Spectroscopic properties of rare-earth ions in heavy metal oxide and phosphate-containing glasses

1999 ◽  
Author(s):  
H. Ebendorff-Heidepriem ◽  
Doris Ehrt ◽  
Marco Bettinelli ◽  
Adolfo Speghini
Keyword(s):  
Heavy Metal ◽  
Rare Earth ◽  
Metal Oxide ◽  
Spectroscopic Properties ◽  
Rare Earth Ions

scholarly journals Replacement of glass-former B2O3 by GeO2 in amorphous host evidenced by optical methods

2017 ◽  
Vol 9 (4) ◽  
pp. 113
Author(s):  
Joanna Pisarska ◽  
Wojciech Pisarski
Keyword(s):  
Heavy Metal ◽  
Rare Earth ◽  
Glass Ceramics ◽  
Spectroscopic Properties ◽  
Rare Earth Ions ◽  
Optical Methods ◽  
Lead Borate ◽  
Rare Earth Doped ◽  
Germanate Glasses ◽  
Metal Glasses

Two completely different glass-host matrices containing lead, i.e. borate and germanate glasses doped with erbium were studied. Replacement of glass-former B2O3 by GeO2 in amorphous host was evidenced by optical methods. The luminescence decay from the 4I13/2 upper laser state of Er3+ ions is relatively short, whereas up-converted emission signal is reduced definitely in borate glass containing lead due to its high B-O stretching vibrations. The results indicate that germanate glasses containing lead are promising for near-infrared luminescence and up-conversion applications. Full Text: PDF ReferencesR. Balda, A. Oleaga, J. Fernandez, J.M. Fdez-Navarro, "Spectroscopy and frequency upconversion of Er3+ ions in lead niobium germanate glasses", Opt. Mater. 24, 83 (2003). CrossRef H. Yamauchi, Y. Ohishi, "Spectroscopic properties of Er3+-doped PbO?Ga2O3?GeO2 glass for optical amplifiers", Opt. Mater. 27, 679 (2005). CrossRef W.A. Pisarski, Ł. Grobelny, J. Pisarska, R. Lisiecki, W. Ryba-Romanowski, "Spectroscopic properties of Yb3+ and Er3+ ions in heavy metal glasses", J. Alloys Compd. 509, 8088 (2011). CrossRef M.B. Saisudha, J. Ramakrishna, "Effect of host glass on the optical absorption properties of Nd3+, Sm3+, and Dy3+ in lead borate glasses", Phys. Rev. B 53, 6186 (1996). CrossRef C.K. Jayasankar, V. Venkatramu, S. Surendra Babu, P. Babu, "Luminescence properties of Dy3+ ions in a variety of borate and fluoroborate glasses containing lithium, zinc, and lead", J. Alloys Compd. 374, 22 (2004). CrossRef W.A. Pisarski et al. "Luminescence spectroscopy of rare earth-doped oxychloride lead borate glasses", J. Lumin. 131, 649 (2011). CrossRef M. Kochanowicz, W. Mazerski, J. Żmojda, K. Czajkowski, D. Dorosz, "Green upconversion emission in tellurite optical fibre codoped with Yb3+/Er3+", Phot. Lett. Poland 5, 35 (2013). CrossRef J. Dorosz, "Novel constructions of optical fibers doped with rare ? earth ions", Ceramics 86 (2005). CrossRef J. Żmojda, D. Dorosz, M. Kochanowicz, J. Dorosz, "Spectroscopic properties of Yb3+/Er3+ - doped antimony-phosphate glasses for fiber amplifiers", Phot. Lett. Poland 2, 76 (2010). CrossRef J. Dorosz, R. S. Romaniuk, "Development of Optical Fiber Technology in Poland", INTL J. Electron. Telecom. 57, 191 (2011). CrossRef Q.Y. Zhang et al. "Effects of PbF2 doping on structure and spectroscopic properties of Ga2O3?GeO2?Bi2O3?PbO glasses doped with rare earths", J. Appl. Phys. 99, 033510 (2006) CrossRef W.A. Pisarski, G. Dominiak-Dzik, W. Ryba-Romanowski, J. Pisarska, "Role of PbO substitution by PbF2 on structural behavior and luminescence of rare earth-doped lead borate glass", J. Alloys Compd. 451, 220 (2008). CrossRef M. Sołtys, J. Pisarska, L. Żur, T. Goryczka, W.A. Pisarski, "Influence of M2O3 (M = Al, Ga) glass modifiers on structure, thermal and spectroscopic properties of rare earth ions in lead phosphate based systems", Proc. SPIE 9228, 92280A (2014). CrossRef J. Janek, J. Pisarska, W.A. Pisarski, "Rare earth doped lead-free germanate glasses for modern photonics", Phot. Lett. Poland 6, 71 (2014). CrossRef W.A. Pisarski et al. "Infrared-to-visible conversion luminescence of Er3+ ions in lead borate transparent glass-ceramics", Opt. Mater. 31, 1781 (2009). CrossRef J. Pisarska, L. Żur, W.A. Pisarski, "Optical spectroscopy of Dy3+ ions in heavy metal lead-based glasses and glass?ceramics", J. Mol. Struct. 993, 160 (2011). CrossRef L. Żur, M. Sołtys, J. Pisarska, W.A. Pisarski, "Absorption and luminescence properties of terbium ions in heavy metal glasses", J. Alloys Compd. 578, 512 (2013). CrossRef W.A. Pisarski, L. Żur, M. Kowal, J. Pisarska, "Enhancement and quenching photoluminescence effects for rare earth ? Doped lead bismuth gallate glasses", J. Alloys Compd. 651, 565 (2015). CrossRef M. Shojiya, Y. Kawamoto, K. Kadono, "Judd?Ofelt parameters and multiphonon relaxation of Ho3+ ions in ZnCl2-based glass", J. Appl. Phys. 89, 4944 (2001). CrossRef

