Thermal expansion and thermal conductivity of single-crystal CuxAg1−x InS2 solid solutions grown by the moving solvent method

2005 ◽  
Vol 50 (9) ◽  
pp. 1178-1181
Author(s):  
I. V. Bodnar ◽  
L. V. Yasyukevich
2018 ◽  
Vol 60 (12) ◽  
pp. 2672-2677
Author(s):  
M. A. Borik ◽  
A. V. Kulebyakin ◽  
E. E. Lomonova ◽  
V. A. Myzina ◽  
P. A. Popov ◽  
...  

2019 ◽  
Vol 61 (12) ◽  
pp. 2390
Author(s):  
М.А. Борик ◽  
А.В. Кулебякин ◽  
И.Е. Курицына ◽  
Е.Е. Ломонова ◽  
В.А. Мызина ◽  
...  

Abstract The thermal conductivity of single-crystal solid solutions (ZrO_2)_1 – _ x  _– _ y  _– _ z (Sc_2O_3)_ x (CeO_2)_ y (Y_2O_3)_ z ( x = 0.08–0.10; y = 0.005–0.01; z = 0–0.005) was measured in the temperature range 50–300 K. Phase composition and defective structure of crystals were studied.


2019 ◽  
Vol 61 (12) ◽  
pp. 2397-2402
Author(s):  
M. A. Borik ◽  
A. V. Kulebyakin ◽  
I. E. Kuritsyna ◽  
E. E. Lomonova ◽  
V. A. Myzina ◽  
...  

2012 ◽  
Vol 54 (3) ◽  
pp. 658-661 ◽  
Author(s):  
P. A. Popov ◽  
V. D. Solomennik ◽  
E. E. Lomonova ◽  
M. A. Borik ◽  
V. A. Myzina

Author(s):  
Sergey Volkov ◽  
Rimma Bubnova ◽  
Nadezhda Bolotina ◽  
Maria Krzhizhanovskaya ◽  
Olga Belousova ◽  
...  

Crystal structures of Sr3B2 + xSi1 − xO8 − x/2solid solutions with nominal compositionsx= 0.28, 0.53, 0.78 in the Sr3B2SiO8–Sr2B2O5section of the SrO–B2O3–SiO2system are refined using single-crystal X-ray diffraction data. Incommensurate structure modulations are mainly associated with various orientations of corner-sharing (B,Si)-polyhedra. Preference is given to the (3 + 2)-dimensional symmetry groupPnma(0βγ)000(0{\rm{\bar \beta }}γ)000 for a single crystal compared with an alternate model of a twin formed by monoclinic components, each of them corresponding to the (3 + 1)-dimensional symmetry groupP21/n(0βγ). Single-phase polycrystalline samples of solid solutions are investigated by high-temperature X-ray powder diffraction in air. Orientation preferences of the BO3units lead to a strong anisotropy of thermal expansion. Negative expansion is observed along theaaxis over the temperature range 303–753 K. Anisotropy decreases both on heating and decreasing of the boron content.


2000 ◽  
Vol 626 ◽  
Author(s):  
Antje Mrotzek ◽  
Kyoung-Shin Choi ◽  
Duck-Young Chung ◽  
Melissa A. Lane ◽  
John R. Ireland ◽  
...  

ABSTRACTWe present the structure and thermoelectric properties of the new quaternary selenides K1+xM4–2xBi7+xSe15 (M = Sn, Pb) and K1-xSn5-xBi11+xSe22. The compounds K1+xM4-2xBi7+xSe15 (M= Sn, Pb) crystallize isostructural to A1+xPb4-2xSb7+xSe15 with A = K, Rb, while K1-xSn5-xBi11+xSe22 reveals a new structure type. In both structure types fragments of the Bi2Te3-type and the NaCl-type are connected to a three-dimensional anionic framework with K+ ions filled tunnels. The two structures vary by the size of the NaCl-type rods and are closely related to β-K2Bi8Se13 and K2.5Bi8.5Se14. The thermoelectric properties of K1+xM4-2xBi7+xSe15 (M = Sn, Pb) and K1-xSn5-xBi11+xSe22 were explored on single crystal and ingot samples. These compounds are narrow gap semiconductors and show n-type behavior with moderate Seebeck coefficients. They have very low thermal conductivity due to an extensive disorder of the metal atoms and possible “rattling” K+ ions.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Yoshihiko Imanaka ◽  
Toshihisa Anazawa ◽  
Fumiaki Kumasaka ◽  
Hideyuki Jippo

AbstractTailored material is necessary in many industrial applications since material properties directly determine the characteristics of components. However, the conventional trial and error approach is costly and time-consuming. Therefore, materials informatics is expected to overcome these drawbacks. Here, we show a new materials informatics approach applying the Ising model for solving discrete combinatorial optimization problems. In this study, the composition of the composite, aimed at developing a heat sink with three necessary properties: high thermal dissipation, attachability to Si, and a low weight, is optimized. We formulate an energy function equation concerning three objective terms with regard to the thermal conductivity, thermal expansion and specific gravity, with the composition variable and two constrained terms with a quadratic unconstrained binary optimization style equivalent to the Ising model and calculated by a simulated annealing algorithm. The composite properties of the composition selected from ten constituents are verified by the empirical mixture rule of the composite. As a result, an optimized composition with high thermal conductivity, thermal expansion close to that of Si, and a low specific gravity is acquired.


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