Semiconducting polymer blends that exhibit stable charge transport at high temperatures
Keyword(s):
Although high-temperature operation (i.e., beyond 150°C) is of great interest for many electronics applications, achieving stable carrier mobilities for organic semiconductors at elevated temperatures is fundamentally challenging. We report a general strategy to make thermally stable high-temperature semiconducting polymer blends, composed of interpenetrating semicrystalline conjugated polymers and high glass-transition temperature insulating matrices. When properly engineered, such polymer blends display a temperature-insensitive charge transport behavior with hole mobility exceeding 2.0 cm2/V·s across a wide temperature range from room temperature up to 220°C in thin-film transistors.
2012 ◽
Vol 710
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pp. 457-462
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2014 ◽
Vol 778-780
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pp. 903-906
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2011 ◽
Vol 462-463
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pp. 1-6
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