scholarly journals A new kind of invisible gold in pyrite hosted in deformation-related dislocations

Geology ◽  
2021 ◽  
Author(s):  
Denis Fougerouse ◽  
Steven M. Reddy ◽  
Mark Aylmore ◽  
Lin Yang ◽  
Paul Guagliardo ◽  
...  

Mining of “invisible gold” associated with sulfides in gold ores represents a significant proportion of gold production worldwide. Gold hosted in sulfide minerals has been proposed to be structurally bound in the crystal lattice as a sulfide-gold alloy and/or to occur as discrete metallic nanoparticles. Using a combination of microstructural quantification and nanoscale geochemical analyses on a pyrite crystal from an orogenic gold deposit, we show that dislocations hosted in a deformation low-angle boundary can be enriched in Ni, Cu, As, Pb, Sb, Bi, and Au. The cumulative trace-element enrichment in the dislocations is 3.2 at% higher compared to the bulk crystal. We propose that trace elements were segregated during the migration of the dislocation following the dislocation-impurity pair model. The gold hosted in nanoscale dislocations represents a new style of invisible gold.

2017 ◽  
Author(s):  
Cigdem Yucel ◽  
◽  
Sebnem Arslan ◽  
Sebnem Arslan ◽  
Mehmet Celik ◽  
...  

2010 ◽  
Vol 60 (4) ◽  
pp. 620-626 ◽  
Author(s):  
Annabelle F. Keene ◽  
Scott G. Johnston ◽  
Richard T. Bush ◽  
Edward D. Burton ◽  
Leigh A. Sullivan

Nature ◽  
1993 ◽  
Vol 362 (6416) ◽  
pp. 184-184 ◽  
Author(s):  
Alex N. Halliday ◽  
Gareth R. Davies ◽  
Der-Chuen Lee ◽  
Simone Tommasini ◽  
Cassi R. Paslick ◽  
...  

1992 ◽  
Vol 29 (2) ◽  
pp. 353-372 ◽  
Author(s):  
D. Pillet ◽  
M. Chenevoy ◽  
M. Bélanger

The Lake Brisson peralkaline granite in Labrador, which by way of its age of 1189 Ma is the most recent phase of the Gardar magmatic stage, was intruded in the Middle Proterozoic at the margin of a granulitic complex, retrograded to an amphibolite facies during Aphebian, and of an Elsonian adamellite pluton. It shows a petrographie zonation ("feldspathic" facies at the center, "quartzose" facies including early quartz at the edge) suggestive of a permissive multiphase intrusion, and is characterized by deuteritic alteration via metalliferous fluids (Zr, Y, Nb, Be; rare earths). All facies are Na-peralkaline, well evolved, and represent end-members of a differentiated magmatic suite of the designated A type. The relative behavior of the major elements indicates that the facies differentiation was controlled by fractional crystallization and was also greatly influenced by alkaline feldspath and by increase of f(O2) in the final stage of evolution. The trace elements contents, significantly higher than those reported for other peralkaline complexes, are a confirmation of the influence of fractional crystallization. The unsual trace element enrichment in an altered quartzose facies is the result of the effects of a final oxidizing fluid phase, rich in F; the relative depletion of Na and the enrichment in Sr and Ca of the fluid are explained by its having been contaminated by the wall rocks. [Journal Translation]


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Simona Ferrando ◽  
Maurizio Petrelli ◽  
Maria Luce Frezzotti

Abstract The geochemical signature of magmas generated at convergent margins greatly depends on the nature of fluids and melts released during subduction. While major- and trace-elements transport capacity of ultrahigh pressure (UHP) hydrous-silicate melts has been investigated, little is known about solute enrichment and fractionation in UHP (>3.5–4 GPa) solute-rich aqueous fluids released along colder geothermal gradients. Here, we performed in situ LA-ICP-MS trace-element analyses on selected UHP prograde-to-peak fluid inclusions trapped in a kyanite-bearing quartzite from Sulu (China). The alkali-aluminosilicate-rich aqueous fluid released from the meta-sediments by dehydration reactions is enriched in LILE, U, Th, Sr, and REE. Inclusions trapped at increasing temperature (and pressure) preserve a gradual and selective trace-element enrichment resulting from the progressive dissolution of phengite and carbonate and the partial dissolution of allanite/monazite. We show that, at the investigated P-T conditions, aqueous fluids generated by dissolution of volatile-bearing minerals fractionate trace-element distinctly from hydrous-silicate melts, regardless of the source lithology. The orogenic/post-orogenic magmas generated in a mantle enriched by metasomatic processes involving either solute-rich aqueous fluids or hydrous-silicate melts released by the slab at UHP conditions can preserve evidence of the nature of these agents.


Author(s):  
D.E. LEYDEN ◽  
W. WEGSCHEIDER ◽  
W.B. BODNAR ◽  
E.D. SEXTON ◽  
W.K. NONIDEZ

Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 897 ◽  
Author(s):  
Diego Medina ◽  
Corby G. Anderson

Globally, copper, silver, and gold orebody grades have been dropping, and the mineralogy surrounding them has become more diversified and complex. The cyanidation process for gold production has remained dominant for over 130 years because of its selectivity and feasibility in the mining industry. For this reason, the industry has been adjusting its methods for the extraction of gold, by utilizing more efficient processes and technologies. Often, gold may be found in conjunction with copper and silver in ores and concentrates. Hence, the application of cyanide to these types of ores can present some difficulty, as the diversity of minerals found within these ores can cause the application of cyanidation to become more complicated. This paper outlines the practices, processes, and reagents proposed for the effective treatment of these ores. The primary purpose of this review paper is to present the hydrometallurgical processes that currently exist in the mining industry for the treatment of silver, copper, and gold ores, as well as concentrate treatments. In addition, this paper aims to present the most important challenges that the industry currently faces, so that future processes that are both more efficient and feasible may be established.


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