Black phosphorus composites with engineered interfaces for high-rate high-capacity lithium storage

Science ◽  
2020 ◽  
Vol 370 (6513) ◽  
pp. 192-197 ◽  
Author(s):  
Hongchang Jin ◽  
Sen Xin ◽  
Chenghao Chuang ◽  
Wangda Li ◽  
Haiyun Wang ◽  
...  
Keyword(s):  
Solid Electrolyte Interphase ◽  
High Capacity ◽  
Black Phosphorus ◽  
High Rate ◽  
Lithium Storage ◽  
Covalent Bonds ◽  
Continuous Growth ◽  
Edge Reconstruction ◽  
Covalently Bonded ◽  
Li Ion

High-rate lithium (Li) ion batteries that can be charged in minutes and store enough energy for a 350-mile driving range are highly desired for all-electric vehicles. A high charging rate usually leads to sacrifices in capacity and cycling stability. We report use of black phosphorus (BP) as the active anode for high-rate, high-capacity Li storage. The formation of covalent bonds with graphitic carbon restrains edge reconstruction in layered BP particles to ensure open edges for fast Li+ entry; the coating of the covalently bonded BP-graphite particles with electrolyte-swollen polyaniline yields a stable solid–electrolyte interphase and inhibits the continuous growth of poorly conducting Li fluorides and carbonates to ensure efficient Li+ transport. The resultant composite anode demonstrates an excellent combination of capacity, rate, and cycling endurance.

Li-ion capacitors based on activated ferric oxide as an anode

2021 ◽  
pp. 1-18
Author(s):  
Xinhui Zhao ◽  
Qingqing Ren
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
Low Cost ◽  
Solid Electrolyte Interphase ◽  
Cycling Performance ◽  
Fe2o3 Nanoparticles ◽  
Energy Storage Devices ◽  
Lithium Storage ◽  
Continuous Growth ◽  
Li Ion

Abstract Low-cost Fe-based electrode materials for Li-ion energy storage devices attract lots of attention. In this work, porous Fe2O3 nanoparticles are synthesized by a simple route. Firstly, their lithium storage performance is investigated by assembling half-cell configurations with Li foil as the counter electrode. During initial dozens of cycles, capacities of Fe2O3 nanoparticles fall off rapidly, which is related to continuous growth of solid electrolyte interphase (SEI). Amazingly, the capacities show an upturn in extended cycles. The pseudocapacitance of activated capacities is revealed by executing cyclic voltammetry (CV) tests at various scan rates on 500-cycled Fe2O3 electrodes. Based on electrochemical results, we speculate this special cycling performance of Fe2O3 nanoparticles may be associated with reversible electrochemical processes of SEI under the catalysis of nano-size Fe. Further, 500-cycled Fe2O3 anodes are reassembled with activated carbon cathodes for Li-ion capacitors (LICs). The LICs show energy densities of 110 Wh kg−1 at power densities of 136 W kg−1, and 72.8% capacity retention after 3000 cycles at 2 A g−1. We report an interesting electrochemical behavior of porous Fe2O3 nanoparticles, and a high-performance LIC based on activated Fe2O3 as an anode. This work may offer a new understanding for lithium storage capacities of metal oxide anodes.

Controllable synthesis of Li3VO4/N doped C nanofibers toward high-capacity and high-rate Li-ion storage

2021 ◽  
pp. 138386
Author(s):  
Zhen Xu ◽  
Daobo Li ◽  
Jie Xu ◽  
Junlin Lu ◽  
Dongmei Zhang ◽  
...  
Keyword(s):  
High Capacity ◽  
High Rate ◽  
Controllable Synthesis ◽  
Ion Storage ◽  
Li Ion

Spinel/Layered Heterostructured Cathode Material for High-Capacity and High-Rate Li-Ion Batteries

2013 ◽  
Vol 25 (27) ◽  
pp. 3722-3726 ◽  
Author(s):  
Feng Wu ◽  
Ning Li ◽  
Yuefeng Su ◽  
Haofang Shou ◽  
Liying Bao ◽  
...  
Keyword(s):  
Cathode Material ◽  
High Capacity ◽  
High Rate ◽  
Li Ion Batteries ◽  
Li Ion

High-rate and long-life of Li-ion batteries using reduced graphene oxide/Co3O4 as anode materials

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24320-24330 ◽  
Author(s):  
Junkai He ◽  
Ying Liu ◽  
Yongtao Meng ◽  
Xiangcheng Sun ◽  
Sourav Biswas ◽  
...  
Keyword(s):  
Anode Materials ◽  
High Capacity ◽  
High Rate ◽  
Microwave Method ◽  
Li Ion Batteries ◽  
Li Ion Battery ◽  
Reduced Graphene ◽  
One Step ◽  
Li Ion ◽  
Long Life

A new one-step microwave method was designed for synthesis of rGO/Co3O4, and the Li-ion battery showed high capacity and long life.

