Synthesis of some erbium(III) chelates and characterization of their NIR emission properties for use in organic near infrared optical amplification waveguides

2005 ◽  
Author(s):  
Laurent Divay ◽  
Pierre Le Barny ◽  
Jacques Delaire ◽  
Brigitte Loiseaux
Keyword(s):  
Near Infrared ◽  
Optical Amplification ◽  
Emission Properties ◽  
Nir Emission

Highly Fluorescent Au25-xAgx Nanoclusters Protected with Poly(ethylene glycol) - and Zwitterion-Modified Thiolate Ligands

2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi
Keyword(s):  
Quantum Yield ◽  
Near Infrared ◽  
Small Diameter ◽  
Binding Energies ◽  
Thiolate Ligands ◽  
Nir Emission ◽  
Thiolate Complexes ◽  
Long Lifetime ◽  
Poly Ethylene

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>

Highly Fluorescent Au25-xAgx Nanoclusters Protected with Poly(ethylene glycol) - and Zwitterion-Modified Thiolate Ligands

2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi
Keyword(s):  
Quantum Yield ◽  
Near Infrared ◽  
Small Diameter ◽  
Binding Energies ◽  
Thiolate Ligands ◽  
Nir Emission ◽  
Thiolate Complexes ◽  
Long Lifetime ◽  
Poly Ethylene

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>

Effect of Ce3+ Concentration on the Luminescence Properties of Ce3+/Er3+/Yb3+ Tri-Doped NaYF4 Nanocrystals

2016 ◽  
Vol 16 (4) ◽  
pp. 3749-3753 ◽  
Author(s):  
Xuee Liu ◽  
Jianbei Qiu ◽  
Xuhui Xu ◽  
Dacheng Zhou
Keyword(s):  
Energy Transfer ◽  
Hydrothermal Method ◽  
Fluorescence Intensity ◽  
Emission Intensity ◽  
Doping Concentration ◽  
Near Infrared ◽  
Luminescence Properties ◽  
Emission Mechanism ◽  
Emission Properties ◽  
Nir Emission

In order to investigate the effect of Ce3+ concentration on the emission properties of Er3+/Yb3+ codoped NaYF4 nanocrystals, Ce3+/Er3+/Yb3+ tri-doped NaYF4 nanocrystals were prepared through a facile EDTA-assisted hydrothermal method. The upconversion (UC) and the near infrared (NIR) emission properties of Er3+ ions were systematically investigated in the NaYF4:Ce3+/Er3+/Yb3+ nanocrystals. Under 980 nm excitation, with the increasing of Ce3+ concentration, the emission intensity of Er3+ at 1550 nm (4I13/2 → 4I15/2) band increases initially and then decreases. The increase of the fluorescence intensity of 1550 nm is due to the energy transfer between Er3+ and Ce3+ ions: Er3+:4I11/2 +Ce3+:2F5/2 → Er3+:4I13/2 +Ce3+:2F7/2. But when Ce3+ doping concentration is 2.0%, the cross relaxation:Er3+:4I13/2 +Ce3+:2F5/2 →Er3+:4I15/2 +Ce3+:2F7/2 happens, which depopulates the 4I13/2 level of Er3+ and results in the decrease of the emission intensity of Er3+ at 1550 nm band. Meanwhile, incorporation of Ce3+ dramatically decreases the visible UC emission intensity. A possible emission mechanism was proposed.

A novel strategy to prepare 2D YBO: Ce-Yb nanosheets with enhanced near-infrared (NIR) emission properties

2017 ◽  
Vol 259 ◽  
pp. e49
Author(s):  
Hui Miao ◽  
Guowei Zhang ◽  
Xiaoyun Hu ◽  
Enzhou Liu ◽  
Jintao Bai ◽  
...  
Keyword(s):  
Near Infrared ◽  
Emission Properties ◽  
Nir Emission ◽  
Novel Strategy

Effects of fused rings linked to the 2,5-position of pyrrole derivatives with near-infrared emission on their aggregation-enhanced emission properties

2019 ◽  
Vol 3 (10) ◽  
pp. 2072-2076 ◽  
Author(s):  
Fei Ren ◽  
Jianbing Shi ◽  
Bin Tong ◽  
Zhengxu Cai ◽  
Yuping Dong
Keyword(s):  
Near Infrared ◽  
Infrared Emission ◽  
Pyrrole Derivatives ◽  
Emission Properties ◽  
Nir Emission ◽  
Near Infrared Emission

Pyrrole derivatives with NIR emission and AEE properties were synthesized through introducing different fused rings and a furanylidene group.

Ligand Influence Versus Electronic Configuration of d-metal Ion in Determining the Fate of NIR Emission from LnIII Ions: A Case Study with CuII, NiII and ZnII Complexes.

2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha
Keyword(s):  
Metal Ion ◽  
Selection Rule ◽  
Near Infrared ◽  
Electronic Configuration ◽  
Infrared Region ◽  
Direct Excitation ◽  
Characteristic Emission ◽  
Nir Emission ◽  
Near Infrared Region

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...

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