Structure of dimeric monoisopropoxydicaprolactamoalane and diisopropoxymonocaprolactamoalane

1980 ◽  
Vol 45 (5) ◽  
pp. 1336-1342 ◽  
Author(s):  
Otomar Kříž ◽  
Bohuslav Čásenský ◽  
Jiří Macháček
Keyword(s):  
Molecular Weight ◽  
Spectral Measurements ◽  
Aluminium Isopropoxide ◽  
Bridge Formation ◽  
H Nmr ◽  
Oxygen Atoms

Molecular weight and 1H-NMR and IR spectral measurements evidence that in dimeric aluminium isopropoxide in which one or two isopropoxyls have been replaced by caprolactam ligand, only the oxygen atoms of the isopropoxyl take part in the bridge formation between the two aluminium atoms.

119Sn, 13C and 1H NMR Spectra of Tris(1-butyl)stannyl D-Glucuronate

1997 ◽  
Vol 62 (8) ◽  
pp. 1169-1176 ◽  
Author(s):  
Antonín Lyčka ◽  
Jaroslav Holeček ◽  
David Micák
Keyword(s):  
Chemical Shift ◽  
Carbonyl Group ◽  
1H Nmr ◽  
Equatorial Plane ◽  
Title Compound ◽  
Nmr Spectra ◽  
Hydroxyl Groups ◽  
Carboxylic Group ◽  
H Nmr ◽  
Oxygen Atoms

The 119Sn, 13C and 1H NMR spectra of tris(1-butyl)stannyl D-glucuronate have been measured in hexadeuteriodimethyl sulfoxide, tetradeuteriomethanol and deuteriochloroform. The chemical shift values have been assigned unambiguously with the help of H,H-COSY, TOCSY, H,C-COSY and 1H-13C HMQC-RELAY. From the analysis of parameters of 119Sn, 13C and 1H NMR spectra of the title compound and their comparison with the corresponding spectra of tris(1-butyl)stannyl acetate and other carboxylates it follows that in solutions of non-coordinating solvents (deuteriochloroform) the title compound is present in the form of more or less isolated individual molecules with pseudotetrahedral environment around the central tin atom and with monodentately bound carboxylic group. The interaction of tin atom with oxygen atoms of carbonyl group and hydroxyl groups of the saccharide residue - if they are present at all - are very weak. In solutions in coordinating solvents (hexadeuteriodimethyl sulfoxide or tetradeuteriomethanol), the title compound forms complexes with one molecule of the solvent. Particles of these complexes have a shape of trigonal bipyramid with the 1-butyl substituents in equatorial plane and the oxygen atoms of monodentate carboxylic group and coordinating solvent in axial positions.

scholarly journals Synthesis and characterization of different soybean oil-based polyols with fatty alcohol and aromatic alcohol

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 491-499
Author(s):  
Fukai Yang ◽  
Hao Yu ◽  
Yuyuan Deng ◽  
Xinyu Xu
Keyword(s):  
Molecular Weight ◽  
Soybean Oil ◽  
Retention Time ◽  
Ring Opening ◽  
Isoamyl Alcohol ◽  
Synthesis And Characterization ◽  
Intermolecular Force ◽  
H Nmr ◽  
Epoxy Groups

Abstract In this article, five kinds of soybean oil-based polyols (polyol-E, polyol-P, polyol-I, polyol-B, and polyol-M) were prepared by ring-opening the epoxy groups in epoxidized soybean oil (ESO) with ethyl alcohol, 1-pentanol, isoamyl alcohol, p-tert-butylphenol, and 4-methoxyphenol in the presence of tetrafluoroboric acid as the catalyst. The SOPs were characterized by FTIR, 1H NMR, GPC, viscosity, and hydroxyl numbers. Compared with ESO, the retention time of SOPs is shortened, indicating that the molecular weight of SOPs is increased. The structure of different monomers can significantly affect the hydroxyl numbers of SOPs. Due to the large steric hindrance of isoamyl alcohol, p-hydroxyanisole, and p-tert-butylphenol, SOPs prepared by these three monomers often undergo further dehydration to ether reactions, which consumes the hydroxyl of polyols, thus forming dimers and multimers; therefore, the hydroxyl numbers are much lower than polyol-E and polyol-P. The viscosity of polyol-E and polyol-P is much lower than that of polyol-I, polyol-B, and polyol-M. A longer distance between the molecules and the smaller intermolecular force makes the SOPs dehydrate to ether again. This generates dimer or polymers and makes the viscosity of these SOPs larger, and the molecular weight greatly increases.

