Kinetics of precipitation of sparingly soluble inorganic salts

1972 ◽  
Vol 37 (5) ◽  
pp. 1445-1449 ◽  
Author(s):  
O. Söhnel
1965 ◽  
Vol 87 (6) ◽  
pp. 1414-1414
Author(s):  
Silvester Liotta

2010 ◽  
Vol 81 (1) ◽  
pp. 64-73 ◽  
Author(s):  
B. Sonderegger ◽  
E. Kozeschnik ◽  
H. Leitner ◽  
H. Clemens ◽  
J. Svoboda ◽  
...  

2007 ◽  
Vol 561-565 ◽  
pp. 2275-2278 ◽  
Author(s):  
Maribel L. Saucedo-Muñoz ◽  
Victor M. Lopez-Hirata

Three types of austenitic stainless steels JK2, JJ1 and JN1 were isothermally aged at temperatures from 873 to 1173 K for 10 to 1000 minutes in order to study the microstructural evolution. In general, the kinetics of precipitation for JN1 steel was faster than that of JJ1 steel, because of its higher interstitial solute content. The TTP diagrams showed that the intergranular precipitation of M23C6 and M2N preceded to the intragranular precipitation of M2N and M2N and η phase in JN1 and JJ1 steels, respectively.


2014 ◽  
Vol 12 (12) ◽  
pp. 1294-1303 ◽  
Author(s):  
Vladimir Beliy ◽  
Elena Udoratina

AbstractThe purpose of this work was to study the kinetics of wood pyrolysis in the presence of inorganic salts, representatives of classes of alkali and alkaline earth metal halides (NaCl, KCl, KBr, CaCl2, BaCl2·2H2O) and Lewis acids (AlCl3·6H2O, FeCl3·6H2O, CuCl2, CuBr2, ZnCl2·1.5H2O, NiCl2·6H2O, SnCl2·2H2O) using TG-DSC. The activity of these catalysts was estimated by the temperature of the beginning of pyrolysis, charcoal yield and kinetic parameters, such as energy of activation and reaction order. Using the Lewis acids as catalysts for pyrolysis leads to a decrease in the temperature of the process beginning and the activation energy. In the presence of other catalysts activation energy does not significantly change. The increase of a seeming reaction order in the presence of Lewis acids possibly is a consequence of complication of the thermodestruction mechanism, with the appearance of new parallel competing stages.


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