Kinetics and mechanism of sulphur dioxide oxidation on a vanadium catalyst. III. Correlation of the data with equations derived for the reduction-oxidation mechanism

1968 ◽  
Vol 33 (8) ◽  
pp. 2540-2547 ◽  
Author(s):  
A. Regner ◽  
A. Šimeček
Keyword(s):  
Sulphur Dioxide ◽  
Oxidation Mechanism ◽  
Kinetics And Mechanism ◽  
Vanadium Catalyst

scholarly journals Kinetics and mechanism of the oxidation of dithiocarbamic acids in the presence of Co(II) phthalocyaninetetacarboxylic acid

2016 ◽  
Vol 81 (9) ◽  
pp. 1025-1036 ◽  
Author(s):  
Artur Vashurin ◽  
Ilya Kuzmin ◽  
Vladimir Mayzlish ◽  
Mikhail Razumov ◽  
Oleg Golubchikov ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Kinetic Data ◽  
Great Influence ◽  
Oxidation Mechanism ◽  
Kinetics And Mechanism ◽  
Sodium Diethyldithiocarbamate ◽  
Reduced Form ◽  
Self Association

Present work contains kinetic data of oxidation of sodium diethyldithiocarbamate in presence of phthalocyanine catalysts. It is shown that nature of peripheral substituent has a great influence on self-association of phthalocyanines and on its catalytic activity. Oxidation mechanism of sodium diethyldithiocarbamate involving formation of triple complex of substrate, reduced form of catalyst and oxygen is offered. It is also shown that oxidation mechanism of dithiocarbamic acids is different than for cysteine.

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