Alternating poly(ester amide)s from glutaric anhydride and α,ω-aminoalcohols: synthesis and thermal properties

e-Polymers ◽  
2003 ◽  
Vol 3 (1) ◽  
Author(s):  
Thomas Fey ◽  
Helmut Keul ◽  
Hartwig Höcker
Keyword(s):  
Molecular Weight ◽  
Thermal Properties ◽  
Homologous Series ◽  
Average Molecular Weight ◽  
Number Average Molecular Weight ◽  
Melting Points ◽  
Glutaric Anhydride ◽  
H Nmr ◽  
Activating Agent ◽  
Dimethylformamide Solution

Abstract Alternating poly(ester amide)s 6a - e were prepared by polycondensation of α-carboxyl-ω-hydroxyamides 3a - e which were obtained by aminolysis of glutaric anhydride (1) and α,ω-aminoalcohols, H2N-(CH2)x-OH (x = 2 - 6) 2a - e. The polycondensation was performed in dimethylformamide solution using a carbodiimide as activating agent, or in bulk with Bu2Sn(OMe)2, Ti(OBu)4 and Sn(octoate)2 as a catalyst. For the polycondensation in bulk, the influence of catalyst and of temperature on the number-average molecular weight was studied. 1H NMR analyses of the poly(ester amide)s clearly show the alternating microstructure. The poly(ester amide)s from glutaric anhydride and the homologous series of α,ω-aminoalcohols are semicrystalline materials; their melting points show the odd/even effect observed for other poly(ester amide)s.

Combined proteomic and metabonomic studies in three genetic forms of the renal Fanconi syndrome

2007 ◽  
Vol 293 (2) ◽  
pp. F456-F467 ◽  
Author(s):  
Annalisa Vilasi ◽  
Pedro R. Cutillas ◽  
Anthony D. Maher ◽  
Severine F. M. Zirah ◽  
Giovambattista Capasso ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Fanconi Syndrome ◽  
Low Molecular Weight ◽  
Renal Fanconi Syndrome ◽  
Dent’S Disease ◽  
H Nmr ◽  
Low Molecular Weight Proteinuria ◽  
Dent's Disease ◽  
Underlying Mechanisms ◽  
Normal Urine

The renal Fanconi syndrome is a defect of proximal tubular function causing aminoaciduria and low-molecular-weight proteinuria. Dent's disease and Lowe syndrome are defined X-linked forms of Fanconi syndrome; there is also an autosomal dominant idiopathic form (ADIF), phenotypically similar to Dent's disease though its gene defect is still unknown. To assess whether their respective gene products are ultimately involved in a common reabsorptive pathway for proteins and low-molecular-mass endogenous metabolites, we compared renal Fanconi urinary proteomes and metabonomes with normal (control) urine using mass spectrometry and1H-NMR spectroscopy, respectively. Urine from patients with low-molecular-weight proteinuria secondary to ifosfamide treatment (tubular proteinuria; TP) was also analyzed for comparison. All four of the disorders studied had characteristic proteomic and metabonomic profiles. Uromodulin was the most abundant protein in normal urine, whereas Fanconi urine was dominated by albumin.1H-NMR spectroscopic data showed differences in the metabolic profiles of Fanconi urine vs. normal urine, due mainly to aminoaciduria. There were differences in the urinary metabolite and protein compositions between the three genetic forms of Fanconi syndrome: cluster analysis grouped the Lowe and Dent's urinary proteomes and metabonomes together, whereas ADIF and TP clustered together separately. Our findings demonstrate a distinctive “polypeptide and metabolite fingerprint” that can characterize the renal Fanconi syndrome; they also suggest that more subtle and cause-specific differences may exist between the different forms of Fanconi syndrome that might provide novel insights into the underlying mechanisms and cellular pathways affected.

