Heats of mixing of normal paraffin hydrocarbons with cyclohexane, application of the quasi-lattice theory

1969 ◽  
Vol 34 (6) ◽  
pp. 1792-1796 ◽  
Author(s):  
F. Veselý ◽  
J. Pick
1963 ◽  
Vol 41 (2) ◽  
pp. 278-286 ◽  
Author(s):  
B. Dacre ◽  
G. C. Benson

Values of heats of mixing are reported for methanol, n-butanol, and n-octanol with carbon tetrachloride at 25 °C. The experimental results are combined with data from other sources and an analysis of the excess thermodynamic functions for carbon tetrachloride solutions of methanol, ethanol, n-propanol, n-butanol, and n-octanol in terms of Barker's theory of solutions is described. The behavior of these systems can be reproduced fairly well by the Barker model.


1967 ◽  
Vol 45 (1) ◽  
pp. 22-24 ◽  
Author(s):  
Hoskyns K. Deq. Jones ◽  
David P. L. Poon ◽  
R. F. Lama ◽  
Benjamin C.-Y. Lu

1961 ◽  
Vol 65 (2) ◽  
pp. 335-338 ◽  
Author(s):  
J. R. Goates ◽  
R. L. Snow ◽  
M. R. James

1978 ◽  
Vol 43 (3) ◽  
pp. 837-847 ◽  
Author(s):  
Julius Pouchlý ◽  
Antonín Živný ◽  
Ján Biroš

1978 ◽  
Vol 43 (3) ◽  
pp. 829-836 ◽  
Author(s):  
Ján Biroš ◽  
Antonín Živný ◽  
Julius Pouchlý

1984 ◽  
Vol 49 (6) ◽  
pp. 1334-1341 ◽  
Author(s):  
František Veselý ◽  
Vladimír Dohnal ◽  
Miriam Valentová ◽  
Jiří Pick

Three models of continuously associated solution complemented by an assumption of polynomial temperature dependence of corresponding interaction parameters were used for simultaneous description of the concentration and temperature dependence of heats of mixing of 1-butanol, 2-butanol and 2-methyl-2-propanol with cyclohexane. Very good results were reached for the first two systems where the Liebermann and Wilhelm model has proved to be the most suitable. With respect to the probable existence of cyclic associates in solutions of 2-methyl-2-propanol, none of the used models which assume only linear association satisfied to the extent required.


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