Fourth order perturbation theory for the diffusion equation: continuous-wave results for absorbing defects

2009 ◽  
Author(s):  
Angelo Sassaroli ◽  
Fabrizio Martelli ◽  
Sergio Fantini
Keyword(s):  
Perturbation Theory ◽  
Diffusion Equation ◽  
Fourth Order ◽  
Continuous Wave ◽  
Order Perturbation ◽  
Order Perturbation Theory

Field-Dependence of Chemical Shifts in Colbalt(III) N.M.R. Spectroscopy. Theoretical Predictions

1979 ◽  
Vol 32 (1) ◽  
pp. 1 ◽  
Author(s):  
DM Doddrell ◽  
DT Pegg ◽  
MR Bendell
Keyword(s):  
Perturbation Theory ◽  
Field Dependence ◽  
Fourth Order ◽  
Chemical Shifts ◽  
Order Perturbation ◽  
Order Perturbation Theory ◽  
Chemical Shielding ◽  
Field Dependent ◽  
Theoretical Predictions ◽  
Shielding Tensor

Ramsey's suggestion of fourth-order perturbation theory contribution to a field-dependent chemical shielding arising from paramagnetic currents is more closely examined. The effect is shown to be opposite in sign to the field-invariant chemical shielding tensor and, for cobalt(111) chemical shifts, only becomes important for some complexes for field strengths in excess of 20T.

Sign in / Sign up

Export Citation Format

Share Document