Nd3+-doped sol-gel glasses: enhanced fluorescence lifetime by Al-codoping and CO2-laser processing

2003 ◽  
Author(s):  
Bettina Wilhelm ◽  
Valerio Romano ◽  
Heinz P. Weber
Author(s):  
George C. Ruben ◽  
Merrill W. Shafer

Traditionally ceramics have been shaped from powders and densified at temperatures close to their liquid point. New processing methods using various types of sols, gels, and organometallic precursors at low temperature which enable densificatlon at elevated temperatures well below their liquidus, hold the promise of producing ceramics and glasses of controlled and reproducible properties that are highly reliable for electronic, structural, space or medical applications. Ultrastructure processing of silicon alkoxides in acid medium and mixtures of Ludox HS-40 (120Å spheres from DuPont) and Kasil (38% K2O &62% SiO2) in basic medium have been aimed at producing materials with a range of well defined pore sizes (∼20-400Å) to study physical phenomena and materials behavior in well characterized confined geometries. We have studied Pt/C surface replicas of some of these porous sol-gels prepared at temperatures below their glass transition point.


2004 ◽  
Vol 398 (1-3) ◽  
pp. 151-156 ◽  
Author(s):  
M. Feuillade ◽  
C. Croutxé-Barghorn ◽  
L. Mager ◽  
C. Carré ◽  
A. Fort

1998 ◽  
Vol 519 ◽  
Author(s):  
L. Bergogne ◽  
S. Fennouh ◽  
J. Livage ◽  
C. Roux

AbstractBioencapsulation in sol-gel materials has been widely studied during the past decade. Trapped species appear to retain their bioactivity in the porous silica matrix. Small analytes can diffuse through the pores allowing bioreactions to be performed in-situ, inside the sol-gel glass. A wide range of biomolecules and micro-organisms have been encapsulated. The catalytic activity of enzymes is used for the realization of biosensors or bioreactors. Antibody-antigen recognition has been shown to be feasible within sol-gel matrices. Trapped antibodies bind specifically the corresponding haptens and can be used for the detection of traces of chemicals. Even whole cells are now encapsulated without any alteration of their cellular organization. They can be used for the production of chemicals or as antigens for immunoassays.


2004 ◽  
Vol 30 (3) ◽  
pp. 205-214 ◽  
Author(s):  
Massimo Bottini ◽  
Almerinda Di Venere ◽  
Lutz Tautz ◽  
Alessandro Desideri ◽  
Paolo Lugli ◽  
...  

2017 ◽  
Vol 8 (4) ◽  
pp. 364-371 ◽  
Author(s):  
Daniela Carta ◽  
Julian R. Jones ◽  
Sen Lin ◽  
Gowsihan Poologasundarampillai ◽  
Robert J. Newport ◽  
...  

1994 ◽  
Vol 9 (10) ◽  
pp. 2703-2705 ◽  
Author(s):  
Fengqing Wu ◽  
David Machewirth ◽  
Elias Snitzer ◽  
George H. Sigel

High quality Nd-doped single-mode fibers have been prepared by using a sol-gel process. The longest fluorescence lifetime measured was 520 μs in an Al: SiO2 glass fiber containing 0.47 wt.% neodymium oxide. An efficient neodymium fiber laser with a slope above threshold of 42% was successfully demonstrated with the sol-gel prepared Nd-doped single-mode fibers as a fiber laser oscillator.


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