Yields of elementar iodine after the irradiation of alkyl iodides by electrons

1963 ◽  
Vol 28 (5) ◽  
pp. 1338-1341 ◽  
Author(s):  
K. Svoboda
Keyword(s):  
Alkyl Iodides

scholarly journals Enantioselective Radical Addition/Cross‐Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents

2019 ◽  
Vol 58 (40) ◽  
pp. 14245-14249 ◽  
Author(s):  
Matteo Chierchia ◽  
Peilin Xu ◽  
Gabriel J. Lovinger ◽  
James P. Morken
Keyword(s):  
Cross Coupling ◽  
Radical Addition ◽  
Alkyl Iodides ◽  
Organozinc Reagents

A Facile Procedure for the Direct Conversion of Ethers to Alkyl Iodides

1988 ◽  
Vol 18 (2) ◽  
pp. 119-124 ◽  
Author(s):  
Hsing-Jang Liu ◽  
Virginia Wiszniewski
Keyword(s):  
Direct Conversion ◽  
Alkyl Iodides

Organometallics in prostaglandin synthesis

1988 ◽  
Vol 326 (1592) ◽  
pp. 579-585 ◽  
Keyword(s):  
Conjugate Addition ◽  
Prostaglandin Synthesis ◽  
Side Chain ◽  
Prostaglandin E ◽  
Controlled Synthesis ◽  
One Pot ◽  
Naturally Occurring ◽  
Chain Unit ◽  
Alkyl Iodides

An extremely short way to prostaglandins has been opened by combining the newly devised organometallic methodologies. Convergent, one-pot creation of the prostanoid framework is achieved by organocopper conjugate addition of the S-configurated ω-side-chain unit to (R)-4-trialkylsiloxy-2-cyclopentenone followed by the organotin-aided trapping of the enolate intermediate by α-side-chain alkyl iodides. Prostaglandin E 2 can be prepared in only three steps from the chiral building units. The protected 5,6-didehydro-PGE 2 derivatives thus obtained serve as common intermediates for the synthesis of a variety of naturally occurring prostaglandins including prostacyclin. This approach is also useful for the controlled synthesis of isocarbacyclin.

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