Steady-state and time-resolved fluorometry of fluorescent pollutants and heavy metal complexes

Author(s):  
Ute Resch ◽  
Knut Rurack
2005 ◽  
Vol 77 (6) ◽  
pp. 1035-1050 ◽  
Author(s):  
A. D’Aléo ◽  
S. Welter ◽  
E. Cecchetto ◽  
L. De Cola

The synthesis and photophysical properties of heterometallic dinuclear complexes based on ruthenium and osmium trisbipyridine units, Ru-mPh3-Os and Ru-mPh5-Os, in which the metal complexes are linked via an oligophenylene bridge centrally connected in the meta position, are described. Electronic energy transfer from the excited ruthenium-based component (donor) to the osmium moiety (acceptor) has been investigated using steady-state and time-resolved spectroscopy. The results obtained for the meta-substituted compounds are compared with the analogous systems in which the phenylene spacers are substituted in the para position. The mechanism of energy transfer is discussed.


RSC Advances ◽  
2021 ◽  
Author(s):  
Guanzhao Wen ◽  
Xianshao Zou ◽  
Rong Hu ◽  
Jun Peng ◽  
Zhifeng Chen ◽  
...  

Ground- and excited-states properties of N2200 have been studied by steady-state and time-resolved spectroscopies as well as time-dependent density functional theory calculations.


2021 ◽  
Author(s):  
Elena Bassan ◽  
Andrea Gualandi ◽  
Pier Giorgio Cozzi ◽  
Paola Ceroni

BODIPYs offer a versatile platform to build organic triplet photosensitisers for PDT, TTA upconversion and photocatalysis. Tuning their properties provides the opportunity of replacing heavy-metal complexes and can lead to improved sustainability.


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