13C-NMR spectra of aldoses in molybdate complexes

1980 ◽  
Vol 45 (1) ◽  
pp. 123-126 ◽  
Author(s):  
Juraj Alföldi ◽  
Vojtech Bílik ◽  
Ladislav Petruš
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
Hydroxyl Groups ◽  
13C Nmr Spectra ◽  
C Nmr

Analysis of 13C-NMR spectra has shown that ribose, talose and allose behave as trident donors in their molybdate complexes using hydroxyl groups at C(2), C(3) and C(4), whereas lyxose and mannose use hydroxyl groups at C(1), C(2) and C(3).

13C NMR spectra of hydroxy adamantanes additivity in 13C NMR spectra of dihydroxyadamantanes

1979 ◽  
Vol 44 (7) ◽  
pp. 2230-2237 ◽  
Author(s):  
Jan Schraml ◽  
Harald Jancke ◽  
Günter Engelhardt ◽  
Luděk Vodička ◽  
Josef Hlavatý
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
Chemical Shifts ◽  
Hydroxyl Groups ◽  
13C Nmr Spectra ◽  
Limited Information ◽  
Adamantane Skeleton ◽  
Cyclic Compounds ◽  
Intramolecular Hydrogen ◽  
C Nmr

The 13C NMR spectra of all monohydroxy and ditopic dihydroxy adamantane isomers were measured and the lines assigned. The numbers of the isomers and of the non-equivalent carbon atoms permitted a verification of the simple additivity of the shielding contributions of two hydroxyl groups on the rigid adamantane skeleton in the isomers without a possibility of a direct OH-OH interaction. If such interactions occur, deviations are found. The direction and magnitude of the deviations is in agreement with the current interpretation of 13C chemical shifts in other classes of cyclic compounds. It is concluded that the deviations are not caused by intramolecular hydrogen bonds. The deviations and the values of substituent chemical shifts offer some limited information about the origin of the shielding effects, especially of those dependent on stereochemistry and degree of substitution (γanti effect).

13C NMR spectra of 1-aryl-ferrocenylethylenes

1986 ◽  
Vol 51 (3) ◽  
pp. 670-676 ◽  
Author(s):  
Eva Solčániová ◽  
Štefan Toma ◽  
Tibor Liptaj
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
Substituent Effects ◽  
13C Nmr Spectra ◽  
Bridge Group ◽  
C Nmr ◽  
Electron Effects

13C NMR spectra of 18 ferrocene analogues of trans stilbenes (1-aryl-2-ferrocenylethylenes) were measured. It was found that bridge group weakens the transfer of the substituent electron effects into ferrocene nucleus, especially distinctly into 3',4'positions of cyclopentadienyl ring. The transfer of substituent effects into β-position of the bridge -CH=CH- is greater in derivatives studied by us than in stilbenes. Synthesis of 1-(4-dimethylaminophenyl)-2-ferrocenylethylene is described.

17O and 13C NMR spectra of some geminal diacetates

1988 ◽  
Vol 53 (3) ◽  
pp. 588-592 ◽  
Author(s):  
Antonín Lyčka ◽  
Josef Jirman ◽  
Jaroslav Holeček
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
Chemical Shifts ◽  
The Other ◽  
13C Nmr Spectra ◽  
Other Hand ◽  
Carboxylic Esters ◽  
C Nmr ◽  
Oxygen Atoms

The 17O and 13C NMR spectra of eight geminal diacetates RCH(O(CO)CH3)2 derived from simple aldehydes have been measured. In contrast to the dicarboxylates R1R2E(O(CO)R3)2, where E = Si, Ge, or Sn, whose 17O NMR spectra only contain a single signal, and, on the other hand, in accordance with organic carboxylic esters, the 17O NMR spectra of the compound group studied always exhibit two well-resolved signals with the chemical shifts δ(17O) in the regions of 183-219 ppm and 369-381 ppm for the oxygen atoms in the groups C-O and C=O, respectively.

Proximity and conformation effects in 29Si and 13C NMR spectra of di-ortho substituted trimethylsiloxybenzenes

1990 ◽  
Vol 55 (8) ◽  
pp. 2027-2032 ◽  
Author(s):  
Jan Schraml ◽  
Robert Brežný ◽  
Jan Čermák
Keyword(s):  
Benzene Ring ◽  
13C Nmr ◽  
Proximity Effect ◽  
Nmr Spectra ◽  
Methoxy Group ◽  
Chemical Shifts ◽  
Proximity Effects ◽  
13C Nmr Spectra ◽  
Methoxy Groups ◽  
C Nmr

29Si and 13C NMR spectra of five 4-substituted 2,6-dimethoxytrimethylsiloxybenzenes were studied with the aim to elucidate the nature of the deshielding proximity effects observed in the spectra of ortho substituted trimethylsiloxybenzenes. The sensitivity of 29Si chemical shifts to para substitution is in the studied compounds essentially the same as in mono ortho methoxytrimethylsiloxybenzenes. The deshielding proximity effect of the ìsecondî methoxy group is somewhat smaller than that of the ìfirstî group. The present results indicate that the two methoxy groups assume coplanar conformations with the benzene ring and are turned away from the trimethylsiloxy group which is not in the benzene plane. It is argued that in mono ortho methoxytrimethylsiloxybenzenes the two substituent groups adopt the same conformations as in the compounds studied here.

