scholarly journals Response to Comment on "Long-term climate forcing by atmospheric oxygen concentrations"

Science ◽  
2016 ◽  
Vol 353 (6295) ◽  
pp. 132-132 ◽  
Author(s):  
C. J. Poulsen ◽  
C. Tabor ◽  
J. White
Science ◽  
2015 ◽  
Vol 348 (6240) ◽  
pp. 1238-1241 ◽  
Author(s):  
C. J. Poulsen ◽  
C. Tabor ◽  
J. D. White

2020 ◽  
Author(s):  
Yuzhen Yan ◽  
Michael Bender ◽  
Edward Brook ◽  
Heather Clifford ◽  
Preston Kemeny ◽  
...  

<p>Gases preserved in ice cores provide a potential direct archive for atmospheric oxygen. Yet, oxygen-to-nitrogen ratios in ice cores (expressed as δO<sub>2</sub>/N<sub>2</sub>) are modified by a number of processes related to gas trapping and gas losses in the ice. Such complications have long hindered the use of ice core δO<sub>2</sub>/N<sub>2</sub> to derive true atmospheric oxygen concentrations. Recently, a persistent decline in δO<sub>2</sub>/N<sub>2</sub>, observed in four different ice cores (GISP2, Vostok, Dome F, and EDC), is interpreted to reflect decreasing atmospheric O<sub>2</sub> concentrations over the late Pleistocene (Stolper et al., 2016). The rate of δO<sub>2</sub>/N<sub>2</sub> change is -8.4±0.2 ‰/Myr (1σ). Using new measurements made on EDC samples stored at -50 °C and therefore free from gas loss, Extier et al (2018) confirms the decrease in δO<sub>2</sub>/N<sub>2</sub> with a slope of -7.0±0.6‰/Myr (1σ).</p><p>Here, we present new δO<sub>2</sub>/N<sub>2</sub> measurements made on 1.5-million-year-old blue ice cores from Allan Hills Blue Ice Areas, East Antarctica. We use argon-to-nitrogen ratios (δAr/N<sub>2</sub>) in the ice to correct for the fractionations during bubble close-off and gas losses. In those processes, δAr/N<sub>2</sub> is fractionated in a fashion similar to δO<sub>2</sub>/N<sub>2</sub> (Huber et al., 2006; Severinghaus and Battle, 2006). Paired δO<sub>2</sub>/N<sub>2</sub>-δAr/N<sub>2</sub> values measured from the same sample were classified into three different time slices: 1.5 Ma (million years old), 950 ka, and 490 ka. Between 950 ka and 490 ka, we observe a decline in δO<sub>2</sub>/N<sub>2</sub> similar to that observed in the aforementioned deep ice cores. This observation gives us confidence in the validity of the Allan Hills blue ice δO<sub>2</sub>/N<sub>2</sub> records. Between 1.5 Ma and 950 ka, however, there is no statistically significant trend in ice core δO<sub>2</sub>/N<sub>2</sub>. Our results show a surprising lack of variability from 1.5 to 0.95 Ma; even during the past ~0.9 Ma, the rate of decline was very slow.</p>


2016 ◽  
Vol 20 (7) ◽  
pp. 2877-2898 ◽  
Author(s):  
Hannes Müller Schmied ◽  
Linda Adam ◽  
Stephanie Eisner ◽  
Gabriel Fink ◽  
Martina Flörke ◽  
...  

Abstract. When assessing global water resources with hydrological models, it is essential to know about methodological uncertainties. The values of simulated water balance components may vary due to different spatial and temporal aggregations, reference periods, and applied climate forcings, as well as due to the consideration of human water use, or the lack thereof. We analyzed these variations over the period 1901–2010 by forcing the global hydrological model WaterGAP 2.2 (ISIMIP2a) with five state-of-the-art climate data sets, including a homogenized version of the concatenated WFD/WFDEI data set. Absolute values and temporal variations of global water balance components are strongly affected by the uncertainty in the climate forcing, and no temporal trends of the global water balance components are detected for the four homogeneous climate forcings considered (except for human water abstractions). The calibration of WaterGAP against observed long-term average river discharge Q significantly reduces the impact of climate forcing uncertainty on estimated Q and renewable water resources. For the homogeneous forcings, Q of the calibrated and non-calibrated regions of the globe varies by 1.6 and 18.5 %, respectively, for 1971–2000. On the continental scale, most differences for long-term average precipitation P and Q estimates occur in Africa and, due to snow undercatch of rain gauges, also in the data-rich continents Europe and North America. Variations of Q at the grid-cell scale are large, except in a few grid cells upstream and downstream of calibration stations, with an average variation of 37 and 74 % among the four homogeneous forcings in calibrated and non-calibrated regions, respectively. Considering only the forcings GSWP3 and WFDEI_hom, i.e., excluding the forcing without undercatch correction (PGFv2.1) and the one with a much lower shortwave downward radiation SWD than the others (WFD), Q variations are reduced to 16 and 31 % in calibrated and non-calibrated regions, respectively. These simulation results support the need for extended Q measurements and data sharing for better constraining global water balance assessments. Over the 20th century, the human footprint on natural water resources has become larger. For 11–18% of the global land area, the change of Q between 1941–1970 and 1971–2000 was driven more strongly by change of human water use including dam construction than by change in precipitation, while this was true for only 9–13 % of the land area from 1911–1940 to 1941–1970.


