scholarly journals Phytoplankton contributions to the trace-element composition of Precambrian banded iron formations

2017 ◽  
Vol 130 (5-6) ◽  
pp. 941-951 ◽  
Author(s):  
Kurt O. Konhauser ◽  
Leslie J. Robbins ◽  
Daniel S. Alessi ◽  
Shannon L. Flynn ◽  
Murray K. Gingras ◽  
...  
2020 ◽  
Author(s):  
Xiaohua Han ◽  
Elizabeth Tomaszewski ◽  
Ronny Schönberg ◽  
Yongxin Pan ◽  
James Byrne ◽  
...  

<p>There are longstanding and ongoing controversies about the abiogenic or biogenic origin of magnetite in banded iron formations (BIFs). The trace element composition of magnetite was proposed as a promising tracer for distinguishing biogenic from abiogenic magnetite, which, however, remains to be explored quantitatively. Here, we compared the partitioning of trace elements Zinc (Zn) and Nickel (Ni) in both abiogenic and biogenic magnetite produced either by an abiotic reaction of ferrihydrite with by Fe<sup>2+</sup><sub>aq</sub> or by Fe(III)-reducing bacteria <em>Shewanella oneidensis</em> MR-1. We compared the transformation of three different ferrihydrite (Fh) starting materials: 1) Control Fh without added trace elements, 2) ferrihydrite with co-precipitated Zn (ZnFh) and 3) ferrihydrite with co-precipitated Ni (NiFh) – both in either NaHCO<sub>3</sub> or HEPES buffer. We monitored Fe concentration and speciation in both aqueous and solid phases over time using the spectrophotometric ferrozine assay, analyzed Fh transformation products by Mössbauer spectroscopy as well as X-ray diffraction and quantified Zn and Ni in solution and in the minerals by iCAP-Qc quadrupole mass spectrometer after acidic dissolution of the minerals. In summary our results revealed that both Zn and Ni are much more depleted in abiogenic magnetite than those in biogenic magnetite, independent of whether magnetite was precipitated in NaHCO<sub>3</sub> or HEPES buffer. Although further analyses are needed, this suggests that the trace element distribution could be a chemical signature to distinguish biogenic from abiogenic magnetite in BIFs.</p>


2017 ◽  
Author(s):  
Ryan S. Jackson ◽  
◽  
Horton Newsom ◽  
Agnes Cousin ◽  
Valérie Payre ◽  
...  

2020 ◽  
Vol 58 (12) ◽  
pp. 1321-1330
Author(s):  
K. G. Sukhanova ◽  
S. G. Skublov ◽  
O. L. Galankina ◽  
E. V. Obolonskaya ◽  
E. L. Kotova

Author(s):  
Tereza Koláčková ◽  
Daniela Sumczynski ◽  
Vratislav Bednařík ◽  
Štěpán Vinter ◽  
Jana Orsavová ◽  
...  

2021 ◽  
pp. 104560
Author(s):  
N.R. Kendall ◽  
J. Smith ◽  
L.K. Whistance ◽  
S. Stergiadis ◽  
C Stoate ◽  
...  

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