Decoding the steady elongational viscosity of monodisperse linear polymers using tube-based modeling

2022 ◽  
Vol 66 (1) ◽  
pp. 197-218
Author(s):  
Céline Hannecart ◽  
Taisir Shahid ◽  
Dimitris Vlassopoulos ◽  
Filip Oosterlinck ◽  
Christian Clasen ◽  
...  
Keyword(s):  
Elongational Viscosity ◽  
Linear Polymers

On the surface tension of directed linear polymers

1989 ◽  
Vol 50 (6) ◽  
pp. 599-608 ◽  
Author(s):  
V.B. Priezzhev ◽  
S.A. Terletsky
Keyword(s):  
Surface Tension ◽  
Linear Polymers

Arrangement Of Monomeric Units In Fibrin

1979 ◽  
Author(s):  
Jan Hermans
Keyword(s):  
Fiber Axis ◽  
High Symmetry ◽  
Linear Polymers ◽  
Fiber Volume ◽  
High Fiber ◽  
Rotation Axes ◽  
Small Set ◽  
Helical Turn ◽  
The One ◽  
Kinetics Of

Measurements of light scattering have given much information about formation and properties of fibrin. These studies have determined mass-length ratio of linear polymers (protofibrils) and of fibers, kinetics of polymerization and of lateral association and volume-mass ratio of thick fibers. This ratio is 5 to 1. On the one hand, this high value suggests that the fiber contains channels that allow the diffusion of enzymes such as Factor XHIa and plasmin; on the other hand, the high value appears paradoxical for a stiff fiber made up of elongated units (fibrin monomers) arranged in parallel. Such a high fiber volume is a property of only a small set out of many high-symmetry models of fibrin, which may be constructed from overlapping three-domain monomers which are arranged into strands, are aligned nearly parallel to the fiber axis and make adequate longitudinal and lateral contacts. These models contain helical protofibrils related to each other by rotation axes parallel to the fiber axis. The protofibrils may contain 2, 3 or 4 monomers per helical turn and there are four possible symmetries. A large specific volume is achieved if the ends of each monomer are slightly displaced from the protofibril axis, either by a shift or by a tilt of the monomer. The fiber containing tilted monomers is more highly interconnected; the two ends of a tilted monomer form lateral contacts with different adjacent protofibrils, whereas the two ends of a non-tilted monomer contact the same adjacent protofibril(s).

Mapping the “Extra Solvent Power, ESP” of Ionic Liquids for Monomers, Polymers and Globular Nanoparticles

2017 ◽  
Author(s):  
Jose A. Pomposo
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Linear Polymers ◽  
Green Solvents ◽  
Ionic Polymers ◽  
First Time ◽  
Solvent Power

Understanding the miscibility behavior of ionic liquid (IL) / monomer, IL / polymer and IL / nanoparticle mixtures is critical for the use of ILs as green solvents in polymerization processes, and to rationalize recent observations concerning the superior solubility of some proteins in ILs when compared to standard solvents. In this work, the most relevant results obtained in terms of a three-component Flory-Huggins theory concerning the “Extra Solvent Power, ESP” of ILs when compared to traditional non-ionic solvents for monomeric solutes (case I), linear polymers (case II) and globular nanoparticles (case III) are presented. Moreover, useful ESP maps are drawn for the first time for IL mixtures corresponding to case I, II and III. Finally, a potential pathway to improve the miscibility of non-ionic polymers in ILs is also proposed.

Metal‐Organic Frameworks for Practical Separation of Cyclic and Linear Polymers

2021 ◽  
Author(s):  
Taku Sawayama ◽  
Yubo Wang ◽  
Tomohisa Watanabe ◽  
Masayoshi Takayanagi ◽  
Takuya Yamamoto ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Linear Polymers ◽  
Metal Organic

Effect of chain-penetration on ring shape for mixtures of rings and linear polymers

Polymer ◽  
2021 ◽  
Vol 218 ◽  
pp. 123493
Author(s):  
Katsumi Hagita ◽  
Takahiro Murashima
Keyword(s):  
Linear Polymers ◽  
Ring Shape

scholarly journals Single Chain Dynamic Structure Factor of Linear Polymers in an All-Polymer Nano-Composite

2016 ◽  
Vol 49 (6) ◽  
pp. 2354-2364 ◽  
Author(s):  
Arantxa Arbe ◽  
José A. Pomposo ◽  
Isabel Asenjo-Sanz ◽  
Debsindhu Bhowmik ◽  
Oxana Ivanova ◽  
...  
Keyword(s):  
Structure Factor ◽  
Dynamic Structure ◽  
Dynamic Structure Factor ◽  
Linear Polymers ◽  
Single Chain ◽  
Nano Composite ◽  
Chain Dynamic

Linear polymers containing the 1,3,5-triazine nucleus

1959 ◽  
Vol 40 (136) ◽  
pp. 270-272 ◽  
Author(s):  
Herbert K. Reimschuessel ◽  
Alan M. Lovelace ◽  
Edward M. Hagerman
Keyword(s):  
Linear Polymers
Sign in / Sign up

Export Citation Format

Share Document