Liquid crystalline light-emitting thermally stable readily processable substituted polyacetylenes

Author(s):  
Ben Z. Tang ◽  
Jacky W. Lam ◽  
Jingdong Luo ◽  
Yuping Dong ◽  
Kevin K. Cheuk ◽  
...  
Author(s):  
Vinay S. Sharma ◽  
Anuj S. Sharma ◽  
Nikhil K. Agarwal ◽  
Priyanka A. Shah ◽  
Pranav S. Shrivastav

Correction for ‘Self-assembled blue-light emitting materials for their liquid crystalline and OLED applications: from a simple molecular design to supramolecular materials’ by Vinay S. Sharma et al., Mol. Syst. Des. Eng., 2020, 5, 1691–1705, DOI: 10.1039/D0ME00117A.


2021 ◽  
Author(s):  
Benedikt Grau ◽  
Maximilian Dill ◽  
Frank Hampel ◽  
Axel Kahnt ◽  
Norbert Jux ◽  
...  

Hexaarylbenzene (HAB) derivatives are versatile aromatic systems playing a significant role as chromophores, liquid crystalline materials, molecular receptors, redox materials, organic light-emitting diodes and photochemical switches. Statistical synthesis of simple symmetrical HABs is known <i>via</i> low-yielding cyclotrimerization or Diels-Alder reactions. By contrast, the synthesis of more complex, asymmetrical systems, and without involvement of statistical steps, remains an unsolved problem. Here we present a generally applicable synthetic strategy to access asymmetrical HAB <i>via</i> an atom-economical and high-yielding metal-free four-step domino reaction using nitrostyrenes and <i>α,α</i>-dicyanoolefins as easily available starting materials. Resulting domino product – functionalized triarylbenzene (TAB) - can be used as a key starting compound to furnish asymmetrically substituted hexaarylbenzenes in high overall yield and without involvement of statistical steps. This straightforward domino process represents a distinct approach to creating diverse and still unexplored HAB scaffolds, containing six different aromatic rings around central benzene core.


2011 ◽  
Vol 23 (48) ◽  
pp. 5767-5772 ◽  
Author(s):  
Seung-Yeon Kwak ◽  
SeungCheol Yang ◽  
Na Ree Kim ◽  
Jae Hong Kim ◽  
Byeong-Soo Bae

2020 ◽  
Vol 44 (15) ◽  
pp. 5684-5691 ◽  
Author(s):  
Shigeyuki Yamada ◽  
Akira Mitsuda ◽  
Kaoru Adachi ◽  
Mitsuo Hara ◽  
Tsutomu Konno

Light-emitting liquid-crystalline polymers showing PL in the pristine solid state can control their PL color from blue to light-blue via a thermal phase transition to LC phases, which originates from a dynamic change of aggregated structures.


CrystEngComm ◽  
2020 ◽  
Vol 22 (15) ◽  
pp. 2667-2674 ◽  
Author(s):  
Qipeng Li ◽  
Jinjie Qian ◽  
Jie Zhou ◽  
Lin Du ◽  
Qihua Zhao

A series of isomorphic of highly chemically and thermally stable lanthanide coordination polymers exhibit luminescent probe and warm white-light emission.


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