High capacity, power density and cycling stability of silicon Li-ion battery anodes with a few layer black phosphorus additive

2019 ◽  
Vol 3 (1) ◽  
pp. 245-250 ◽  
Author(s):  
Kingshuk Roy ◽  
Malik Wahid ◽  
Dhanya Puthusseri ◽  
Apurva Patrike ◽  
Subas Muduli ◽  
...  
Keyword(s):  
Power Density ◽  
Anode Material ◽  
High Capacity ◽  
Black Phosphorus ◽  
Cycling Stability ◽  
Li Ion Battery ◽  
Volume Changes ◽  
High Theoretical Capacity ◽  
Li Ion ◽  
Battery Anode

The exceptionally high theoretical capacity of silicon as a Li-ion battery anode material is hard to realize and stabilize in practice due to huge volume changes during lithiation/de-lithiation. With the use of black phosphorus additive we could achieve tremendous stability due to strain management.

Nickel-mediated polyol synthesis of hierarchical V2O5 hollow microspheres with enhanced lithium storage properties

2015 ◽  
Vol 3 (5) ◽  
pp. 1979-1985 ◽  
Author(s):  
Yan-Zhen Zheng ◽  
Haiyang Ding ◽  
Evan Uchaker ◽  
Xia Tao ◽  
Jian-Feng Chen ◽  
...  
Keyword(s):  
High Capacity ◽  
Hollow Microspheres ◽  
Polyol Synthesis ◽  
Li Ion Battery ◽  
Lithium Storage ◽  
Li Ion ◽  
Template Free ◽  
Superior Cycling Stability ◽  
Storage Properties ◽  
Li Storage

Hierarchical Ni–V2O5 hollow microspheres, prepared via a template-free Ni-mediated polyol process, have excellent Li storage properties as a Li-ion battery cathode (high capacity (294 mA h g−1), superior cycling stability/rate performance) due to their unique structure and low V valence state.

Three-dimensionally ordered macroporous Li3V2(PO4)3/C nanocomposite cathode material for high-capacity and high-rate Li-ion batteries

Nanoscale ◽  
2014 ◽  
Vol 6 (6) ◽  
pp. 3302 ◽  
Author(s):  
Donglin Li ◽  
Miao Tian ◽  
Rong Xie ◽  
Qian Li ◽  
Xiaoyong Fan ◽  
...  
Keyword(s):  
Cathode Material ◽  
High Capacity ◽  
High Rate ◽  
Li Ion Batteries ◽  
Li Ion ◽  
Ordered Macroporous

A novel highly crystalline Fe4(Fe(CN)6)3 concave cube anode material for Li-ion batteries with high capacity and long life

2019 ◽  
Vol 7 (18) ◽  
pp. 11478-11486 ◽  
Author(s):  
Xiaowei He ◽  
Lidong Tian ◽  
Mingtao Qiao ◽  
Jianzheng Zhang ◽  
Wangchang Geng ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Hydrothermal Method ◽  
High Capacity ◽  
Li Ion Batteries ◽  
Lithium Storage ◽  
Prussian Blue Analogue ◽  
Storage Performance ◽  
One Step ◽  
Li Ion ◽  
Long Life

Hierarchically structured and ammonium-rich Prussian blue analogue materials are prepared by a one-step hydrothermal method, and show excellent lithium storage performance.

Sulfurization synthesis of a new anode material for Li-ion batteries: understanding the role of sulfurization in lithium ion conversion reactions and promoting lithium storage performance

2019 ◽  
Vol 7 (37) ◽  
pp. 21270-21279 ◽  
Author(s):  
Yanmin Qin ◽  
Zhongqing Jiang ◽  
Liping Guo ◽  
Jianlin Huang ◽  
Zhong-Jie Jiang ◽  
...  
Keyword(s):  
Anode Material ◽  
High Capacity ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Lithium Storage ◽  
Storage Performance ◽  
Carbon Coated ◽  
Li Ion ◽  
Good Cycling Stability

N, S co-doped carbon coated MnOS (MnOS@NSC) has been demonstrated to be a potential anode material for LIBs with high capacity, good cycling stability and excellent rate performance.

Ga2O3-Li3VO4/NC nanofibers toward superb high-capacity and high-rate Li-ion storage

2021 ◽  
Author(s):  
Daobo Li ◽  
Zhen Xu ◽  
Dongmei Zhang ◽  
Cunyuan Pei ◽  
Tao Li ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
High Capacity ◽  
High Rate ◽  
Rate Performance ◽  
Ion Storage ◽  
Li Ion ◽  
High Rate Performance

The high-rate performance of Ga2O3-based electrode has been seriously restricted by its modest reaction kinetics caused by the particular challenge in morphology regulation. Here Ga2O3-Li3VO4/N doped C nanofibers (G-LVO/NC NFs)...

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