Phosphorus, nitrogen, and the redox evolution of the Paleozoic oceans

Geology ◽  
2005 ◽  
Vol 33 (7) ◽  
pp. 573 ◽  
Author(s):  
Matthew R. Saltzman
Keyword(s):  
Elements ◽  
2020 ◽  
Vol 16 (3) ◽  
pp. 191-196 ◽  
Author(s):  
Christopher T. Reinhard ◽  
Noah J. Planavsky

The redox state of Earth’s atmosphere has undergone a dramatic shift over geologic time from reducing to strongly oxidizing, and this shift has been coupled with changes in ocean redox structure and the size and activity of Earth’s biosphere. Delineating this evolutionary trajectory remains a major problem in Earth system science. Significant insights have emerged through the application of redox-sensitive geochemical systems. Existing and emerging biogeochemical modeling tools are pushing the limits of the quantitative constraints on ocean–atmosphere redox that can be extracted from geochemical tracers. This work is honing our understanding of the central role of Earth’s biosphere in shaping the long-term redox evolution of the ocean–atmosphere system.


2021 ◽  
Vol 567 ◽  
pp. 110304
Author(s):  
Yu Zou ◽  
Gregory E. Webb ◽  
Fenghua Zhao ◽  
Dongna Liu ◽  
Hongwei Kuang ◽  
...  

2021 ◽  
Vol 352 (8) ◽  
pp. 579-588
Author(s):  
Frederic Moynier ◽  
David A. Fike ◽  
Gabrielle Menard ◽  
Woodward W. Fischer ◽  
John P. Grotzinger ◽  
...  

2015 ◽  
Vol 417 ◽  
pp. 148-162 ◽  
Author(s):  
C.A. Partin ◽  
A. Bekker ◽  
N.J. Planavsky ◽  
T.W. Lyons

2022 ◽  
Author(s):  
Xiaotong Ge ◽  
Daizhao Chen ◽  
Gongjing Zhang ◽  
Taiyu Huang ◽  
Mu Liu ◽  
...  

Nature ◽  
2007 ◽  
Vol 445 (7124) ◽  
pp. 194-197 ◽  
Author(s):  
Alain Burgisser ◽  
Bruno Scaillet
Keyword(s):  

2019 ◽  
Vol 530 ◽  
pp. 119318 ◽  
Author(s):  
Hengye Wei ◽  
Zhanwen Tang ◽  
Detian Yan ◽  
Jianguo Wang ◽  
Andrew P. Roberts

2020 ◽  
Vol 10 (4) ◽  
pp. 20190140 ◽  
Author(s):  
Noah J. Planavsky ◽  
Leslie J. Robbins ◽  
Balz S. Kamber ◽  
Ronny Schoenberg

Deciphering the role—if any—that free oxygen levels played in controlling the timing and tempo of the radiation of complex life is one of the most fundamental questions in Earth and life sciences. Accurately reconstructing Earth's redox history is an essential part of tackling this question. Over the past few decades, there has been a proliferation of research employing geochemical redox proxies in an effort to tell the story of Earth's oxygenation. However, many of these studies, even those considering the same geochemical proxy systems, have led to conflicting interpretations of the timing and intensity of oxygenation events. There are two potential explanations for conflicting redox reconstructions: (i) that free oxygen levels were incredibly dynamic in both time and space or (ii) that collectively, as a community—including the authors of this article—we have frequently studied rocks affected by secondary weathering and alteration (particularly secondary oxidation) while neglecting to address the impact of this alteration on the generated data. There are now multiple case studies that have documented previously overlooked secondary alteration, resolving some of the conflicting constrains regarding redox evolution. Here, an analysis of a large shale geochemistry database reveals significant differences in cerium (Ce) anomalies, a common palaeoredox proxy, between outcrop and drill core samples. This inconsistency provides support for the idea that geochemical data from altered samples are frequently published in the peer-reviewed literature. As individuals and a geochemical community, most of us have been slow to appreciate how pervasive the problem is but there are examples of other communities that have faced and met the challenges raised by such quality control crises. Further evidence of the high potential for alteration of deep-time geochemical samples, and recognition of the manner in which this may lead to spurious results and palaeoenvironmental interpretations, indicate that sample archiving, in publicly accessible collections needs to become a prerequisite for publication of new palaeoredox data. Finally, the geochemical community need to think about ways to implement additional quality control measures to increase the fidelity of palaeoredox proxy work.


1993 ◽  
Vol 101 (2) ◽  
pp. 245-257 ◽  
Author(s):  
James F. Kasting ◽  
David H. Eggler ◽  
Stuart P. Raeburn

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