scholarly journals Breakdown of Hooke’s law of elasticity at the Mott critical endpoint in an organic conductor

2016 ◽  
Vol 2 (12) ◽  
pp. e1601646 ◽  
Author(s):  
Elena Gati ◽  
Markus Garst ◽  
Rudra S. Manna ◽  
Ulrich Tutsch ◽  
Bernd Wolf ◽  
...  

The Mott metal-insulator transition, a paradigm of strong electron-electron correlations, has been considered as a source of intriguing phenomena. Despite its importance for a wide range of materials, fundamental aspects of the transition, such as its universal properties, are still under debate. We report detailed measurements of relative length changes ΔL/Las a function of continuously controlled helium-gas pressurePfor the organic conductor κ-(BEDT-TTF)2Cu[N(CN)2]Cl across the pressure-induced Mott transition. We observe strongly nonlinear variations of ΔL/Lwith pressure around the Mott critical endpoint, highlighting a breakdown of Hooke’s law of elasticity. We assign these nonlinear strain-stress relations to an intimate, nonperturbative coupling of the critical electronic system to the lattice degrees of freedom. Our results are fully consistent with mean-field criticality, predicted for electrons in a compressible lattice with finite shear moduli. We argue that the Mott transition for all systems that are amenable to pressure tuning shows the universal properties of an isostructural solid-solid transition.

The mathematical theory of small elastic deformations has been developed to a high degree of sophistication on certain fundamental assumptions regarding the stress-strain relationships which are obeyed by the materials considered. The relationships taken are, in effect, a generalization of Hooke’s law— ut tensio, sic vis . The justification for these assumptions lies in the widespread agreement of experiment with the predictions of the theory and in the interpretation of the elastic behaviour of the materials in terms of their known structure. The same factors have contributed to our appreciation of the limitations of these assumptions. The principal problems, which the theory seeks to solve, are the determination of the deformation which a body undergoes and the distribution of stresses in it, when certain forces are applied to it, and when certain points of the body are subjected to specified displacements. These problems are always dealt with on the assumption that the generalization of Hooke’s law is obeyed by the material of the body and that the deformation is small, i.e. the change of length, in any linear element in the material, is small compared with the length of the element in the undeformed state. Apart from the fact that the generalization of Hooke’s law is obeyed accurately by a very wide range of materials, under a considerable variety of stress and strain conditions, it has the further advantage that it leads to a mathematically tractable theory.


1956 ◽  
Vol 29 (1) ◽  
pp. 296-301
Author(s):  
P. I. Zubov ◽  
Z. N. Zhurkina ◽  
V. A. Kargin

Abstract 1. The mechanical properties of gels prepared from solutions of natural rubber and synthetic rubber were studied. 2. It was established that gels of synthetic rubber (polybutadiene rubber) have a wide range of relaxation periods. Gels of natural rubber (smoked sheet) behave like ideally elastic substances, following Hooke's law in the change of rate of deformation by 1000 times. 3. The viscosity of solutions of natural rubber and of polybutiadiene rubber in the presence of sulfur monochloride was studied. 4. We observed that sulfur monochloride sharply decreases the viscosity of natural rubber solutions and has almost no influence on the viscosity of synthetic rubber solutions.


2020 ◽  
Author(s):  
Lucian Chan ◽  
Garrett Morris ◽  
Geoffrey Hutchison

The calculation of the entropy of flexible molecules can be challenging, since the number of possible conformers grows exponentially with molecule size and many low-energy conformers may be thermally accessible. Different methods have been proposed to approximate the contribution of conformational entropy to the molecular standard entropy, including performing thermochemistry calculations with all possible stable conformations, and developing empirical corrections from experimental data. We have performed conformer sampling on over 120,000 small molecules generating some 12 million conformers, to develop models to predict conformational entropy across a wide range of molecules. Using insight into the nature of conformational disorder, our cross-validated physically-motivated statistical model can outperform common machine learning and deep learning methods, with a mean absolute error ≈4.8 J/mol•K, or under 0.4 kcal/mol at 300 K. Beyond predicting molecular entropies and free energies, the model implies a high degree of correlation between torsions in most molecules, often as- sumed to be independent. While individual dihedral rotations may have low energetic barriers, the shape and chemical functionality of most molecules necessarily correlate their torsional degrees of freedom, and hence restrict the number of low-energy conformations immensely. Our simple models capture these correlations, and advance our understanding of small molecule conformational entropy.


