scholarly journals All-polymeric control of nanoferronics

2015 ◽  
Vol 1 (11) ◽  
pp. e1501264 ◽  
Author(s):  
Beibei Xu ◽  
Huashan Li ◽  
Asha Hall ◽  
Wenxiu Gao ◽  
Maogang Gong ◽  
...  

In the search for light and flexible nanoferronics, significant research effort is geared toward discovering the coexisting magnetic and electric orders in crystalline charge-transfer complexes. We report the first example of multiferroicity in centimeter-sized crystalline polymeric charge-transfer superstructures that grow at the liquid-air interface and are controlled by the regioregularity of the polymeric chain. The charge order–driven ferroic mechanism reveals spontaneous and hysteretic polarization and magnetization at the donor-acceptor interface. The charge transfer and ordering in the ferroic assemblies depend critically on the self-organizing and molecular packing of electron donors and acceptors. The invention described here not only represents a new coupling mechanism of magnetic and electric ordering but also creates a new class of emerging all-organic nanoferronics.

CrystEngComm ◽  
2015 ◽  
Vol 17 (32) ◽  
pp. 6227-6235 ◽  
Author(s):  
Amparo Salmerón-Valverde ◽  
Sylvain Bernès

A series of solvated donor–acceptor organic complexes were shown to slowly release the lattice solvent while the degree of charge transfer decreases steadily. This behavior is not observed in the case of a hydrate.


2019 ◽  
Vol 25 (59) ◽  
pp. 13547-13565 ◽  
Author(s):  
Karlee P. Castro ◽  
Eric V. Bukovsky ◽  
Igor V. Kuvychko ◽  
Nicholas J. DeWeerd ◽  
Yu‐Sheng Chen ◽  
...  

1984 ◽  
Vol 39 (12) ◽  
pp. 1274-1278 ◽  
Author(s):  
M. H. Abdel-Kader ◽  
R. M. Issa ◽  
M. M. Ayad ◽  
M. S. Abdel-Mottaleb

The charge transfer complexes of 2,3- (I) and 2,6-Dimethylnaphthalenes (II) as electron donors with tri- and di-nitrobenzenes as electron acceptors are prepared and investigated by element analysis, IR. 1H nmr and electronic absorption spectroscopy. The results showed that I yields CT complexes of 1:1 type only while II is capable of forming 1 : 1 and 1 : 2 (donor: acceptor) compounds. The spectral characteristics of the CT complexes are pointed out and discussed. The difference in the donor behaviour between I and II is explained in the light of PPP-MO calculations.


2020 ◽  
Vol 8 (43) ◽  
pp. 15199-15207
Author(s):  
Paul Beyer ◽  
Eduard Meister ◽  
Timo Florian ◽  
Alexander Generalov ◽  
Wolfgang Brütting ◽  
...  

Charge transfer complex (CPX) formation at a donor–acceptor interface reduces the amount of Fermi-level pinning induced interfacial charge transfer.


Author(s):  
Olga A Otmakhova ◽  
Alexey Piryazev ◽  
Galina N Bondarenko ◽  
Georgii A. Shandryuk ◽  
Alexey Merekalov ◽  
...  

Electron donor-acceptor liquid crystals have been attracting considerable attention due to possible applications in optoelectronics and photonics. The creation of such charge transfer complexes is a powerful and flexible instrument...


1973 ◽  
Vol 4 (44) ◽  
pp. no-no
Author(s):  
M. RAILEANU ◽  
I. RADULIAN ◽  
M. OLTENEANU ◽  
M. CONSTANTIN

Sign in / Sign up

Export Citation Format

Share Document