Strain softening of concentrated cohesive particulate suspensions prior to yield

2021 ◽  
Vol 65 (3) ◽  
pp. 355-370
Author(s):  
Tiara E. Kusuma ◽  
Peter J. Scales ◽  
Richard Buscall ◽  
Daniel R. Lester ◽  
Anthony D. Stickland
Author(s):  
John G. Sheehan

The goal is to examine with high resolution cryo-SEM aqueous particulate suspensions used in coatings for printable paper. A metal-coating chamber for cryo-preparation of such suspensions was described previously. Here, a new conduction-cooling system for the stage and cold-trap in an SEM specimen chamber is described. Its advantages and disadvantages are compared to a convection-cooling system made by Hexland (model CT1000A) and its mechanical stability is demonstrated by examining a sample of styrene-butadiene latex.In recent high resolution cryo-SEM, some stages are cooled by conduction, others by convection. In the latter, heat is convected from the specimen stage by cold nitrogen gas from a liquid-nitrogen cooled evaporative heat exchanger. The advantage is the fast cooling: the Hexland CT1000A cools the stage from ambient temperature to 88 K in about 20 min. However it consumes huge amounts of liquid-nitrogen and nitrogen gas: about 1 ℓ/h of liquid-nitrogen and 400 gm/h of nitrogen gas. Its liquid-nitrogen vessel must be re-filled at least every 40 min.


1999 ◽  
Vol 40 (4-5) ◽  
pp. 123-130 ◽  
Author(s):  
S. Malato ◽  
J. Blanco ◽  
C. Richter ◽  
B. Milow ◽  
M. I. Maldonado

Particulate suspensions of TiO2 irradiated with natural solar tight in a large experimental plant catalyse the oxidation of organic contaminants. The problem in using TiO2 as a photocatalyst is electron/hole recombination. One strategy for inhibiting e−/h+ recombination is to add other (irreversible) electron acceptors to the reaction. In many highly toxic waste waters where degradation of organic pollutants is the major concern, the addition of an inorganic anion to enhance the organic degradation rate may be justified. For better results, these additives should fulfil the following criteria: dissociate into harmless by-products and lead to the formation of ·OH or other oxidising agents. In this paper, we attempt to demonstrate the optimum conditions for the treatment of commercial pesticide rinsates found in the wastewater produced by a pesticide container recycling plant. The experiments were performed in one of the pilot plants of the largest solar photocatalytic system in Europe, the Detoxification Plants of the Plataforma Solar de Almería (PSA), in Spain. After testing ten different commercial pesticides, results show that peroxydisulphate enhances the photocatalytic miniralization of all of them. This study is part of an extensive project focused on the design of a solar photocatalytic plant for decontamination of agricultural rinsates in Almería (Spain).


1985 ◽  
Vol 40 (7) ◽  
pp. 653-665
Author(s):  
J. S. Mshana ◽  
A. S. Krausz

Constitutive equations of cyclic strain and stress softening for materials with low internal stress levels are derived from the rate theory. The study shows that over the high stress and low temperature range where the description of plastic flow in cyclic softening can be approximated with activation over a single energy barrier, cyclic strain softening is well related to stress relaxation process while cyclic stress softening is related to creep process. The material structural characteristics for cyclic strain softening, cyclic stress softening and stress relaxation are identical. Subsequently, it is shown that cyclic stress and strain softening within the high stress and low temperature range can be evaluated from the constitutive equations using the material structural characteristics measured from a simple stress relaxation test.


Author(s):  
Sheng Yu-ming ◽  
Li Chao ◽  
Xia Ming-yao ◽  
Zou Jin-feng

Abstract In this study, elastoplastic model for the surrounding rock of axisymmetric circular tunnel is investigated under three-dimensional (3D) principal stress states. Novel numerical solutions for strain-softening surrounding rock were first proposed based on the modified 3D Hoek–Brown criterion and the associated flow rule. Under a 3D axisymmetric coordinate system, the distributions for stresses and displacement can be effectively determined on the basis of the redeveloped stress increment approach. The modified 3D Hoek–Brown strength criterion is also embedded into finite element software to characterize the yielding state of surrounding rock based on the modified yield surface and stress renewal algorithm. The Euler implicit constitutive integral algorithm and the consistent tangent stiffness matrix are reconstructed in terms of the 3D Hoek–Brown strength criterion. Therefore, the numerical solutions and finite element method (FEM) models for the deep buried tunnel under 3D principal stress condition are presented, so that the stability analysis of surrounding rock can be conducted in a direct and convenient way. The reliability of the proposed solutions was verified by comparison of the principal stresses obtained by the developed numerical approach and FEM model. From a practical point of view, the proposed approach can also be applied for the determination of ground response curve of the tunnel, which shows a satisfying accuracy compared with the measuring data.


Author(s):  
Fengyi Hou ◽  
Zhijie Xia ◽  
Yihu Song ◽  
Wei Chen ◽  
Qiang Zheng

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