1963 ◽  
Vol 3 (01) ◽  
pp. 1-8 ◽  
Author(s):  
N.T. Burdine

BURDINE, N.T., SOCONY MOBIL OIL CO., INC., DALLAS, TEX Abstract The present investigation is concerned with the cumulative damage to rock samples when exposed to cyclic stresses under various loading conditions. Information on the response of rocks to repetitive deformational forces is an essential prerequisite to an understanding of the fundamentals of drilling. Using a laboratory designed and constructed dynamic-stress apparatus, preliminary data were obtained on cylindrical rock samples. The experiments consist of measuring the number of cycles to failure for a given axial load ( static plus dynamic). Data were obtained for various confining and pore pressures, pore fluids (air and water), frequencies of stress application and loading procedures. The results are related to failure theories and dynamic fatigue properties of other materials. Introduction In most conventional and new drilling processes, repetitive forces are applied to the bottom of the borehole. Furthermore, in hard-rock drilling the number of applications of the forces to a particular section of rock may become excessively large. The present investigation is concerned with the cumulative damage to rocks when exposed to cyclic stresses under various loading conditions. It is believed that the experiments will lead to a better understanding of the mechanical response of rocks to particular deformational forces and to a more efficient drillingprocedure.Thepresent investigation is the initial part of a general study of the behavior of inelastic materials under static and dynamic conditions, including both theoretical and experimental studies. SURVEY OF FAILURE THEORIES OF MATERIALS Few, even phenomenological, theories on rock deformation have been established because the state of knowledge of flow, fracture and strength of rocks is largely empirical. Most of the theories that do exist were originally formulated for other materials. HOOKE'S LAW The state of stress in continuous media is completely determined by the stress tensor and the state of deformation by the strain tensor . In the linear theory of elasticity the generalized Hooke's law is ..........................(1) where the coefficients are the components of the elasticity tensor. For homogeneous and isotropic conditions the number of independent coefficients reduce to two, and Eq. 1 becomes ..................(2) in which and are Lame's constants; is the kronecker delta; and is the dilation. This simplified version of Hooke's law has been used quite extensively in geophysical research where most of the information about the mechanical properties of the earth have been obtained. However, it has only limited application in rock fatigue studies. MATERIAL BEHAVIOR Many solids obey Hooke's law at small stresses, but for higher stresses a hysteretic effect occurs due to temporary or permanent residual deformation of the solid (inelastic deformation). Such deviations in mechanical behavior exist in varying degrees in different classes of materials. Most elastic materials have a microscopic heterogeneity due either to random distribution of anisotropic particles, or due to some preferred particle orientation, or both. Other materials are quite grossly heterogeneous. And the method of formation, particularly in rocks, oftentimes creates residual stress concentrations which have complicated states of imperfect equilibrium. Also, the thermal effects resulting from structural behavior give rise to nonuniform temperature distributions and the degradation of mechanical energy. When such bodies are exposed to certain large loading conditions, the inelastic behavior is intensified so strongly that the deformation, normally brittle, becomes ductile. SPEJ P. 1^


2021 ◽  
Vol 2021 (5) ◽  
Author(s):  
Brandon S. DiNunno ◽  
Niko Jokela ◽  
Juan F. Pedraza ◽  
Arttu Pönni

Abstract We study in detail various information theoretic quantities with the intent of distinguishing between different charged sectors in fractionalized states of large-N gauge theories. For concreteness, we focus on a simple holographic (2 + 1)-dimensional strongly coupled electron fluid whose charged states organize themselves into fractionalized and coherent patterns at sufficiently low temperatures. However, we expect that our results are quite generic and applicable to a wide range of systems, including non-holographic. The probes we consider include the entanglement entropy, mutual information, entanglement of purification and the butterfly velocity. The latter turns out to be particularly useful, given the universal connection between momentum and charge diffusion in the vicinity of a black hole horizon. The RT surfaces used to compute the above quantities, though, are largely insensitive to the electric flux in the bulk. To address this deficiency, we propose a generalized entanglement functional that is motivated through the Iyer-Wald formalism, applied to a gravity theory coupled to a U(1) gauge field. We argue that this functional gives rise to a coarse grained measure of entanglement in the boundary theory which is obtained by tracing over (part) of the fractionalized and cohesive charge degrees of freedom. Based on the above, we construct a candidate for an entropic c-function that accounts for the existence of bulk charges. We explore some of its general properties and their significance, and discuss how it can be used to efficiently account for charged degrees of freedom across different energy scales.


2021 ◽  
Vol 11 (2) ◽  
pp. 787
Author(s):  
Bartłomiej Ambrożkiewicz ◽  
Grzegorz Litak ◽  
Anthimos Georgiadis ◽  
Nicolas Meier ◽  
Alexander Gassner

Often the input values used in mathematical models for rolling bearings are in a wide range, i.e., very small values of deformation and damping are confronted with big values of stiffness in the governing equations, which leads to miscalculations. This paper presents a two degrees of freedom (2-DOF) dimensionless mathematical model for ball bearings describing a procedure, which helps to scale the problem and reveal the relationships between dimensionless terms and their influence on the system’s response. The derived mathematical model considers nonlinear features as stiffness, damping, and radial internal clearance referring to the Hertzian contact theory. Further, important features are also taken into account including an external load, the eccentricity of the shaft-bearing system, and shape errors on the raceway investigating variable dynamics of the ball bearing. Analysis of obtained responses with Fast Fourier Transform, phase plots, orbit plots, and recurrences provide a rich source of information about the dynamics of the system and it helped to find the transition between the periodic and chaotic response and how it affects the topology of RPs and recurrence quantificators.


2000 ◽  
Vol 122 (3) ◽  
pp. 147-152 ◽  
Author(s):  
Hui He ◽  
Mohamad Metghalchi ◽  
James C. Keck

A simple model has been developed to estimate the sensible thermodynamic properties such as Gibbs free energy, enthalpy, heat capacity, and entropy of hydrocarbons over a wide range of temperatures with special attention to the branched molecules. The model is based on statistical thermodynamic expressions incorporating translational, rotational and vibrational motions of the atoms. A method to determine the number of degrees of freedom for different motion modes (bending and torsion) has been established. Branched rotational groups, such as CH3 and OH, have been considered. A modification of the characteristic temperatures for different motion mode has been made which improves the agreement with the exact values for simple cases. The properties of branched alkanes up to 2,3,4,-trimthylpentane have been calculated and the results are in good agreement with the experimental data. A relatively small number of parameters are needed in this model to estimate the sensible thermodynamic properties of a wide range of species. The model may also be used to estimate the properties of molecules and their isomers, which have not been measured, and is simple enough to be easily programmed as a subroutine for on-line kinetic calculations. [S0195-0738(00)00902-X]


1939 ◽  
Vol 7 (2) ◽  
pp. 134-134
Author(s):  
Zigmond Wilchinsky

2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Hao Hu ◽  
Hepeng Ding ◽  
Feng Liu

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