Structure and rheology of di- and triblock copolymers of polystyrene and poly(n-butyl acrylate)

2011 ◽  
Vol 55 (2) ◽  
pp. 379-400 ◽  
Author(s):  
Nicolas Jullian ◽  
Laurent Rubatat ◽  
Pierre Gerard ◽  
Jean Peyrelasse ◽  
Christophe Derail
Keyword(s):  
Butyl Acrylate ◽  
Triblock Copolymers

Synthesis and Characterization of Poly(styrene-b-n-butyl acrylate-b-styrene) Triblock Copolymers Using a Dialkoxyamine as Initiator

2002 ◽  
Vol 35 (10) ◽  
pp. 3844-3848 ◽  
Author(s):  
Sophie Robin ◽  
Olivier Guerret ◽  
Jean-Luc Couturier ◽  
Rosangela Pirri ◽  
Yves Gnanou
Keyword(s):  
Butyl Acrylate ◽  
Triblock Copolymers ◽  
Synthesis And Characterization

Synthesis of Polystyrene-b-poly(n-butyl acrylate)-b-Polystyrene Triblock Copolymers as Binder for Pigment Dyeing

2012 ◽  
Vol 441 ◽  
pp. 473-477
Author(s):  
Lei Yang ◽  
Cheng Jie Hu ◽  
Hai Yang ◽  
Dong Ming Qi
Keyword(s):  
Mechanical Properties ◽  
Butyl Acrylate ◽  
Triblock Copolymer ◽  
Chain Transfer ◽  
Triblock Copolymers ◽  
Polymerization Process ◽  
Fastness Properties ◽  
Copolymer Films ◽  
Reversible Addition ◽  
Dyed Fabrics

Well-controlled polystyrene-b-poly (n-butyl acrylate)-b-polystyrene (PSt-b-PnBA-b-PSt) triblock copolymers were prepared by RAFT (reversible addition-fragmentation chain transfer) emulsion polymerization process. The mechanical properties of the triblock copolymers were investigated in comparison to the P(nBA-co-St) statistical copolymers. When the PSt content is 20%, the ultimate tensile strength of triblock copolymer is nearly six times the strength of statistical copolymer, while their modulus are all around 3.0×103 Pa. The triblock copolymer films feel smooth and non-tacky as the PSt content is higher than 20%. It indicates that PSt-b-PnBA-b-PSt triblock copolymers can be used as binders in pigment dyeing, providing the dyed fabrics with soft non-tacky handle and good fastness properties.

Synthesis of diblock and triblock copolymers from butyl acrylate and styrene by reverse iodine transfer polymerization

2010 ◽  
Vol 119 (4) ◽  
pp. 2476-2484 ◽  
Author(s):  
Francisco J. Enríquez-Medrano ◽  
Ramiro Guerrero-Santos ◽  
Martín Hernández-Valdez ◽  
Patrick Lacroix-Desmazes
Keyword(s):  
Butyl Acrylate ◽  
Triblock Copolymers ◽  
Iodine Transfer

Anionic polymerization of acrylic monomers. 6. Synthesis, characterization, and modification of poly(methyl methacrylate)-poly(tert-butyl acrylate) di- and triblock copolymers

1991 ◽  
Vol 24 (18) ◽  
pp. 4997-5000 ◽  
Author(s):  
Sunil K. Varshney ◽  
Christian Jacobs ◽  
Jean Paul Hautekeer ◽  
Philippe Bayard ◽  
Robert Jerome ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Butyl Acrylate ◽  
Triblock Copolymers ◽  
Poly Methyl Methacrylate ◽  
Tert Butyl ◽  
Acrylic Monomers
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