scholarly journals Crystal Structure and Cyclic Voltammetric Studies on the Metal Complexes of N-(Dimethylcarbamothioyl)-4-fluorobenzamide

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Gun Binzet ◽  
Ersan Turunc ◽  
Ulrich Flörke ◽  
Nevzat Külcü ◽  
Hakan Arslan
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Analysis Data ◽  
Complex Compounds ◽  
Planar Geometry ◽  
Cyclic Voltammetric ◽  
Bond Lengths ◽  
H Nmr ◽  
Cyclic Voltammetric Studies ◽  
Oxygen Atoms

We synthesized N-(dimethylcarbamothioyl)-4-fluorobenzamide compound and its copper(II) and nickel(II) complexes. The structures of compounds have been characterized by elemental analysis and spectral data (IR, 1H NMR). Furthermore, crystal and molecular structure of the synthesized complexes have been identified by using single crystal X-ray diffraction data. In the complexes formation the metal atom was coordinated via two sulfur atoms and two oxygen atoms. The single crystal structure of copper(II) and nickel(II) complex exhibits slightly distorted square planar geometry. The oxygen atoms are in a cis configuration. It appeared that the lengths of the thiocarbonyl and carbonyl bonds are longer than the average for C=S and C=O; meanwhile the C‐N bonds in the complex ring appeared to be shorter than the average for C‐N single bonds. These data show that C-O, C-S, and C-N bond lengths of the complexes suggest considerable electronic delocalization in the chelate ring. All bond lengths and angles obtained as a result of the analyses are found to be within experimental error limits. The obtained crystal analysis data shows that the structure of complex compounds is compatible with similar compounds in literature. Electrochemical behavior of complexes has been investigated by cyclic voltammetry technique in aprotic media. From the cyclic voltammetric investigation, both of the complexes have demonstrated electroactive properties.

Synthesis and thermal properties of triblock copolymers of methyl methacrylate using combination of anionic and controlled radical polymerization: Poly(methyl methacrylate) center block bearing different microstructures

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhengji Song ◽  
Carole Pelletier ◽  
Yinghua Qi ◽  
Jasim Ahmed ◽  
Sunil K. Varshney ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Thermal Properties ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Alkyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
H Nmr

AbstractABA and/or ABC type triblock copolymers were synthesized by living anionic and controlled radical polymerization in which poly(methyl methacrylate) was used as central block. The structural composition of these block copolymers were determined by 1H NMR. The block length/molecular weight and microstructure of these polymers were measured by SEC. The microstructure of resultant central alkyl methacrylate block can be tailored from highly syndiotactic to highly isotactic structure by varying the solvent and/or initiator. The thermal and rheological properties of center poly(methyl methacrylate) block and poly(styreneb- methyl methacrylate-b- styrene) tri block copolymers were studied in detail.

Preparation of poly(methyl methacrylate) nano-latexes via UV irradiation in the presence of iron aqueous solution

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Hong Zhang ◽  
Limin Zang ◽  
Jiahe Luo ◽  
Jinshan Guo
Keyword(s):  
Aqueous Solution ◽  
Molecular Weight ◽  
Glass Transition ◽  
Transition Temperature ◽  
Methyl Methacrylate ◽  
High Efficiency ◽  
Particle Sizes ◽  
H Nmr ◽  
Reaction Conversion ◽  
Emulsifying Agent

AbstractThe UV-initiated emulsion polymerization of methyl methacrylate (MMA) in the presence of FeCl3 was studied. The photopolymerization presented high efficiency even though using a small percentage of photoinitiator. The entire polymerization could be performed within 10 min and displayed a conversion higher than 90% at ambient temperature. The particle sizes could be tuned in the range of 20-90 nm. The effects of content of initiator and emulsifying agent upon the reaction conversion, distribution of molecular weight, diameter of particles and glass-transition temperature were examined. 1H-NMR technique was used to investigate the structural properties of PMMA.