scholarly journals The NMR Spin Systems of Scutellaria 8β,13-Epoxy-neo-clerod-3-en-15,16-olides and Revision of 1H and 13C NMR Spectra Reported Data

2020 ◽  
Vol 15 (10) ◽  
pp. 1934578X2093378
Author(s):  
Josep Coll Toledano
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
Spin Systems ◽  
13C Nmr Spectra ◽  
1H And 13C Nmr ◽  
Nmr Data ◽  
Reported Data ◽  
New Compounds ◽  
C Nmr ◽  
Shielding Effects

The present review of NMR spectroscopic structural elucidation data of new compounds isolated from Scutellaria species is focused on the title compounds, displaying a peculiar 13-spiro feature. It contains a compilation of 1H and 13C NMR data of these diterpenoids grouped by similar substitution patterns. Comparing shielding effects pointed out not only the identity of some compounds (already reported) but also potential misassignments and convenient revisions to get unambiguous structural proposals.

scholarly journals 1H- und C-NMR-Spektren von Methoxy-substituierten Äthylenen / 1H and 13C NMR Spectra of Methoxy-substituted Ethylenes

1976 ◽  
Vol 31 (1) ◽  
pp. 35-38 ◽  
Author(s):  
M. Herberhold ◽  
G. O. Wiedersatz ◽  
C. G. Kreiter
Keyword(s):  
Charge Distribution ◽  
Vinyl Ether ◽  
13C Nmr ◽  
Nmr Spectra ◽  
13C Nmr Spectra ◽  
1H And 13C Nmr ◽  
Methyl Vinyl ◽  
Methyl Vinyl Ether ◽  
Cis And Trans ◽  
C Nmr

The charge distribution in the methoxy -substituted olefins of the series ethylene, methyl vinyl ether, 1,1-dimethoxyethylene, cis- and trans-dimethoxyethylene, tetramethoxyethylene, is discussed on the basis of the 1H and 13C NMR spectra

13C-NMR-Spektren einiger Acridon-Derivate [1] / 13C NMR Spectra of Some Acridone Derivatives [1]

1979 ◽  
Vol 34 (3) ◽  
pp. 516-519 ◽  
Author(s):  
I. Mester ◽  
D. Bergenthal ◽  
Zs. Rózsa ◽  
J. Reisch
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
13C Nmr Spectra ◽  
Acridone Derivatives ◽  
C Nmr

Abstract The 13C NMR spectra of acridone derivatives 3-5, 8-12, melicopicine (14), melicopidine (15) and melicopine (16) are presented. The substituent parameters for OH and OCH3 groups in acridone derivatives have also been given.

29Si (and 13C) NMR spectra of all pertrimethylsilylated O-acetyl and O-benzoyl 1,6-anhydro-β-D-glucopyranose derivatives. A test of empirical assignment rules

1985 ◽  
Vol 50 (5) ◽  
pp. 1176-1183 ◽  
Author(s):  
Jan Schraml ◽  
Štefan Kučár ◽  
Jan Zelený ◽  
Václav Chvalovský
Keyword(s):  
13C Nmr ◽  
Nmr Spectra ◽  
Chemical Shifts ◽  
13C Nmr Spectra ◽  
Rule Based ◽  
C Nmr

All O-acetyl-1,6-anhydro-β-D-glucopyranoses and O-benzoyl-1,6-anhydro-β-D-glucopyranoses were pertrimethylsilylated. 29Si and 13C NMR spectra of the pertrimethylsilyl derivatives were measured and the 29Si chemical shifts were used to test two previously described empirical assignment rules. The rule based on the shielding order must be either restricted to the order δ(Si-2) > δ(Si-4) which holds for all the studied compounds or modified for each subclass of the studied compounds with the same O-substituents. The rule based on Hammett type dependence gives correct predictions for Si-3 chemical shifts. When both rules can be applied they yield identical assignments, in other cases they complement each other.

Stoffwechselprodukte von Mikroorganismen, XXIX [1] 13C-NMR-Spektren hochsubstituierter Naturstoffe vom Phthalid-Typ / Investigations on Metabolites of Microorganisms, XXIX [1] 13C NMR Spectra of Highly Substituted Natural Products of the Phthalide Type

1985 ◽  
Vol 40 (3) ◽  
pp. 426-428 ◽  
Author(s):  
Hans Achenbach ◽  
Andreas Mühlenfeld ◽  
Dieter Hunkler
Keyword(s):  
Natural Products ◽  
13C Nmr ◽  
Structure Elucidation ◽  
Nmr Spectra ◽  
13C Nmr Spectra ◽  
Substituted Benzenes ◽  
C Nmr

Since the usual 13C shift increments are not applicable for very highly substituted benzenes, the 13C NMR spectra of 3-O-ethyl-cyclopolic acid (1) and 2 were studied and fully analyzed. These results were essential for the structure elucidation of a number of new highly substituted phthalides recently isolated from cultures of Aspergillus duricaulis [3].

Sign in / Sign up

Export Citation Format

Share Document