Depolarization ratio of the ν1 Raman band of methane at different environment

2021 ◽  
Author(s):  
Dmitry V. Petrov ◽  
Aleksandr Tanichev
Keyword(s):  
Raman Band ◽  
Depolarization Ratio

scholarly journals Depolarization Ratio of the ν1 Raman Band of Pure CH4 and Perturbed by N2 and CO2

Molecules ◽  
2021 ◽  
Vol 27 (1) ◽  
pp. 144
Author(s):  
Aleksandr S. Tanichev ◽  
Dmitry V. Petrov
Keyword(s):  
Carbon Dioxide ◽  
Raman Spectroscopy ◽  
Raman Spectrum ◽  
Pressure Range ◽  
Raman Band ◽  
High Sensitivity ◽  
Gas Analysis ◽  
Depolarization Ratio ◽  
Single Pass ◽  
Pure Methane

In this work, the effect of nitrogen and carbon dioxide on the depolarization ratio of the ν1 band of methane in the pressure range of 0.1–5 MPa is studied. A high-sensitivity single-pass Raman spectrometer was used to obtain accurate results. Moreover, we took into account the overlap of the ν1 band by the ν3 and ν2 + ν4 bands using the simulation of their spectra. The depolarization ratio of the ν1 band in pure methane is within 0–0.001, and the effect of nitrogen and carbon dioxide on this parameter is negligible in the indicated pressure range. The obtained results are useful for correct simulation of the Raman spectrum of methane at different pressures, which is necessary to improve the accuracy of gas analysis methods using Raman spectroscopy.

RAMAN SPECTRA OF TITANIUM DI-, TRI-, AND TETRA-CHLORIDES

2001 ◽  
Vol 15 (28n30) ◽  
pp. 3865-3868 ◽  
Author(s):  
H. MIYAOKA ◽  
T. KUZE ◽  
H. SANO ◽  
H. MORI ◽  
G. MIZUTANI ◽  
...  
Keyword(s):  
Force Constant ◽  
Raman Spectra ◽  
Normal Mode ◽  
Raman Band ◽  
Normal Mode Analysis ◽  
Force Constants ◽  
Mode Analysis ◽  
Oxidation Number

We have obtained the Raman spectra of TiCl n (n= 2, 3, and 4). Assignments of the observed Raman bands were made by a normal mode analysis. The force constants were determined from the observed Raman band frequencies. We have found that the Ti-Cl stretching force constant increases as the oxidation number of the Ti species increases.

Nitrogen and Oxygen Self-Broadening and Shift Coefficients of Rotational-Vibrational Raman Band in 1–50 ATM Range

2021 ◽  
Vol 63 (9) ◽  
pp. 1646-1648
Author(s):  
D. V. Petrov ◽  
I. I. Matrosov ◽  
A. R. Zaripov ◽  
A. S. Tanichev
Keyword(s):  
Raman Band

scholarly journals Atmospheric Ice Particle Shape Estimates from Polarimetric Radar Measurements and In Situ Observations

2017 ◽  
Vol 34 (12) ◽  
pp. 2569-2587 ◽  
Author(s):  
Sergey Y. Matrosov ◽  
Carl G. Schmitt ◽  
Maximilian Maahn ◽  
Gijs de Boer
Keyword(s):  
Aspect Ratio ◽  
Particle Shape ◽  
Characteristic Size ◽  
In Situ Measurements ◽  
Department Of Energy ◽  
Depolarization Ratio ◽  
Suggested Approach ◽  
Aspect Ratios ◽  
Radar Measurements

AbstractA remote sensing approach to retrieve the degree of nonsphericity of ice hydrometeors using scanning polarimetric Ka-band radar measurements from a U.S. Department of Energy Atmospheric Radiation Measurement (ARM) Program cloud radar operated in an alternate transmission–simultaneous reception mode is introduced. Nonsphericity is characterized by aspect ratios representing the ratios of particle minor-to-major dimensions. The approach is based on the use of a circular depolarization ratio (CDR) proxy reconstructed from differential reflectivity ZDR and copolar correlation coefficient ρhυ linear polarization measurements. Essentially combining information contained in ZDR and ρhυ, CDR-based retrievals of aspect ratios are fairly insensitive to hydrometeor orientation if measurements are performed at elevation angles of around 40°–50°. The suggested approach is applied to data collected using the third ARM Mobile Facility (AMF3), deployed to Oliktok Point, Alaska. Aspect ratio retrievals were also performed using ZDR measurements that are more strongly (compared to CDR) influenced by hydrometeor orientation. The results of radar-based retrievals are compared with in situ measurements from the tethered balloon system (TBS)-based video ice particle sampler and the ground-based multiangle snowflake camera. The observed ice hydrometeors were predominantly irregular-shaped ice crystals and aggregates, with aspect ratios varying between approximately 0.3 and 0.8. The retrievals assume that particle bulk density influencing (besides the particle shape) observed polarimetric variables can be deduced from the estimates of particle characteristic size. Uncertainties of CDR-based aspect ratio retrievals are estimated at about 0.1–0.15. Given these uncertainties, radar-based retrievals generally agreed with in situ measurements. The advantages of using the CDR proxy compared to the linear depolarization ratio are discussed.

VIBRATIONAL FREQUENCY PERTURBATIONS IN THE RAMAN SPECTRUM OF COMPRESSED GASEOUS HYDROGEN

1964 ◽  
Vol 42 (6) ◽  
pp. 1058-1069 ◽  
Author(s):  
A. D. May ◽  
G. Varghese ◽  
J. C. Stryland ◽  
H. L. Welsh
Keyword(s):  
Raman Band ◽  
Intermolecular Forces ◽  
Hydrogen Gas ◽  
High Spectral Resolution ◽  
Intermolecular Potential ◽  
Dispersion Forces ◽  
Frequency Shifts ◽  
Linear Coefficient ◽  
Relative Population ◽  
Good Agreement

The frequencies of the Q(J) lines of the fundamental Raman band of compressed hydrogen gas were measured with high spectral resolution for a series of densities from 25 to 400 Amagat units at 300 °K and 85 °K. The frequency shifts are expressed as a power series in the gas density. The linear coefficient at a given temperature has the form aJ = ai + ae(nJ/n), where ai, constant for all the Q lines, can be interpreted in terms of isotropic intermolecular forces, and ae(nJ/n), proportional to the relative population of the initial J level, arises from the inphase coupled oscillation of pairs of molecules. The temperature variation of ai is analyzed on the basis of the Lennard-Jones intermolecular potential and the molecular pair distribution function. The repulsive overlap forces and the attractive dispersion forces give, respectively, positive and negative contributions to ai, which can be characterized by the empirical parameters Krep and Katt. The values of Katt and ae are in good agreement with calculations based on the polarizability model of the dispersion forces. The relation of the results to the Raman frequency shifts in solid hydrogen is discussed.

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