficients of these ions are the water content of serum and the binding between albumin and chloride. Quantitative expressions for activity-concentration conversion factors are given. Calculations show that the conversion factors vary significantly in disease states due to changes in protein.

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