scholarly journals A general approach to composites containing nonmetallic fillers and liquid gallium

2021 ◽  
Vol 7 (1) ◽  
pp. eabe3767
Author(s):  
Chunhui Wang ◽  
Yan Gong ◽  
Benjamin V. Cunning ◽  
Seunghwan Lee ◽  
Quan Le ◽  
...  

We report a versatile method to make liquid metal composites by vigorously mixing gallium (Ga) with non-metallic particles of graphene oxide (G-O), graphite, diamond, and silicon carbide that display either paste or putty-like behavior depending on the volume fraction. Unlike Ga, the putty-like mixtures can be kneaded and rolled on any surface without leaving residue. By changing temperature, these materials can be stiffened, softened, and, for the G-O–containing composite, even made porous. The gallium putty (GalP) containing reduced G-O (rG-O) has excellent electromagnetic interference shielding effectiveness. GalP with diamond filler has excellent thermal conductivity and heat transfer superior to a commercial liquid metal–based thermal paste. Composites can also be formed from eutectic alloys of Ga including Ga-In (EGaIn), Ga-Sn (EGaSn), and Ga-In-Sn (EGaInSn or Galinstan). The versatility of our approach allows a variety of fillers to be incorporated in liquid metals, potentially allowing filler-specific “fit for purpose” materials.

2010 ◽  
Vol 168-170 ◽  
pp. 1021-1024
Author(s):  
Guo Xuan Xiong ◽  
Zhi Bin Zhang ◽  
Min Deng ◽  
Yu Fen Zhou

The cement-based composite shielding materials filled with carbon materials such as ordinary carbon materials (graphite, coke and carbon black), carbon fiber and nano-carbon materials (carbon nano-tube and nano-carbon black) were prepared. The relationship of conductivity and shielding effectiveness in a frequency range of 100 KHz~1.5 GHz was studied. The electric properties of cement-based composites filled with carbon fiber is better than other carbon materials. With the contents of carbon fiber of 5.vol%, the average shielding effectiveness is about 37 dB and the maximum shielding effectiveness reaches 40 dB.


2021 ◽  
pp. 002199832110316
Author(s):  
Jiayang Zhang ◽  
Hongjiang Ni ◽  
Ming Gong ◽  
Jun Li ◽  
Daijun Zhang ◽  
...  

Electromagnetic shielding performance has been achieved for a polyimide (PI)-matrix composite by the strategy of self-metallization of its thermosetting PI matrix. Self-metallization of the thermosetting PI was realized by silver ion/poly(amic acid) (PAA) precursor ion exchange and thermal reduction. The factors influencing the self-metallization were investigated. The electrical conductivity and integrity for the surface of the PI were achieved by optimization of ion exchange/thermal reduction parameters. The fabricated PI-matrix composite exhibits a maximum electromagnetic interference shielding effectiveness value of 81 dB. Importantly, the electromagnetic shielding performance can be maintained even after heat condition of 300°C. Meanwhile, the surface-metallized PI composite exhibits mechanical property equivalent to the pristine composite, and an Ag/matrix interfacial strength higher than 19.6 MPa. Besides, self-metallization mechanism of the thermosetting PI was investigated.


2021 ◽  
pp. 095400832110645
Author(s):  
Karim Benzaoui ◽  
Achour Ales ◽  
Ahmed Mekki ◽  
Abdelhalim Zaoui ◽  
Boudjemaa Bouaouina ◽  
...  

The conventional electromagnetic interference (EMI) shielding materials are being gradually replaced by a new generation of supported conducting polymer composites (CPC) films due to their many advantages. This work presents a contribution on the effects of silane surface–modified flexible polypyrrole-silver nanocomposite films on the electromagnetic interference shielding effectiveness (EMI-SE). Thus, the UV-polymerization was used to in-situ deposit the PPy-Ag on the biaxial oriented polyethylene terephthalate (BOPET) flexible substrates whose surfaces were treated by 3-aminopropyltrimethoxysilane (APTMS). X-ray Photoelectron Spectroscopy (XPS) analyzes confirmed the APTMS grafting procedure. Structural, morphological, thermal, and electrical characteristics of the prepared films were correlated to the effect of substrate surface treatment. Thereafter, EMI-SE measurements of the elaborated films were carried out as per ASTM D4935 standard for a wide frequency band extending from 50 MHz to 18 GHz. The obtained results confirmed that the APTMS-treated BOPET film exhibit higher EMI shielding performance and better electrical characteristics compared to the untreated film. In fact, a 32% enhancement of EMI-SE was noted for the treated films compared to the untreated ones. Overall, these results put forward the role played by the surface treatment in strengthening the position of flexible PPy-Ag supported films as high-performance materials in electronic devices and electromagnetic interference shielding applications.


Sign in / Sign up

Export Citation Format

Share Document