Light intensity dependence of open-circuit voltage and short-circuit current of polymer/fullerene solar cells

Author(s):  
L. Jan A. Koster ◽  
Valentin D. Mihailetchi ◽  
Robert Ramaker ◽  
Hangxing Xie ◽  
Paul W. Blom
2011 ◽  
Vol 25 (09) ◽  
pp. 679-684 ◽  
Author(s):  
W. B. XIAO ◽  
X. D. HE ◽  
J. T. LIU ◽  
Y. Q. GAO

At room temperature, the performance of low-concentrating solar cells is investigated experimentally and discussed by theory. The results show that the short-circuit current, which is larger than that of unconcentrated radiation, linearly increases with the light intensity and is directly proportional to the concentration ratio. However, the different behavior is obtained for the open-circuit voltage. The open-circuit voltage is also larger than that at the unconcentrated light level and follows a logarithmic function of the light intensity, showing almost no dependence on the concentration ratios. The main reason is the decrease in internal resistance of solar cell with decreasing spot size, because the increase of incident light intensity leads to an increase of current density. Therefore, an advantage of the low-concentrating photovoltaic systems results from the improvement of the short-circuit current, but not from the open-circuit voltage. This work is very significant for the design of low-concentrating system.


2018 ◽  
Vol 9 ◽  
pp. 1802-1808 ◽  
Author(s):  
Katherine Atamanuk ◽  
Justin Luria ◽  
Bryan D Huey

The nanoscale optoelectronic properties of materials can be especially important for polycrystalline photovoltaics including many sensor and solar cell designs. For thin film solar cells such as CdTe, the open-circuit voltage and short-circuit current are especially critical performance indicators, often varying between and even within individual grains. A new method for directly mapping the open-circuit voltage leverages photo-conducting AFM, along with an additional proportional-integral-derivative feedback loop configured to maintain open-circuit conditions while scanning. Alternating with short-circuit current mapping efficiently provides complementary insight into the highly microstructurally sensitive local and ensemble photovoltaic performance. Furthermore, direct open-circuit voltage mapping is compatible with tomographic AFM, which additionally leverages gradual nanoscale milling by the AFM probe essentially for serial sectioning. The two-dimensional and three-dimensional results for CdTe solar cells during in situ illumination reveal local to mesoscale contributions to PV performance based on the order of magnitude variations in photovoltaic properties with distinct grains, at grain boundaries, and for sub-granular planar defects.


NANO ◽  
2019 ◽  
Vol 14 (10) ◽  
pp. 1950127 ◽  
Author(s):  
Farhad Jahantigh ◽  
S. M. Bagher Ghorashi

Perovskite solar cells have recently been considered to be an auspicious candidate for the advancement of future photovoltaic research. A power conversion efficiency (PCE) as high as 22% has been reported to be reached, which can be obtained through an inexpensive and high-throughput solution process. Modeling and simulation of these cells can provide deep insights into their fundamental mechanism of performance. In this paper, two different perovskite solar cells are designed by using COMSOL Multiphysics to optimize the thickness of each layer and the overall thickness of the cell. Electric potential, electron and hole concentrations, generation rate, open-circuit voltage, short-circuit current and the output power were calculated. Finally, PCEs of 20.7% and 26.1% were predicted. Afterwards, according to the simulation results, the role of the hole transport layer (HTL) was investigated and the optimum thickness of the perovskite was measured to be 200[Formula: see text]nm for both cells. Therefore, the spin coating settings are selected so that a coating with this thickness for cell 1 is deposited. In order to compare the performance of HTM layer, solar cells with a Spiro-OMeTAD HTM and without the HTM layer in their structure were fabricated. According to the obtained photovoltaic properties, the solar cell made with Spiro-OMeTAD has a more favorable open-circuit voltage ([Formula: see text]), short-circuit current density ([Formula: see text]), fill factor (FF) and PCE compared to the cell without the HTM layer. Also, hysteresis depends strongly on the perovskite grain size, because large average grain size will lead to an increase in the grain’s contact surface area and a decrease in the density of grain boundaries. Finally, according to the results, it was concluded that, in the presence of a hole transport layer, ion transfer was better and ion accumulation was less intense, and therefore, the hysteresis decreases.


2014 ◽  
Vol 665 ◽  
pp. 111-114 ◽  
Author(s):  
Ying Huang ◽  
Xiao Ming Shen ◽  
Xiao Feng Wei

In this paper, InAlN/Si single-heterojunction solar cells have been theoretically simulated based on wxAMPS software. The photovoltaic parameters, such as open circuit voltage, short circuit current, fill factor and conversion efficiency were investigated with changing the indium content and thickness of n-InAlN layer. Simulation results show that the optimum efficiency of InAlN/Si solar cells is 23.1% under AM 1.5G spectral illuminations, with the indium content and thickness of n-InAlN layer are 0.65 and 600nm, respectively. The simulation would contribute to design and fabricate high efficiency InAlN/Si solar cells in experiment.


2005 ◽  
Vol 87 (20) ◽  
pp. 203502 ◽  
Author(s):  
L. J. A. Koster ◽  
V. D. Mihailetchi ◽  
H. Xie ◽  
P. W. M. Blom

2021 ◽  
Vol 5 (3) ◽  
pp. 242-250
Author(s):  
D. Sergeyev ◽  
K. Shunkeyev ◽  
B. Kuatov ◽  
N. Zhanturina

In this paper, the features of the characteristics of model thin-film solar cells based on the non-toxic multicomponent compound CuZn2AlS4 (CZAS) are considered. The main parameters (open-circuit voltage, short-circuit current, fill factor, efficiency) and characteristics (quantum efficiency, current-voltage characteristic) of thin-film solar cells based on CZAS have been determined. The minimum optimal thickness of the CZAS absorber is found (1-1.25 microns). Deterioration of the performance of solar cells with an increase in operating temperature (280-400 K) is shown. It is revealed that in the wavelength range of 390-500 nm CZAS has a high external quantum efficiency, which allows its use in designs of multi-junction solar cells designed to absorb solar radiation in the specified range. It is shown that the combination of CZAS films with a buffer layer of non-toxic ZnS increases the performance of solar cells.


2014 ◽  
Vol 116 (15) ◽  
pp. 154506 ◽  
Author(s):  
Yong Zhao ◽  
Chunjun Liang ◽  
Mengjie Sun ◽  
Qian Liu ◽  
Fujun Zhang ◽  
...  

Solar Cells ◽  
1991 ◽  
Vol 31 (3) ◽  
pp. 279-281 ◽  
Author(s):  
Guo-cai Dai ◽  
Qing-hai Miao ◽  
Zhong-zao Ren ◽  
Zhen-xun Zheng ◽  
Hong-lei Ma

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