A Method for Determining Diffusion Constants of Colloids which Show Mechanical Birefringence

1932 ◽  
Vol 3 (4) ◽  
pp. 494-500 ◽  
Author(s):  
Paul Boeder
Keyword(s):  
Diffusion Constants

scholarly journals Relationship between Li+ diffusion and ion conduction for single-crystal and powder garnet-type electrolytes studied by 7Li PGSE NMR spectroscopy

2019 ◽  
Vol 21 (42) ◽  
pp. 23589-23597 ◽  
Author(s):  
Kikuko Hayamizu ◽  
Yasuhiko Terada ◽  
Kunimitsu Kataoka ◽  
Junji Akimoto ◽  
Tomoyuki Haishi
Keyword(s):  
Nmr Spectroscopy ◽  
Ionic Conductivity ◽  
Single Crystal ◽  
Ion Conduction ◽  
Diffusion Constants ◽  
Pgse Nmr

Li-diffusion constants of single-crystal and powder garnets were determined and plotted versus ionic conductivity. Estimated NE carrier numbers were larger than atomic Li numbers for metal containing garnets and insensitive to temperature.

ULTRACENTRIFUGE AND DIFFUSION STUDIES ON GLUTEN

1942 ◽  
Vol 20c (3) ◽  
pp. 130-159 ◽  
Author(s):  
A. G. McCalla ◽  
Nils Gralén
Keyword(s):  
Sodium Salicylate ◽  
Minimum Weight ◽  
Average Molecular Weight ◽  
Sedimentation Equilibrium ◽  
Velocity Sedimentation ◽  
Molecular Characteristics ◽  
Weight Average Molecular Weight ◽  
Diffusion Constants ◽  
Diffusion Studies ◽  
And Diffusion

The molecular characteristics of gluten in sodium salicylate solutions were studied by means of sedimentation velocity, sedimentation equilibrium, and diffusion measurements. The proportion of total gluten protein molecularly dispersed increased with increase in concentration of sodium salicylate up to 12%, but the dispersed portions had essentially the same sedimentation constant (2.5 ± 0.15) regardless of the concentration of the dispersing medium.The most soluble 25 per cent of the gluten was all molecularly dispersed, but was definitely inhomogeneous. The weight-average molecular weight of this fraction was 44,000, but there is reason to believe the minimum weight may be about 35,000. None of the other fractions was entirely molecularly dispersed, the proportion decreasing with decreasing solubility of the fractions. Aggregates of many sizes existed in all of these fractions, but only the most insoluble contained aggregates large enough to cause opacity. Sedimentation constants of the molecularly dispersed portions increased slightly with decreasing solubility, while diffusion constants decreased markedly. None of the fractions yielded normal curves (diffusion diagrams) but the more soluble the fraction, the more nearly normal the curve. The inhomogeneity responsible for the varying rates of diffusion was due partly to differences in proportion and properties of the molecularly dispersed gluten and partly to aggregates.All properties showed progressive changes both within and between the arbitrarily produced fractions. These results, therefore, support the hypothesis that gluten is a protein system showing progressive and regular changes in properties with change in solubility.

scholarly journals A dynamical mean field theory for the study of surface diffusion constants

1997 ◽  
Vol 380 (2-3) ◽  
pp. L501-L505 ◽  
Author(s):  
T. Hjelt ◽  
I. Vattulainen ◽  
J. Merikoski ◽  
T. Ala-Nissila ◽  
S.C. Ying
Keyword(s):  
Field Theory ◽  
Surface Diffusion ◽  
Mean Field Theory ◽  
Mean Field ◽  
Dynamical Mean Field Theory ◽  
Diffusion Constants

Method of determining the diffusion constants of helium in plastics

1972 ◽  
Vol 4 (2) ◽  
pp. 308-309
Author(s):  
A. M. Poimanov ◽  
A. R. Bel'nik ◽  
V. N. Moiseev
Keyword(s):  
Diffusion Constants

Diffusion of Ce-Al Melts Measured by Sliding Cell Technique

2017 ◽  
Vol 898 ◽  
pp. 679-683
Author(s):  
Cheng Chen ◽  
Jin Liang Hu ◽  
Lang Xiang Zhong ◽  
Bo Zhang
Keyword(s):  
Activation Energy ◽  
Temperature Dependence ◽  
Strong Interaction ◽  
Al Alloy ◽  
Diffusion Behavior ◽  
Diffusion Constants

The diffusion behavior of Ce-Al alloy melt at three temperatures of 943K, 953K and 963K was investigated by sliding shear method. The inter-diffusion constants D show Arrhenius-type temperature dependence in the investigated regimes. Compared with the previous results achieved in Ce-Cu melt, liquid Ce-Al displays a much slower diffusion behavior and rather higher activation energy ED, which was caused by the strong interaction between Ce and Al.

A laser interferometric study of the diffusion of O2, N2, H2, and Ar into water

1977 ◽  
Vol 55 (8) ◽  
pp. 1415-1421 ◽  
Author(s):  
Robert Neville O'Brien ◽  
William Frank Hyslop
Keyword(s):  
Surface Resistance ◽  
Diffusion Constants ◽  
Interferometric Study ◽  
Laser Interferometric

The diffusion constants of O2, N2, H2, and Ar at 24 °C in H2O are calculated from interferometric data. The question of surface resistance to diffusion of O2 into water is discussed. There appears to be no such resistance.

scholarly journals A rapid method for determining diffusion constants in solution

1948 ◽  
Vol 192 (1030) ◽  
pp. 382-402 ◽  
Keyword(s):  
Monochromatic Light ◽  
Diffusion Constant ◽  
Initial Boundary ◽  
Optic Axis ◽  
Theory And Practice ◽  
Dilute Solution ◽  
Sharp Boundary ◽  
Diffusion Constants ◽  
A Cell ◽  
Molecular Substances

A method has been rediscovered, and developed in theory and practice, for optical observation of the earliest stages of diffusion across an initially sharp boundary between a dilute solution and a solvent. It enables the diffusion constant of a monodisperse solute to be measured about fifty times as quickly as by other methods, at lower concentration and possibly with greater accuracy; it should therefore be particularly valuable for the study of high molecular substances. The method is based on the interference pattern which is formed when monochromatic light from a horizontal slit is focused after passing through a cell where diffusion is occurring. The pattern, a set of horizontal bands, contracts towards the optic axis as diffusion proceeds, at a rate from which the diffusion constant can be calculated. By counting the bands in the pattern the refractive increment of the solute can be determined. The sharp initial boundary is obtained by flowing the solution and solvent out through a common narrow horizontal slit. The construction, calibration, and use of the apparatus are described.

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