Azobenzene-polymer-stabilized ferroelectric liquid crystals: photoalignment and morphology

Author(s):  
Yue Zhao ◽  
Nadine Paiement ◽  
Sonia Sevigny ◽  
Steve LeClair ◽  
Shahrokh Motallebi ◽  
...  
2005 ◽  
Vol 32 (5) ◽  
pp. 599-607 ◽  
Author(s):  
Sonia Sévigny ◽  
Luc Bouchard ◽  
Shahrokh Motallebi ◽  
Yue Zhao

2004 ◽  
Vol 76 (7-8) ◽  
pp. 1499-1508 ◽  
Author(s):  
Yue Zhao

The reversible trans–cis photoisomerization of azobenzene and azopyridine chromophore was used to design and exploit novel photoactive materials based on polymers and liquid crystals. This paper reviews our recent studies on several systems. These include azobenzene-containing thermoplastic elastomers that can be used to prepare mechanically tunable diffraction gratings, side-chain azopyridine polymers for combined self-assembly and photoactivity, azobenzene polymer-stabilized ferroelectric liquid crystals whose bulk alignment can be achieved by light with no need for surface orientation layers, and, finally, self-assembled photoactive liquid-crystal gels that can display light-induced reorganization leading to the formation of electrically switchable diffraction gratings.


MRS Bulletin ◽  
1997 ◽  
Vol 22 (9) ◽  
pp. 15-20 ◽  
Author(s):  
Christopher N. Bowman ◽  
C. Allan Guymon

The following is based on the presentation made by Christopher N. Bowman, recipient of the MRS Outstanding Investigator Award, at the 1997 MRS Spring Meeting.I would like to focus on our recent work involving photopolymerizations of monomers in a liquid-crystalline environment. This work is one of the many aspects of photopolymerizations that we are focusing on at the University of Colorado. In particular this effort concentrates on understanding the influence of a liquid-crystalline medium and monomer segregation on polymerization behavior and polymer structure. These studies are of considerable importance for polymer-stabilized ferroelectric liquid crystals (FLCs) because of the enormous potential impact on the area.I will briefly introduce liquid crystals (LCs), FLCs, and photopolymerizations. I will then discuss the observed electrooptic properties and how these properties change as the LC phase during polymerization is varied. Finally I will address how polymerization kinetics are affected by the LC phase and monomer segregation. This discussion will include results from x-ray diffraction, polarized infrared spectroscopy, and differential scanning calorimetry experiments.


2008 ◽  
Vol 364 (1) ◽  
pp. 78-85 ◽  
Author(s):  
Toru Fujisawa ◽  
Isa Nishiyama ◽  
Kazuaki Hatsusaka ◽  
Kiyofumi Takeuchi ◽  
Haruyoshi Takatsu ◽  
...  

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