Decomposition of effective specific heat of molecular relaxation for gas detection in a mixture

2017 ◽  
Vol 141 (3) ◽  
pp. 1844-1851 ◽  
Author(s):  
Tingting Liu ◽  
Shu Wang ◽  
Ming Zhu
2016 ◽  
Vol 716 ◽  
pp. 555-565
Author(s):  
Michael P. Howson ◽  
Bradley P. Wynne ◽  
Peter S. Davies ◽  
Sinan S. Al-Bermani ◽  
Jesus Talamantes-Silva

The present work explores the importance of model parameters and input variables when simulating the quenching of thick sectioned nuclear forgings. The modelling approach adopted uses values of specific heat capacity, containing latent heat release, to simulate cooling curves; rather than calculating transformation kinetics based upon a mathematical model. Termed the effective specific heat (Cpeff), two different methods were used to establish values: differential scanning calorimetry (DSC) and thermos dynamic predictive software. Values were then included in finite element (FE) models to simulate the characteristic cooling at the mid-wall position in a thick section forging and were validated against production thermocouple data. The investigation found that the formation of ferrite, bainite and martensite or lower bainite were all represented by the data established using DSC and critical formation temperatures were comparable with others in the literature. Conversely, values calculated using the thermodynamic software failed to represent ferrite formation and predicted different critical transformation temperatures for bainite. The simulated cooling curve that used the software predicted Cpeff data was comparable to the thermocouple data either side of the bainite transformation, however during the transformation the effects of latent heat on cooling rate were over predicting leading to disparities. The equivalent DSC cooling curves produced a near exact match.


Pramana ◽  
1974 ◽  
Vol 3 (6) ◽  
pp. 383-389
Author(s):  
P B Lal Chaurasia ◽  
D R Chaudhary ◽  
R C Bhandari

2019 ◽  
Vol 282 ◽  
pp. 02052
Author(s):  
Václav Kočí ◽  
Jiří Maděra ◽  
Robert Černý

A precise technique for determination of effective specific heat capacity of building materials is presented within this paper. The applicability of the technique is demonstrated on a PCM-enhanced plaster, being characterized by a phase change between 15 and 30 °C. The effective specific heat capacity is determined by means of inverse analysis of calorimetric data using computational model of the device. The identified effective specific heat capacity values reached up to 1890 J·kg-1·K-1 when cooled and 1580 J·kg-1·K-1 when heated. Using this quantity in simulation of thermal performance, the PCM-enhanced plaster showed to have a promising potential to be used in buildings’ interiors as a thermal regulator to stabilize inner environment as it contributed to a thermal oscillation decrease by up to 2.5 °C


1972 ◽  
Vol 50 (20) ◽  
pp. 2464-2470 ◽  
Author(s):  
R. M. Yealland ◽  
J. M. Deckers ◽  
I. D. Scott ◽  
C. T. Tuori

Measurements have been made of the concentration of dimers produced during the expansion from a supersonic nozzle. The gases studied were: Ar, N2,O2, CO, CO2, C2H4, and N2O. It is shown that an effective specific heat ratio of the expanding gas offers a means of correlating the dimer concentration in terms of the source gas pressure and temperature. The two nozzles employed had opening diameters of 0.14 mm and 0.065 mm. An attempt to obtain a universal dependence for all gases in terms of reduced source parameters was partially successful. Source temperature was varied between 90 °K and 295 °K.


1983 ◽  
Vol 36 (6) ◽  
pp. 891 ◽  
Author(s):  
S Lee

According to a new theory based on energy balance, the radius ratio Yp/Yo of a constant-current plasma pinch depends only on the value of the effective specific heat ratio y of the pinched plasma. In this paper the value of y for argon is computed as a function of temperature. From these values the constant-current pinch ratios are computed. The results show argon pinch ratios of about o� 08 from (2-4) x 106 K, rising to 0�18 at 1�1 x 107 K and to O� 27 at 108 K. There is good agreement between this theory and an Imperial College measurement of Y o/ro ~ 0 �17 for a constant-current argon pinch at an estimated temperature of 1 keY.


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