Modelling of chemical reactors. II. Tubular non-isothermal, non-adiabatic packed bed reactor; Problems in the design of a reactor with radial heat transfer for the reaction A → B

1967 ◽  
Vol 32 (9) ◽  
pp. 3309-3333 ◽  
Author(s):  
M. Marek ◽  
V. Hlaváček
Author(s):  
Elvis E. Dominguez-Ontiveros ◽  
Carlos Estrada-Perez ◽  
Yassin A. Hassan

In the Advanced Gas Cooled Pebble Bed Reactors for nuclear power generation, the fuel is spherical coated particles. The energy transfer phenomenon requires detailed understanding of the flow and temperature fields around the spherical fuel pebbles. Detailed information of the complex flow structure within the bed is needed. Generally, for computing the flow through a packed bed reactor or column, the porous media approach is usually used with lumped parameters for hydrodynamic calculations and heat transfer. While this approach can be reasonable for calculating integral flow quantities, it may not provide all the detailed information of the heat transfer and complex flow structure within the bed. The present experimental study presents the full velocity field using particle image velocity technique (PTV) in a conjunction with matched refractive index fluid with the pebbles to achieve optical access. Velocity field measurements are presented delineating the complex flow structure.


2019 ◽  
Author(s):  
Nasser Vahedi ◽  
Alparslan Oztekin

Abstract The new generation of Concentrated Solar Power (CSP) plants requires high temperature and high energy density storage system with good cyclic stability. The potential solution satisfying such requirements is the thermochemical energy storage (TCES) using gas-solid redox reaction. Design of efficient storage reactor is very critical for applications of such storage systems. Packed bed reactors have a simpler design with no moving components and are more cost-effective compared to other available moving bed design configurations while having high-pressure drop is their main drawback. Any improvement in the pressure drop makes the design more suitable for commercial applications, especially at high temperature operating conditions. Cobalt oxide redox reaction has been considered for this study because of its unique features, especially high enthalpy of reaction (energy density) and high reaction temperature. A rectangular cross-section packed bed reactor with a large aspect ratio is selected as a reference conventional packed bed reactor. The novel split-flow packed bed reactor design configuration is proposed in which a portion of heat transfer fluid is passed through adjacent side channels. The split flow ratio of 1/3 has been considered for the case study. The transient two-dimensional numerical model is developed for solving mass, momentum, and energy equations for both gas and solid phases using suitable reaction kinetics for the reversible reduction and re-oxidation process. Complete storage cycle, including both the charging and discharging mode, has been simulated using finite element method. The split flow design performance is compared with the reference case considering the same size of the reaction bed. It is shown that the conversion time is increased while the pressure drop reduced below half of the pressure loss of the conventional design. Reduced mass flow rate passing through the bed results in considerable improvement in required pressure work with a penalty of storage performance. Further study is needed to optimize the split flow ratio and the surface heat transfer characteristics of the bed. The proposed design configuration could be a breakthrough in packed bed reactors, especially for high-temperature storage applications.


2018 ◽  
Vol 178 ◽  
pp. 367-376 ◽  
Author(s):  
Srinivas Krishnaswamy ◽  
Amol Deshpande ◽  
K.N. Ponnani

AIChE Journal ◽  
2011 ◽  
Vol 58 (1) ◽  
pp. 256-267 ◽  
Author(s):  
Estevan Tioni ◽  
Roger Spitz ◽  
J. P. Broyer ◽  
Vincent Monteil ◽  
Timothy McKenna

Author(s):  
Laércio G. Oliveira ◽  
Ramdayal Swarnakar ◽  
Antonio G. B. de Lima

The fixed-bed reactors of circular cylindrical geometry with heated or cooled walls are frequently used to carry out heterogeneous reactions of solid-gas type in engineering applications. The design of a fixed bed reactor requires an extensive knowledge of heat transfer characteristics within the packed bed. In this sense, this work presents a three-dimensional mathematical model to predict the heat transfer inside a fixed bed elliptical cylinder heat exchanger. The model considers uniform velocity and temperature profiles of the fluid phase at the entrance of the reactor, and constant thermo-physical properties. The surface of the equipment convective boundary condition is assumed to be constant. The energy equation, written in the elliptical cylindrical coordinates, was discretized using a finite-volume method considering a fully implicit formulation, and WUDS interpolation scheme. Numerical results of the dimensionless temperature profiles inside the packed bed reactor at a steady state are presented and temperature distribution is interpreted. To validate the model, numerical results obtained for the circular cylinder are compared with analytical results from literature and a good agreement was obtained.


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