Evaluation of Spectroscopic Properties of Yb 3+ in Silicate-Based Heavy Metal Oxide Glasses

2003 ◽  
Vol 20 (3) ◽  
pp. 408-410 ◽  
Author(s):  
Dai Neng-Li ◽  
Hu Li-Li ◽  
Dai Shi-Xun ◽  
Yang Jian-Hu ◽  
Lin Ao-Xiang
Keyword(s):  
Heavy Metal ◽  
Metal Oxide ◽  
Spectroscopic Properties ◽  
Oxide Glasses

scholarly journals SiO2-SnO2:Er3+ Glass-Ceramic Monoliths

2018 ◽  
Author(s):  
Lam Thi Ngoc Tran ◽  
Damiano Massella ◽  
Lidia Zur ◽  
Alessandro Chiasera ◽  
Stefano Varas ◽  
...  
Keyword(s):  
Rare Earth ◽  
Optical Sensors ◽  
Tin Dioxide ◽  
Sol Gel ◽  
Glass Ceramics ◽  
Building Blocks ◽  
Spectroscopic Properties ◽  
Silica Matrix ◽  
Rare Earth Ions ◽  
Planar Waveguides

The development of efficient luminescent systems, such as microcavities, solid state lasers, integrated optical amplifiers, optical sensors is the main topic in glass photonics. The building blocks of these systems are glass-ceramics activated by rare earth ions because they exhibit specific morphologic, structural and spectroscopic properties. Among various materials that could be used as nanocrystals to be imbedded in silica matrix, tin dioxide presents some interesting peculiarities, e.g. the presence of tin dioxide nanocrystals allows increase in both solubility and emission of rare earth ions. Here, we focus our attention on Er3+ - doped silica – tin dioxide photonic glass-ceramics fabricated by sol-gel route. Although the SiO2-SnO2:Er3+ could be fabricated in different geometrical systems: thin films, monoliths and planar waveguides we herein limit ourselves to the monoliths. The effective role of tin dioxide as luminescence sensitizer for Er3+ ions is confirmed by spectroscopic measurements and detailed fabrication protocols are discussed.

The magnetic and spectroscopic properties of certain rare-earth double nitrates

1955 ◽  
Vol 232 (1191) ◽  
pp. 458-474 ◽  
Keyword(s):  
Rare Earth ◽  
Electric Field ◽  
Spectroscopic Properties ◽  
Rare Earth Ions ◽  
Rare Earth Ion ◽  
Crystalline Electric Field ◽  
Paramagnetic Resonance ◽  
Systematic Fashion ◽  
Resonance Data ◽  
Rare Earth Series

The theory that has been developed for rare-earth ions in crystals is here applied to the double nitrates. The paramagnetic resonance data and certain spectroscopic properties of the different rare-earth double nitrates, depending as they do on the crystalline electric field at a rare-earth ion, are related to the six parameters through which the field is defined. It is found that most of the experimental results can be fitted to values of the parameters that vary in a systematic fashion along the rare-earth series.

Electrical and Raman Spectroscopic Studies on Aurivillius Layered-Pervoskite Ceramics

2019 ◽  
Vol 1154 ◽  
pp. 80-90
Author(s):  
Mohammed Abdul Basheer ◽  
Vagmare Gangadhar ◽  
Guduru Prasad ◽  
Gobburu Subramanya Kumar ◽  
Nandi Venkata Prasad
Keyword(s):  
Rare Earth ◽  
Complex Impedance ◽  
Spectroscopic Properties ◽  
Spectroscopic Studies ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
Raman Spectroscopic ◽  
Solid State Route ◽  
A Site ◽  
Rare Earth La

Double rare-earth (La; Sm/Gd) substituted Aurivillius family of Bismuth Layered Structured Ferroelectrics (BLSF) namely Bi2.6Sm0.2La0.2TiNbO9 (BSLT; sample-A), Bi2.6Gd0.2La0.2TiNbO9 (BGLT; sample-B), single phase ceramics were prepared by solid state route. In addition, intergrowth (x BSLT - (1-x) BGLT, where x=0.49; sample-C) and solid solution (BSLT­x - BGLTy; where x + y=0.4; sample-D) materials were prepared. Dielectric, ferroelectric and Raman spectroscopic properties were studied on the said above materials. The X-ray diffraction analysis and Raman spectra revealed well-formation of stable structure. Though, the sample-C and sample-D have lower coercive field, compared to the sample-A and sample-B, but they exhibited sharp hysterisis loop. Therefore the instrinsic defects of sample-D inhabits more sensitivity towards the ferroelectric behaviour. The results were corroborated to the impedance and dielectrical data. The results were consistent with the SEM micrographs and complex impedance plots. An attempt is made to understand the effect of rare-earth ions on A-site of layered-pervoskite structure, defined as: (Bi2O2)2+(An-1BnO3n+1)2-.The term n represents number of pervoskite blocks interleaved with the bismuth oxide layers.

Dependence of the Spectroscopic Properties of Europium on the Spatial Distribution of Rare-Earth Ions in Fluorophosphate Glasses

2005 ◽  
Vol 31 (4) ◽  
pp. 420-426 ◽  
Author(s):  
T. V. Bocharova ◽  
G. O. Karapetyan ◽  
A. M. Mironov ◽  
N. O. Tagil’tseva ◽  
O. V. Yanush
Keyword(s):  
Spatial Distribution ◽  
Rare Earth ◽  
Spectroscopic Properties ◽  
Rare Earth Ions
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