1997 ◽  
Vol 6 (2) ◽  
pp. 130-139 ◽  
Author(s):  
JURGEN ALHEIT ◽  
EBERHARD HAGEN
Keyword(s):  

2014 ◽  
Vol 21 (2) ◽  
pp. 594-604 ◽  
Author(s):  
Bryan A. Black ◽  
Jason B. Dunham ◽  
Brett W. Blundon ◽  
Jayne Brim-Box ◽  
Alan J. Tepley

2021 ◽  
Author(s):  
Jordon Hemingway ◽  
Daniel Rothman ◽  
Katherine Grant ◽  
Sarah Rosengard ◽  
Timothy Eglinton ◽  
...  

<p>The vast majority of organic carbon (OC) produced by life is respired back to carbon dioxide (CO<sub>2</sub>), but roughly 0.1% escapes and is preserved over geologic timescales. By sequestering reduced carbon from Earth’s surface, this “slow OC leak” contributes to CO<sub>2</sub> removal and promotes the accumulation of atmospheric oxygen and oxidized minerals. Countering this, OC contained within sedimentary rocks is oxidized during exhumation and erosion of mountain ranges. By respiring previously sequestered reduced carbon, erosion consumes atmospheric oxygen and produces CO<sub>2</sub>. The balance between these two processes—preservation and respiration—regulates atmospheric composition, Earth-surface redox state, and global climate. Despite this importance, the governing mechanisms remain poorly constrained. To provide new insight, we developed a method that investigates OC composition using bond-strength distributions coupled with radiocarbon ages. Here I highlight a suite of recent results using this approach, and I show that biospheric OC interacts with particles and becomes physiochemically protected during aging, thus promoting preservation. I will discuss how this mechanistic framework can help elucidate why OC preservation—and thus atmospheric composition, Earth-surface redox state, and climate—has varied throughout Earth history.</p>


1990 ◽  
Vol 14 ◽  
pp. 358-358
Author(s):  
Mary Jo Spencer ◽  
Paul A. Mayewski ◽  
W. Berry Lyons ◽  
Mark S. Twickler ◽  
Pieter Grootes

In 1984 a 200-m ice core was collected from a local accumulation basin in the Dominion Range, Transantarctic Mountains, Antarctica. A complete oxygen isotope record has been obtained and a considerable portion of the core has been analyzed in detail for chloride, nitrate, sulfate, and sodium. About half of the chloride is due to sea salt with the remainder originating as gaseous HCl. Nitrate levels have increased markedly over the last 1000 years whereas the levels of the other constituents have remained fairly constant.The oxygen isotope results suggest that this region of Antarctica is responding to long-term global climate forcing as well as to shorter-term climatic variations. This data will be compared with the anion and sodium records in order to determine the effects of climatic forcing on these other records. In particular, nitrate appears to vary in concert with fluctuations in long-term climate. Additionally, variations in each constituent over the 3500 year period will be examined in detail to determine the influence of other processes which affect their concentrations.


Geology ◽  
2020 ◽  
Author(s):  
Graham A. Shields ◽  
Benjamin J.W. Mills

Although it is widely accepted that Earth’s long-term surface temperature is regulated by the mutual dependence of silicate weathering and climate on CO2, the root causes of some climatic events remain unresolved. We show here for the first time that imbalances between evaporite weathering and deposition can affect climate through the process of carbonate sedimentation. Calcium sulfate weathering supplies Ca2+ ions to the ocean unaccompanied by carbonate alkalinity, so that increased carbonate precipitation strengthens greenhouse forcing through transfer of CO2 to the atmosphere. Conversely, calcium sulfate deposition weakens greenhouse forcing, while the high depositional rates of evaporite giants may overwhelm the silicate weathering feedback, causing several degrees of planetary cooling. Non-steady-state evaporite dynamics and related feedbacks have hitherto been overlooked as drivers of long-term carbon cycle change. Here, we illustrate the importance of evaporite deposition, in particular, by showing how a series of massive depositional events contributed to global cooling during the mid–late Miocene.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Eleonora Regattieri ◽  
Giovanni Zanchetta ◽  
Ilaria Isola ◽  
Elena Zanella ◽  
Russell N. Drysdale ◽  
...  

AbstractDisentangling the effects of climate and human impact on the long-term evolution of the Earth Critical Zone is crucial to understand the array of its potential responses to the ongoing Global Change. This task requires natural archives from which local information about soil and vegetation can be linked directly to climate parameters. Here we present a high-resolution, well-dated, speleothem multiproxy record from the SW Italian Alps, spanning the last ~10,000 years of the present interglacial (Holocene). We correlate magnetic properties and the carbon stable isotope ratio to soil stability and pedogenesis, whereas the oxygen isotope composition is interpreted as primarily related to precipitation amount, modulated at different timescales by changes in precipitation source and seasonality. During the 9.7-2.8 ka period, when anthropic pressure over the catchment was scarce, intervals of enhanced soil erosion are related to climate-driven vegetation contractions and occurred during drier periods. Immediately following the onset of the Iron Age (ca. 2.8 ka), by contrast, periods of enhanced soil erosion coincided with a wetter climate. We propose that the observed changes in the soil response to climate forcing were related to early anthropogenic manipulations of Earth’s surface, which made the ECZ more sensitive to climate oscillations.


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