Atmospheric trace gas measurements from the European Space Agency's Global Ozone Monitoring Experiment

1998 ◽  
Author(s):  
Kelly V. Chance ◽  
Robert J. D. Spurr ◽  
Thomas P. Kurosu
1984 ◽  
Vol 2 (1) ◽  
pp. 65-81 ◽  
Author(s):  
E. Robinson ◽  
W. L. Bamesberger ◽  
F. A. Menzia ◽  
A. S. Waylett ◽  
S. F. Waylett

2020 ◽  
Vol 13 (1) ◽  
pp. 101-117 ◽  
Author(s):  
Ece Satar ◽  
Peter Nyfeler ◽  
Bernhard Bereiter ◽  
Céline Pascale ◽  
Bernhard Niederhauser ◽  
...  

Abstract. Atmospheric trace gas measurements of greenhouse gases are critical in their precision and accuracy. In the past 5 years, atmospheric measurement and gas metrology communities have turned their attention to possible surface effects due to pressure and temperature variations during a standard cylinder's lifetime. This study concentrates on this issue by introducing newly built small-volume aluminum and steel cylinders which enable the investigation of trace gases and their affinity for adsorption and desorption on various surfaces over a set of temperature and pressure ranges. The presented experiments are designed to test the filling pressure dependencies up to 30 bar and temperature dependencies from −10 ∘C up to 180 ∘C for these prototype cylinders. We present measurements of CO2, CH4, CO and H2O using a cavity ring-down spectroscopy analyzer under these conditions. Moreover, we investigated CO2 amount fractions using a novel quantum cascade laser spectrometer system enabling measurements at pressures as a low as 5 mbar. This extensive dataset revealed that for absolute pressures down to 150 mbar the enhancement in the amount fraction of CO2 relative to its initial value (at 1200 mbar absolute) is limited to 0.12 µmol mol−1 for the prototype aluminum cylinder. Up to 80 ∘C, the aluminum cylinder showed superior results and less response to varying temperature compared to the steel cylinder. For CO2, these changes were insignificant at 80 ∘C for the aluminum cylinder, whereas a 0.11 µmol mol−1 enhancement for the steel cylinder was observed. High-temperature experiments showed that for both cylinders irreversible temperature effects occur especially above 130 ∘C.


1996 ◽  
Vol 35 (36) ◽  
pp. 7075 ◽  
Author(s):  
J. Roths ◽  
T. Zenker ◽  
U. Parchatka ◽  
F. G. Wienhold ◽  
G. W. Harris

1981 ◽  
Vol 8 (10) ◽  
pp. 1079-1082 ◽  
Author(s):  
R. Leifer ◽  
K. Sommers ◽  
S. F. Guggenheim

2004 ◽  
Vol 4 (1) ◽  
pp. 255-273 ◽  
Author(s):  
O. N. E. Tuinder ◽  
R. de Winter-Sorkina ◽  
P. J. H. Builtjes

Abstract. The radiative scattering by clouds leads to errors in the retrieval of column densities and concentration profiles of atmospheric trace gas species from satellites. Moreover, the presence of clouds changes the UV actinic flux and the photo-dissociation rates of various species significantly. The Global Ozone Monitoring Experiment (GOME) instrument on the ERS-2 satellite, principally designed to retrieve trace gases in the atmosphere, is also capable of detecting clouds. Four cloud fraction retrieval methods for GOME data that have been developed are discussed in this paper (the Initial Cloud Fitting Algorithm, the PMD Cloud Recognition Algorithm, the Optical Cloud Recognition Algorithm (an in-house version and the official implementation) and the Fast Retrieval Scheme for Clouds from the Oxygen A-band). Their results of cloud fraction retrieval are compared to each-other and also to synoptic surface observations. It is shown that all studied retrieval methods calculate an effective cloud fraction that is related to a cloud with a high optical thickness. Generally, we found ICFA to produce the lowest cloud fractions, followed by our in-house OCRA implementation, FRESCO, PC2K and finally the official OCRA implementation along four processed tracks (+2%, +10%, +15% and +25% compared to ICFA respectively). Synoptical surface observations gave the highest absolute cloud fraction when compared with individual PMD sub-pixels of roughly the same size.


Sign in / Sign up

Export Citation Format

Share Document