Halogenodephenylation of triphenyltin(IV) pseudohalides

1985 ◽  
Vol 63 (2) ◽  
pp. 329-331 ◽  
Author(s):  
P. C. Srivastava ◽  
S. K. Srivastava ◽  
Suman B. Sharma
Keyword(s):  
Molecular Weight ◽  
Molar Conductance ◽  
H Nmr ◽  
Elemental Analyses

The halogenodephenylation of Ph3,SnX (X = NCO, NCS, and N3) with IX′ (X′ = Cl and/or Br) yielded new Ph2Sn(X)X′ and PhI. The diphenyltin mixed halide pseudohalides have been characterised by elemental analyses, molar conductance, molecular weight, tic data, ir, and 1H nmr spectral studies.Ph2Sn(NCS)Br with DMSO forms Ph2Sn(NCS)Br•2DMSO complex.

Photoluminescent Tetrazolate-based Eu(III) Complexes: An Outstanding Impact of Aromatic Phosphine Oxide Co-ligands on the Photoluminescence Quantum Yields

2014 ◽  
Vol 69 (2) ◽  
pp. 239-247 ◽  
Author(s):  
Marek Pietraszkiewicz ◽  
Suraj Mal ◽  
Oksana Pietraszkiewicz ◽  
Krzysztof Górski ◽  
Nitin Chelwani
Keyword(s):  
Phosphine Oxide ◽  
Elemental Analysis ◽  
Analytical Data ◽  
Quantum Yields ◽  
Spectroscopic Techniques ◽  
Ancillary Ligands ◽  
H Nmr ◽  
Luminescence Efficiency ◽  
The Eu ◽  
Oxygen Atoms

New ternary Eu(III) 5-(2-pyridyl-1-oxide)tetrazolate complexes with phosphine oxide co-ligands have been synthesized and characterized by elemental analysis, and IR and 1H NMR spectroscopic techniques. The analytical data revealed that these complexes are mononuclear, and the central Eu(III) ion is coordinated by three oxygen and three nitrogen atoms of the tetrazolate and two oxygen atoms from the phosphine oxide ligands. The ancillary ligands increased remarkably the luminescence efficiency of the Eu(III) tetrazolate.

scholarly journals Synthesis, characterization and photoinduced curing of polysulfones with (meth)acrylate functionalities

2010 ◽  
Vol 6 ◽  
Author(s):  
Cemil Dizman ◽  
Sahin Ates ◽  
Lokman Torun ◽  
Yusuf Yagci
Keyword(s):  
Molecular Weight ◽  
Thermal Properties ◽  
Thermal Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
Condensation Polymerization ◽  
Thermal Gravimetric ◽  
Uv Curable ◽  
H Nmr ◽  
Rate Of Polymerization ◽  
Photo Curing

The UV-curable telechelic polysulfones with (meth)acrylate functionalities were synthesized by condensation polymerization and subsequent esterification. The final polymers and intermediates at various stages were characterized by 1H NMR, FT-ATR, and GPC. The oligomeric films prepared from the appropriate solutions containing these telechelics and 2,2-dimethoxy-2-phenylacetophenone (DMPA) as the photoinitiator undergo rapid polymerization upon irradiation forming insoluble networks. The photo-curing behavior was investigated by photo-DSC and the effects of the molecular weight of the polysulfone precursor and type of functionality on the rate of polymerization and conversion were evaluated. Thermal properties of the photochemically cured films were studied by differential scanning calorimeter (DSC) and thermal gravimetric analysis (TGA).

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